Stereoselective construction of quaternary chiral centers using Ti(III)-mediated opening of 2,3-epoxy alcohols: Studies directed toward the synthesis of penifulvins

Tetrahedron Letters

Volumn 51, Issue 33, 2010, Pages 4425-4428

  Chakraborty, Tushar Kanti ^a   Chattopadhyay, Amit Kumar ^b   Samanta, Rajarshi ^b   Ampapathi, Ravi Sankar ^a  

^a CENTRAL DRUG RESEARCH INSTITUTE   (India)

^b INDIAN INSTITUTE OF CHEMICAL TECHNOLOGY   (India)

Author keywords

Penifulvin; Quaternary chiral center; Radical cyclization; Ti(III) mediated epoxide opening

Indexed keywords

ALCOHOL DERIVATIVE; ESTER; INSECTICIDE; PENIFULVIN A; PENIFULVIN B; PENIFULVIN C; PENIFULVIN D; PENIFULVIN E; RADICAL; TITANIUM; UNCLASSIFIED DRUG;

ARTICLE; CHEMICAL STRUCTURE; CHIRALITY; CYCLIZATION; DIASTEREOISOMER; MICHAEL ADDITION; NUCLEAR OVERHAUSER EFFECT; OXIDATION; RING OPENING; STEREOCHEMISTRY; SYNTHESIS;

EID: 77955412455     PISSN: 00404039     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.tetlet.2010.06.076     Document Type: Article

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