Permanent magnetism in phosphine- and chlorine-capped gold: From clusters to nanoparticles

Journal of Nanoparticle Research

Volumn 12, Issue 4, 2010, Pages 1307-1318

  Muñoz Márquez, Miguel A ^a   Guerrero, Estefanía ^a   Fernández, Asunción ^a   Crespo, Patricia ^b,c   Hernando, Antonio ^b,c   Lucena, Raquel ^d   Conesa, José C ^d  

^a INSTITUTO DE CIENCIA DE MATERIALES DE SEVILLA   (Spain)

^b INSTITUTO DE MAGNETISMO APLICADO   (Spain)

^c UNIVERSIDAD COMPLUTENSE DE MADRID   (Spain)

^d INSTITUTO DE CATÁLISIS Y PETROLEOQUÍMICA   (Spain)

Author keywords

EPR spectroscopy'SQUID magnetometry Ferromagnetic behaviour; Gold clusters; Gold nanoparticles

Indexed keywords

EPR SPECTROSCOPY; FERROMAGNETIC BEHAVIOUR; GOLD CLUSTERS; GOLD NANOPARTICLES; SQUID MAGNETOMETRY;

CHARGE TRANSFER; CHLORINE; CHLORINE COMPOUNDS; ELECTRON SPIN RESONANCE SPECTROSCOPY; FERROMAGNETIC MATERIALS; FERROMAGNETISM; GOLD; GOLD COMPOUNDS; ION EXCHANGE; MAGNETOMETERS; NANOMAGNETICS; NANOPARTICLES; PARAMAGNETIC RESONANCE; PHOSPHORUS COMPOUNDS;

ABSORPTION SPECTROSCOPY;

CHLORINE; FERROMAGNETIC MATERIAL; GOLD NANOPARTICLE; IRON; PHOSPHINE;

ARTICLE; CAPPING PHENOMENON; ELECTRON SPIN RESONANCE; LIGAND BINDING; MAGNETISM; METAL BINDING; PARTICLE SIZE; PRIORITY JOURNAL; X RAY SPECTROMETRY;

EID: 77955090967     PISSN: 13880764     EISSN: 1572896X     Source Type: Journal    
DOI: 10.1007/s11051-010-9862-0     Document Type: Article

References (59)

