A proton spin-lattice relaxation rate study of methyl and t-butyl group reorientation in the solid state

Solid State Nuclear Magnetic Resonance

Volumn 38, Issue 1, 2010, Pages 31-35

  Popa, Laura C ^a,c   Rheingold, Arnold L ^b   Beckmann, Peter A ^a  

^a BRYN MAWR COLLEGE   (United States)

^b UNIVERSITY OF CALIFORNIA   (United States)

^c MASSACHUSETTS INSTITUTE OF TECHNOLOGY   (United States)

Author keywords

Intramolecular motion; Methyl group reorientation; Solid state NMR relaxation; t butyl group reorientation; X ray diffraction

Indexed keywords

DYNAMICAL PARAMETERS; EXPERIMENTAL UNCERTAINTY; IN-PLANE; INDEPENDENT BARRIERS; INTRAMOLECULAR MOTION; METHYL GROUP; OUT-OF-PLANE; PROTON SPIN LATTICE RELAXATION; ROTATIONAL BARRIERS; SOLID STATE NMR RELAXATION; SOLID-STATE NUCLEAR MAGNETIC RESONANCE; SPIN LATTICE RELAXATION RATES; SPIN-SPIN INTERACTION; T-BUTYL GROUPS; TIME-SCALES;

ACTIVATION ENERGY; DIFFRACTION; LIGHT POLARIZATION; RESONANCE; ROTATION; SPIN-LATTICE RELAXATION; X RAY DIFFRACTION; X RAYS;

NUCLEAR MAGNETIC RESONANCE;

BUTANE; METHANE; PROTON;

ARTICLE; CHEMICAL STRUCTURE; CHEMISTRY; CONFORMATION; METHODOLOGY; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; TEMPERATURE;

BUTANES; MAGNETIC RESONANCE SPECTROSCOPY; METHANE; MODELS, MOLECULAR; MOLECULAR CONFORMATION; PROTONS; TEMPERATURE;

EID: 77955849467     PISSN: 09262040     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.ssnmr.2010.06.003     Document Type: Article

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