Hypervalent λ3-bromane strategy for Baeyer-Villiger oxidation: Selective transformation of primary aliphatic and aromatic aldehydes to formates, which is missing in the classical Baeyer-Villiger oxidation

Journal of the American Chemical Society

Volumn 132, Issue 27, 2010, Pages 9236-9239

  Ochiai, Masahito ^a   Yoshimura, Akira ^a   Miyamoto, Kazunori ^a   Hayashi, Satoko ^b   Nakanishi, Waro ^b  

^a UNIVERSITY OF TOKUSHIMA   (Japan)

^b WAKAYAMA UNIVERSITY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

AROMATIC ALDEHYDE; BAEYER VILLIGER OXIDATION; CARBONYL COMPOUNDS; FORMATE ESTER; HIGH SELECTIVITY; LIGAND EXCHANGES; NOVEL METHODS; NOVEL STRATEGIES; REDUCTIVE ELIMINATION; SELECTIVE TRANSFORMATION;

AROMATIC COMPOUNDS; CARBONYLATION; CARBOXYLIC ACIDS; ESTERIFICATION; ESTERS; HYDRATES; HYDRATION; ORGANIC ACIDS; OXIDATION;

ALDEHYDES;

ALDEHYDE; ALIPHATIC COMPOUND; ALKYL GROUP; BENZALDEHYDE; BENZENE DERIVATIVE; BROMANE; CARBONYL DERIVATIVE; CARBOXYLIC ACID; DICHLOROMETHANE; ESTER; FORMIC ACID DERIVATIVE; LIGAND; UNCLASSIFIED DRUG; WATER; AROMATIC HYDROCARBON; BROMINATED HYDROCARBON;

ARTICLE; BAEYER VILLIGER REACTION; BIOTRANSFORMATION; CHEMICAL REACTION KINETICS; CHEMICAL STRUCTURE; HYDRATION; METHODOLOGY; REACTION ANALYSIS; STRUCTURE ANALYSIS; CHEMISTRY; OXIDATION REDUCTION REACTION; SYNTHESIS;

ALDEHYDES; FORMATES; HYDROCARBONS, AROMATIC; HYDROCARBONS, BROMINATED; OXIDATION-REDUCTION;

EID: 77955807307     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja104330g     Document Type: Article

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