Sm0.5Sr0.5Co0.4Ni0.6O 3-δ-Sm0.2Ce0.8O1.9 as a potential cathode for intermediate-temperature solid oxide fuel cells

International Journal of Hydrogen Energy

Volumn 35, Issue 16, 2010, Pages 8663-8669

  Fu, Yen Pei ^a  

^a NATIONAL DONG HWA UNIVERSITY   (Taiwan)

Author keywords

Composite cathode; Exchange current density; Mixed ionic and electronic conductor; Oxygen reduction reaction; Solid oxide fuel cells

Indexed keywords

ACTIVE SURFACE AREA; AREA-SPECIFIC RESISTANCES; CATHODE MATERIALS; CATHODE POLARIZATION; CATHODIC VOLTAGE; COMPOSITE CATHODE; DISSOCIATIVE ADSORPTION; EXCHANGE CURRENT DENSITIES; IMPEDANCE DIAGRAMS; INTERMEDIATE TEMPERATURE SOLID OXIDE FUEL CELL; IT-SOFCS; LSM/YSZ; MIXED IONIC AND ELECTRONIC CONDUCTORS; OXYGEN REDUCTION REACTION; POTENTIAL APPLICATIONS; RATE DETERMINING STEP; SDC ELECTROLYTE; TEMPERATURE RANGE; TRIPLE PHASE BOUNDARY;

CATHODES; CERIUM; CERIUM COMPOUNDS; CHARGE TRANSFER; CURRENT DENSITY; ELECTROCHEMICAL CORROSION; ELECTROCHEMICAL IMPEDANCE SPECTROSCOPY; ELECTROLYTIC REDUCTION; GAS ADSORPTION; GAS FUEL PURIFICATION; OXYGEN; SOLID OXIDE FUEL CELLS (SOFC);

ION EXCHANGE;

EID: 77955584069     PISSN: 03603199     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.ijhydene.2010.05.109     Document Type: Article

References (29)

1. B. Zhu, X. Liu, Z. Zhu, and R. Ljungberg Solid oxide fuel cell (SOFC) using industrial grade mixed rare-earth oxide electrolytes Int J Hydrogen Energy 33 2008 3385 3392
2. 3-δ cathode for intermediate-temperature solid oxide fuel cells Int J Hydrogen Energy 33 2008 4681 4688
3. H. Moon, S.D. Kim, S.H. Hyun, and H.S. Kim Development of IT-SOFC unit cells with anode-supported thin electrolytes via tape casting and co-firing Int J Hydrogen Energy 33 2009 1758 1768
4. 3-x/yttria-stabilized zirconia interface by secondary-ion mass spectrometry J Electrochem Soc 145 1998 3196 3202
5. P.N. Dyer, R.E. Richards, S.L. Russck, and D.M. Taylor Ion transport membrane technology for oxygen separation and syngas production Solid State Ionics 134 2000 21 33
6. J.P.P. Huijsmans, F.P.F. Van Berkel, and G.M. Christic Intermediate temperature SOFC - a promise for the 21st century J Power Sources 71 1998 107 110
7. B.C.H. Steels, K.M. Hori, and S. Uchino Kinetic parameters influencing the performance of IT-SOFC composite electrodes Solid State Ionics 135 2000 445 450
8. 1.9-electrolyte based intermediate-temperature solid-oxide fuel cells J Power Sources 168 2007 330 337
9. 3 as a new cathode material J Electrochem Soc 145 1998 3177 3183
10. J. Fleig Solid oxide fuel cell cathodes: polarization mechanisms and modeling of the electrochemical performance Annu Rev Mater Res 33 2003 2003 361 382
11. 2.8 electrolyte interface for solid oxide fuel cells Electrochimica Acta 46 2001 1837 1845
12. J. Drennan, C.P. Travares, and B.C.H. Steels An electron microscope investigation of phases in the system La-Ni-O Mater Res Bull 17 1982 621 626
13. 2 interface by electrochemical impedance spectroscopy J Power Sources 110 1 2002 201 208
14. Y.P. Fu, S.B. Wen, and C.H. Lu Preparation and characterization of samaria-doped ceria electrolyte materials for solid oxide fuel cells J Am Ceram Soc 91 2008 127 131
15. S.B. Adler, B.T. Henderson, M.A. Wilson, D.M. Taylor, and R.E. Richards Reference electrode placement and seals in electrochemical oxygen generators Solid State Ionics 134 2000 35 42
16. J. Winkler, P.V. Hendriksen, N. Bonanos, and M. Mogensen Geometric requirements of solid electrolyte cells with a reference electrode J Electrochem Soc 145 1998 1184 1192
17. S.H. Chan, X.J. Chen, and K.A. Khor Reliability and accuracy of measured overpotential in a three-electrode fuel cell system J Appl Electrochem 31 2001 1163 1170
18. 3 cathodes for low-temperature SOFCs Solid State Ionics 149 2002 11 19
19. 2-δ J Am Ceram Soc 88 2005 79 84
20. H.J. Hwang, J.W. Moon, S. Lee, and E.A. Lee Electrochemical performance of LSCF-based composite cathodes for intermediate temperature SOFCs J Power Sources 145 2005 243 248
21. Y. Leng, S.H. Chan, and Q. Liu Development of LSCF-GDC composite cathodes for low-temperature solid oxide fuel cells with thin film GDC electrolyte Int J Hydrogen Energy 33 2008 3808 3817
22. J.X. Zhu, D.F. Zhou, S.R. Guo, J.F. Ye, X.F. Hao, and X.Q. Cao Grain boundary conductivity of high purity neodymium-doped ceria nanosystem with and without the doping of molybdenum oxide J Power Sources 174 2007 114 123
23. 3-δ cathodes prepared via electroless deposition Electrochim Acta 53 2008 4370 4380
24. S.B. Adler Limitations of charge-transfer models for mixed-conducting oxygen electrodes Solid State Ionics 135 2000 603 612
25. C. Fu, K. Sun, N. Zhang, X. Chen, and D. Zhou Electrochemical characteristics of LSCF-GDC composite cathode for intermediate temperature SOFC Electrochim Acta 52 2007 4589 4594
26. F. Qiang, K.N. Sun, N.Q. Zhang, X.D. Zhu, S.R. Le, and D.R. Zhou Characterization of electrical properties of GDC doped A-site deficient LSCF based composite cathode using impedance spectroscopy J Power Sources 168 2007 338 345
27. S.B. Adler Factors governing oxygen reduction in solid oxide fuel cell cathodes Chem Rev 104 2004 4791 4843
28. 3 cathode material for intermediate temperature solid oxide fuel cells J Power Sources 172 2007 633 640
29. 3 cathode Solid State Ionics 177 2006 377 387