1. Abraham DW, Frank MM, Guha S (2005) Absence of magnetism in hafnium oxide films. Appl Phys Lett 87(25):252, 502
2. Alivisatos AP (1996) Semiconductor clusters, nanocrystals, and quantum dots. Science 271(5251):933-937
3. Alvarez MM, Khoury JT, Schaaff TG, Shafigullin MN, Vezmar I, Whetten RL (1997) Optical absorption spectra of nanocrystal gold molecules. J Phys Chem B 101(19): 3706-3712
4. Andres RP, Bielefeld JD, Henderson JI, Janes DB, Kolagunta VR, Kubiak CP, Mahoney WJ, Osifchin RG (1996) Selfassembly of a two-dimensional superlattice of molecularly linked metal clusters. Science 273:1690-1693
5. Baker TA, Friend CM, Kaxiras E (2008) Chlorine interaction with defects on the Au(111) surface: a first-principles theoretical investigation. J Chem Phys 129(10):104, 702
6. Barnard AS, Young NP, Kirkland AI, van Huis MA, Xu H (2009) Nanogold: a quantitative phase map. ACS Nano 3(6):1431-1436
7. Bartlett PA, Bauer B, Singer SJ (1978) Synthesis of watersoluble undecagold cluster compounds of potential importance in electron microscopic and other studies of biological systems. J Am Chem Soc 100(16):5085-5089
8. Boyen HG, Kästle G, Weigl F, Koslowski B, Dietrich C, Ziemann P, Spatz JP, Riethmüller S, Hartmann C, Möller M, Schmid G, Garnier MG, Oelhafen P (2002) Oxidationresistant gold-55 clusters. Science 297(5586):1533-1536
9. Braunstein P, Lehner H, Matt D, Burgess K, Ohlmeyer MJ (1990) Inorganic Syntheses, vol 27, chap 5: transition metal cluster complexes. Wiley InterScience, Malden. Section 42, A platinum-gold cluster: chloro-1 j Clbis( triethylphosphine-1κ)bis(triphenyl-phosphine)- 2κ,3κ- triangulo-digold-platinum(1+) trifluoromethanesulfonate, pp 218-221
10. 3: The realization of a theoretical prediction. J Chem Soc Chem Commun (5):201-202
11. Brust M, Walker M, Bethell D, Schiffrin DJ, Whyman R (1994) Synthesis of thiol-derivatised gold nanoparticles in a two-phase liquid-liquid system. J Chem Soc Chem Commun, p 801
12. Cleveland CL, Landman U, Schaaff TG, Shafigullin MN, Stephens PW, Whetten RL (1997) Structural evolution of smaller gold nanocrystals: the truncated decahedral motif. Phys Rev Lett 79(10):1873-1876
13. Crespo P, Litrán R, Rojas TC, Multigner M, de la Fuente JM, Sánchez-López JC, García MA, Hernando A, Penadés S, Fernández A (2004) Permanent magnetism, magnetic anisotropy, and hysteresis of thiol-capped gold nanoparticles. Phys Rev Lett 93(8):87, 204
14. Crespo P, García MA, Fernández-Pinel E, Multigner M, Alcántara D, de la Fuente JM, Penadés S, Hernando A (2006) Fe impurities weaken the ferromagnetic behavior in Au nanoparticles. Phys Rev Lett 97(17):177, 203
15. Daniel MC, Astruc D (2004) Gold nanoparticles: assembly, supramolecular chemistry, quantum-size-related properties, and applications toward biology, catalysis and nanotechnology. Chem Rev 104(1):293-346
16. de la Venta J, Bouzas V, Pucci A, Laguna-Marco MA, Haskel D, te Velthuis SGE, Hoffmann A, Lal J, Bleuel M, Ruggeri G, de Julián Fernández C, García MA (2009) X-ray magnetic circular dichroism and small angle neutron scattering studies of thiol capped gold nanoparticles. J Nanosci Nanotech 9:6434-6438
17. Dutta P, Dal S, Seehra S, Anand M, Roberts CB (2007) Magnetism in dodecanethiol-capped gold nanoparticles: role of size and capping agent. Appl Phys Lett 90(21):102, 213
18. Fittipaldi M, Sorace L, Barra AL, Sangregorio C, Sessoli R, Gatteschi D (2009) Molecular nanomagnets and magnetic nanoparticles: the EMR contribution to a common approach. Phys Chem Chem Phys 11(31):6555-6568
