Investigation of methanol oxidation over Au/catalysts using operando IR spectroscopy: Determination of the active sites, intermediate/spectator species, and reaction mechanism

Journal of the American Chemical Society

Volumn 132, Issue 31, 2010, Pages 10832-10841

  Rousseau, Séverine ^a,c   Marie, Olivier ^a   Bazin, Philippe ^a   Daturi, Marco ^a   Verdier, Stéphane ^b   Harlé, Virginie ^b  

^a UNIVERSITÉ DE CAEN   (France)

^b Rhodia Recherches   (France)

^c CENTRO RICERCHE FIAT   (Italy)

Author keywords

[No Author keywords available]

Indexed keywords

ACTIVE SITE; FTIR SPECTROSCOPY; GASEOUS SPECIES; INTERMEDIATE SPECIE; IR SPECTROSCOPY; LOW TEMPERATURES; METHANOL OXIDATION; METHOXY SPECIES; NANO-STRUCTURED; NOBLE METALS; OPERANDO; OPERANDO SPECTROSCOPY; OXIDATION PATHWAY; RATE DETERMINING STEP; REACTION MECHANISM; SIMULTANEOUS ANALYSIS; SURFACE SPECIES;

CATALYST ACTIVITY; FOURIER TRANSFORM INFRARED SPECTROSCOPY; MASS SPECTROMETRY; METHANOL; OXIDATION; PRECIOUS METALS; WAVELET TRANSFORMS;

REACTION INTERMEDIATES;

ALKANE DERIVATIVE; CARBON DIOXIDE; CERIUM OXIDE; GOLD; METHANOL; TITANIUM DIOXIDE;

ADSORPTION; ARTICLE; BIOTRANSFORMATION; CATALYSIS; CATALYST; CHEMICAL COMPOSITION; CHEMICAL REACTION; CONTROLLED STUDY; GAS; INFRARED SPECTROSCOPY; MOLECULAR MODEL; OPERANDO INFRARED SPECTROSCOPY; OXIDATION; PHASE TRANSITION; SURFACE PROPERTY;

CATALYSIS; CATALYTIC DOMAIN; CERIUM; GOLD; MASS SPECTROMETRY; METHANOL; OXIDATION-REDUCTION; SPECTROSCOPY, FOURIER TRANSFORM INFRARED; TITANIUM;

EID: 77955351305     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja1028809     Document Type: Article

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