Potential for fixation of N2 at room temperature utilizing a copper-ion-exchanged MFI-type zeolite as an adsorbent: Evaluation of the bond dissociation energy of adsorbed N≡N and the bond strength of the Cu +-N(≡N) species

Journal of Physical Chemistry Letters

Volumn 1, Issue 15, 2010, Pages 2385-2390

  Itadani, Atsushi ^a   Tanaka, Masashi ^a   Mori, Toshinori ^a   Torigoe, Hiroe ^a   Kobayashi, Hisayoshi ^b   Kuroda, Yasushige ^a  

^a OKAYAMA UNIVERSITY   (Japan)

^b KYOTO INSTITUTE OF TECHNOLOGY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

ADSORPTION MODEL; BOND DISSOCIATION ENERGIES; BOND STRENGTH; DFT CALCULATION; EXPERIMENTAL DATA; MFI-TYPE ZEOLITE; N SPECIES; ROOM TEMPERATURE; VIBRATIONAL FREQUENCIES;

ADSORPTION; DISSOCIATION;

ION EXCHANGE;

EID: 77955388362     PISSN: None     EISSN: 19487185     Source Type: Journal    
DOI: 10.1021/jz100467w     Document Type: Article

References (33)

1. Chatt, J.; Dilworth, J. R.; Richards, R. L. Recent Advances in the Chemistry of Nitrogen Fixation Chem. Rev. 1978, 78, 589-625
2. Hidai, M.; Mizobe, Y. Recent Advances in the Chemistry of Dinitrogen Complexes Chem. Rev. 1995, 95, 1115-1133
3. Himmel, H.-J.; Reiher, M. Intrinsic Dinitrogen Activation at Bare Metal Atoms Angew. Chem., Int. Ed. 2006, 45, 6264-6288
4. n (where n = 1-4), in Low Temperature Matrices Can. J. Chem. 1973, 51, 3332-3343
5. 3 at Ambient Temperature J. Am. Chem. Soc. 1991, 113, 2919-2922
6. Wey, J. P.; Neely, W. C.; Worley, S. D. Infrared Spectroscopy at High Pressure. Adsorption of Dinitrogen on Supported Rhodium in the Absence of Carbon Monoxide J. Phys. Chem. 1991, 95, 8879-8881
7. Kuroda, Y.; Konno, S.; Morimoto, K.; Yoshikawa, Y. Strong Adsorption of Dinitrogen on Copper-Ion-Exchanged Mordenite at Room Temperature J. Chem. Soc., Chem. Commun. 1993, 18-20
8. 2-Adsorption Site Existing on CuZSM-5 Type Zeolite: Effect of Ion-Exchange Level on Adsorption Properties J. Phys. Chem. B 1999, 103, 2155-2164
9. I-ZSM-5: An FTIR Investigation J. Chem. Soc., Faraday Trans. 1995, 91, 3285-3290
10. Recchia, S.; Dossi, C.; Psaro, R.; Fusi, A.; Ugo, R.; Moretti, G. Dinitrogen Irreversible Adsorption on Overexchanged Cu-ZSM-5 J. Phys. Chem. B 2002, 106, 13326-13332
11. Iwamoto, M.; Furukawa, H.; Mine, Y.; Uemura, F.; Mikuriya, S.; Kagawa, S. Copper(II) Ion-Exchanged ZSM-5 Zeolites as Highly Active Catalysts for Direct and Continuous Decomposition of Nitrogen Monoxide J. Chem. Soc., Chem. Commun. 1986, 1272-1273
12. Iwamoto, M.; Yahiro, H. Novel Catalytic Decomposition and Reduction of NO Catal. Today 1994, 22, 5-18
13. x with N-Free Reductants Chem. Rev. 1995, 95, 209-225
14. Giamello, E.; Murphy, D.; Magnacca, G.; Morterra, C.; Shioya, Y.; Nomura, T.; Anpo, M. The Interaction of NO with Copper Ions in ZSM5: An EPR and IR Investigation J. Catal. 1992, 136, 510-520
15. 2+ ESR Study J. Phys. Chem. 1995, 99, 16327-16337
16. I-ZSM-5 J. Phys. Chem. B 1997, 101, 344-360
17. Kumashiro, R.; Kuroda, Y.; Nagao, M. New Analysis of Oxidation State and Coordination Environment of Copper Ion-Exchanged in ZSM-5 Zeolite J. Phys. Chem. B 1999, 103, 89-96
18. Zhang, Y.; Drake, J.; Bell, A. T. Characterization of Cu-ZSM-5 Prepared by Solid-State Ion Exchange of H-ZSM-5 with CuCl Chem. Mater. 2006, 18, 2347-2356
19. + Ions in ZSM-5: A Combined Quantum Mechanics/Interatomic Potential Function Study Phys. Chem. Chem. Phys. 1999, 1, 2019-2026
20. 2 dissociation on Ruthenium. J. Phys. Chem. C 2008, 112, 17768 - 17771 and reference therein.
21. 2 Bond Strength Chem.-Eur. J. 2005, 11, 4096-4102
22. Nakamoto, K. Infrared and Raman Spectra of Inorganic and Coordination Compounds, 5 th ed.; John Wiley & Sons, Inc.: New York, 1997.
23. Barrow, G. M. Physical Chemistry, 6 th ed.; McGraw-Hill: New York, 1996.
24. m (where n = 1-4 and m = 1-3) J. Am. Chem. Soc. 1975, 97, 2672-2675
25. Torreggiani, A.; Esposti, A. D.; Tamba, M.; Marconi, G.; Fini, G. Experimental and Theoretical Raman Investigation on Interactions of Cu(II) with Hhistamine J. Raman Spectrosc. 2006, 37, 291-298
26. Huang, Y.-Y. Infrared Study of Copper(I) Carbonyls in Y Zeolite J. Am. Chem. Soc. 1973, 95, 6636-6640
27. + (n = 1, 2) Complex Ions in Zeolite Cages Inorg. Chem. 1996, 35, 6918-6921
28. Borovkov, V. Y.; Jiang, M.; Fu, Y. Investigation of Copper Carbonyl Species Formed upon CO Adsorption on Copper-Exchanged Zeolites by Diffuse Reflectance FTIR J. Phys. Chem. B 1999, 103, 5010-5019
29. Mortimer, R. G. Physical Chemistry; The Benjamin/Cummings Publishing Company, Inc.: Redwood City, CA, 1993.
30. Silbey, R. J.; Alberty, R. A. Physical Chemistry, 3 th ed.; John Wiley & Sons, Inc.: New York, 2001.
31. +/MFI J. Phys. Chem. A 2003, 107, 10381-10388
32. 2 Adsorption Properties of Copper-Ion-Exchanged MFI-Type Zeolites at Room Temperature J. Phys. Chem. C 2007, 111, 12011-12023
33. 2 Adsorption and Ion-Exchange Features of CuMFI with Different Si/Al Ratios New J. Chem. 2007, 31, 1681-1690