Quaternaries as intermediates in the thermal and oxidative degradation of alkanolamines

Industrial and Engineering Chemistry Research

Volumn 49, Issue 16, 2010, Pages 7147-7151

  Bedell, Stephen A ^a   Worley, Clare M ^a   Al Horr, Rida Sadek ^a   McCrery, David A ^a  

^a DOW CHEMICAL COMPANY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ALKANOLAMINES; HIGH TEMPERATURE; MASS SPECTRAL EVIDENCE; OXIDATIVE DEGRADATION; PRECISE MODELING; SOLVENT COMPOSITION; SYSTEMATIC VARIATION; THERMAL DEGRADATIONS;

DEGRADATION;

EID: 77955595974     PISSN: 08885885     EISSN: 15205045     Source Type: Journal    
DOI: 10.1021/ie100938e     Document Type: Article

References (11)

1. 2 Symposium, April 1, 2010, Abu Dhabi.
2. Bedell, S. A. Oxidative degradation mechanisms for amines in flue gas capture Energy Procedia 2009, 1, 771
3. Kennard, M. L.; Meisen, A. Mechanisms and kinetics of diethanolamine degradation Ind. Eng. Chem. Fundam. 1985, 24, 129
4. Kim, C. J. Degradation of alkanolamines in gas-treating solutions: Kinetics of di-2-propanolamine degradation in aqueous solutions containing carbon dioxide Ind. Eng. Chem. Res. 1988, 27, 1
5. 2 Stoichiometry and Mechanistic Implications Int. J. Greenhouse Gas Control, 2010; in press.
6. Snyder, H. R.; Carnahan, R. E.; Lovejoy, E. R. The disporportionation of tertiary amines J. Am. Chem. Soc. 1954, 76, 1301
7. Hünig, S.; Baron, W. Abbau Quartaerer Ammoniumsalze mit Aethanolamine, I Chem. Ber. 1957, 90, 395
8. March, J. Advanced Organic Chemistry, 3rd Ed.; John Wiley and Sons, New York, 1985; p 299.
9. Lichtfers, T.; Asprion, N.; Claessen, M.; Umino, H.; Tanaka, K. Process for the recovery of carbon dioxide; International Patent Application WO 2007, / 068695 A1.
10. 2S Chem. Eng. Commun. 2006, 193, 129
11. Martell, A. E.; Smith, R. M.; Motekaitis, R. J. NIST Critically Selected Stability Constants of Metal Complexes Database; NIST Standard Reference Database 46, Vers. 7; U.S. Department of Commerce, 2003.