19. Garitaonandia JS, Insausti M, Goikolea E, Suzuki M, Cashion JD, Kawamura N, Ohsawa H, Gil de Muro I, Suzuki K, Plazaola F, Rojo T (2008) Chemically induced permanent magnetism in Au, Ag and Cu nanoparticles: localization of the magnetism by element selective techniques. Nano Lett 8(2):661-667
20. Gonzalez C, Simón-Manso Y, Marquez M, Mujica V (2006) Chemisorption-induced spin symmetry breaking in gold clusters and the onset of paramagnetism in capped gold nanoparticles. J Phys Chem B 110(2):687-691
21. Guerrero E, Rojas TC, Multigner M, Crespo P, Muñoz-Márquez MA, García MA, Hernando A, Fernández A (2007) Evolution of the microstructure, chemical composition and magnetic behaviour during the synthesis of alkanethiolcapped gold nanoparticles. Acta Mater 55(5):1723-1730
22. Guerrero E, Muñoz-Márquez MA, García MA, Crespo P, Fernández-Pinel E, Hernando A, Fernández A (2008) Surface plasmon resonance and magnetism of thiol-capped gold nanoparticles. Nanotechnology 19(17):175, 701
23. Hernando A, Crespo P, García MA (2006a) Origin of orbital ferromagnetism and giant magnetic anisotropy at the nanoscale. Phys Rev Lett 96(5):57, 206
24. Hernando A, Crespo P, García MA, Fernández-Pinel E, de la Venta J, Fernández A, Penadés S (2006b) Giant magnetic anisotropy at the nanoscale: overcoming the superparamagnetic limit. Phys Rev B 74(5):52, 403
25. 3+ substitution in hydroxyapatite: Theory and experiment. Phys Rev B 66(22):107, 224
26. 2 with the Au(111) surface in the temperature range of 120 to 1000 K. Appl Surf Sci 64:235-249
27. Luo W, Pennycook SJ, Pantelides ST (2007) s-Electron ferromagnetism in gold and silver nanoclusters. Nano Lett 7(10):3134-3137
28. Menard LD, Gao SP, Xu H, Twesten RD, Harper AS, Song Y, Wang G, Douglas AD, Yang JC, Frenkel AI, Nuzzo RG, Murray RW (2006a) Sub-nanometer Au monolayer-protected clusters exhibiting molecule-like electronic behavior: quantitative high-angle annular dark-field scanning transmission electron microscopy and electrochemical characterization of clusters with precise atomic stoichiometry. J Phys Chem B 110(26):12874-12883
29. Menard LD, Xu H, Gao SP, Twesten RD, Harper AS, Song Y, Wang G, Douglas AD, Yang JC, Frenkel AI, Murray RW, Nuzzo RG (2006b) Metal core bonding motifs of monodisperse icosahedral Au13 and larger Au monolayerprotected clusters as revealed by X-ray absorption spectroscopy and transmission electron microscopy. J Phys Chem B 110(30):14564-14573
30. Michael F, Gonzalez C, Mujica V, Marquez M, Ratner MA (2007) Size dependence of ferromagnetism in gold nanoparticles: mean field results. Phys Rev B 76(22):224, 409
31. Mingos DMP (1976) Molecular-orbital calculations on cluster compounds of gold. J Chem Soc Dalton Trans (13):1163-1169
32. Mingos DMP (1996) Gold-a flexible friend in cluster chemistry. J Chem Soc Dalton Trans (5):561-566
33. Müllegger S, Hänel K, Strunskus T, Wöll C, Winkler A (2006) Organic molecular beam deposition of oligophenyls on Au(111): a study by X-ray absorption spectroscopy. Chem Phys Chem 7:2552-2558
34. Narayanaswamy D, Marks LD (1993) Transformation in quasimelting. Z Phys D 26:S70-S72
35. Negishi Y, Tsunoyama H, Suzuki M, Kawamura N, Matsushita MM, Maruyama K, Sugawara T, Yokoyama T, Tsukuda T (2006) X-ray magnetic circular dichroism of size-selected, thiolated gold clusters. J Am Chem Soc 128(37):12034-12035
36. Nunokawa K, Onaka S, Ito M, Horibe M, Yonezawa T, Nishihara H, Ozeki T, Chiba H, Watase S, Nakamoto M (2006) Synthesis, single crystal X-ray analysis, and TEM for a single-size Au11 cluster stabilized by SR ligands: the interface between molecules and particles. J Organomet Chem 691:638-642
