Mesoporous aluminosilicate-catalyzed Sakurai allylation and Mukaiyama aldol reaction of acetals

Tetrahedron Letters

Volumn 51, Issue 32, 2010, Pages 4243-4245

  Ito, Suguru ^a   Hayashi, Akira ^a   Komai, Hirotomo ^a   Kubota, Yoshihiro ^a   Asami, Masatoshi ^a  

^a YOKOHAMA NATIONAL UNIVERSITY   (Japan)

Author keywords

Al MCM 41; Mukaiyama aldol reaction; Sakurai allylation; Solid acid catalyst

Indexed keywords

ACETAL DERIVATIVE; ALLYLTRIMETHYLSILANE; ALUMINUM DERIVATIVE; SILICATE;

ALLYLATION; ARTICLE; CATALYSIS; CHEMICAL ANALYSIS; CHEMICAL REACTION; MUKAIYAMA REACTION;

EID: 77955305545     PISSN: 00404039     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.tetlet.2010.06.034     Document Type: Article

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40. 2/g and 2.7 nm, respectively.
41. 2/g.
42. 2/g and 2.6 nm, respectively.
43. 2/g, respectively. The average pore diameter (BJH) was 2.7 nm.
44. 13C NMR spectra. The recovered catalyst was dried at 70 °C for 15 min. Then, the catalyst (50 mg) was dried at 120 °C for 1 h under vacuum and used in a second run.
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46. 13C NMR spectra. The recovered catalyst was dried at 70 °C for 15 min. Then, the catalyst (50 mg) was dried at 120 °C for 1 h under vacuum and used in a second run.
47. Silica sources of present and previous MCM-41 were tetraethyl orthosilicate and colloidal silica, respectively.
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