37. Periyasamy G, Remacle F (2009) Ligand and solvation effects on the electronic properties of Au55 clusters: a density functional theory study. Nano Lett 9(8):3007-3011
38. Sampedro B, Crespo P, Hernando A, Litrán R, Sánchez- López JC, López-Cartes C, Fernández A, Ramírez J, Calbet JG, Vallet M (2003) Ferromagnetism in fcc twinned 2.4 nm size Pd nanoparticles. Phys Rev Lett 91(23):203, 237
39. 55 clusters. Chem Soc Rev 37:1909-1930
40. 6-a gold cluster of an exceptional size. Chem Ber 114:3634-3642
41. Shinohara T, Sato T, Taniyama T (2003) Surface ferromagnetism of Pd fine particles. Phys Rev Lett 91(19):197, 201
42. Song Y, Huang T, Murray RW (2003) Heterophase ligand exchange and metal transfer between monolayer protected clusters. J Am Chem Soc 125(38):11694-11701
43. 3 on gold and copper. Langmuir 8(1):90-94
44. Suber L, Fiorani D, Scavia G, Imperatori P, Plunkett WR (2007) Permanent magnetism in dithiol-capped silver nanoparticles. Chem Mater 19(6):1509-1517
45. Sun S, Murray CB, Weller D, Folks L, Moser A (2000) Monodisperse FePt nanoparticles and ferromagnetic FePt nanocrystal superlattices. Science 287:1989-1992
46. 2 with an interstitial gold atom in a hexagonal antiprismatic cage. J Am Chem Soc 114(7):2743-2745
47. Tronconi AL, Morais PC, Pelegrini F, Tourinho FA (1993) Electron paramagnetic resonance study of ionic waterbased manganese ferrite ferrofluids. J Magn Magn Mater 122:90-92
48. Turner M, Golovko VB, Vaughan OPH, Abdulkin P, Berenguer- Murcia A, Tikhov MS, Johnson BFG, Lambert RM (2008) Selective oxidation with dioxygen by gold nanoparticles catalysts derived from 55-atom clusters. Nature 454:981-U31
49. Valden M, Lai X, Goodman DW (1998) Onset of catalytic activity of gold clusters on titania with the appearance of nonmetallic properties. Science 281(5383):1647-1650
50. Walter M, Akola J, Lopez-Acevedo O, Jadzinsky PD, Calero G, Ackerson CJ, Whetten RL, Grönbeck H, Häkkinen H (2008) A unified view of ligand-protected gold clusters as superatom complexes. Proc Natl Acad Sci USA 105(51): 9157-9162
51. Weare WW, Reed SM, Warner MG, Hutchison JE (2000) Improved synthesis of small (dcore & 1.5 nm) phosphinestabilized gold nanoparticles. J Am Chem Soc 122(51): 12890-12891
52. Whetten RL, Price RC (2007) Nano-golden order. Science 318:407-408
53. Whetten RL, Khoury JT, Alvarez MM, Murthy S, Vezmar I, Wang ZL, Stephens PW, Cleveland CL, Luedtke WD, Landman U (1996) Nanocrystal gold molecules. Adv Mat 8(5):428
54. Wilcoxon JP, Martin JE, Provencio P (2000) Size distributions of gold nanoclusters studied by liquid chromatography. Langmuir 16(25):9912-9920
55. Woehrle GH, Hutchison JE (2005) Thiol-functionalized undecagold clusters by ligand exchange: synthesis, mechanism, and properties. Inorg Chem 44(18):6149-6158
56. Yamamoto Y, Miura T, Suzuki M, Kawamura N, Miyagawa H, Nakamura T, Kobayashi K, Teranishi T, Hori H (2004) Direct observation of ferromagnetic spin polarization in gold nanoparticles. Phys Rev Lett 93(11):116, 801
57. Yang Y, Chen S (2003) Surface manipulation of the electronic energy of subnanometer-sized gold clusters: an electrochemical and spectroscopic investigation. Nano Lett 3(1):75-79
58. Yu M, Bovet N, Satterley CJ, Bengió S, Lovelock KRJ, Milligan PK, Jones RG, Woodruff DP, Dhanak V (2006) True nature of an archetypal self-assembly system: mobile Au-thiolate species on Au(111). Phys Rev Lett 97(16):102, 166
59. Zhang P, Sham TK (2002) Tuning the electronic behavior of Au nanoparticles with capping molecules. Appl Phys Lett 81(4):736-738