Synthesis and properties of sulfonated poly(ether ketone ether sulfone) (S-PEKES) via bisphenol S: Effect of sulfonation

Polymer Bulletin

Volumn 65, Issue 3, 2010, Pages 265-281

  Changkhamchom, S ^a   Sirivat, A ^a  

^a CHULALONGKORN UNIVERSITY   (Thailand)

Author keywords

Degree of sulfonation; Proton exchange membrane; Sulfonated poly(ether ketone ether sulfone)

Indexed keywords

AROMATIC RINGS; BISPHENOLS; CARBONYL GROUPS; CHAIN STIFFNESS; DEGREE OF SULFONATION; DIELECTRIC PERMITTIVITIES; ELECTRICAL CONDUCTIVITY; FTIR; ION EXCHANGE CAPACITY; LCR METERS; NUCLEOPHILIC AROMATIC SUBSTITUTION POLYCONDENSATION; POLYMER SAMPLES; PROTON EXCHANGE MEMBRANE; PROTON EXCHANGE MEMBRANES; SULFONATED POLY(ETHER KETONE ETHER SULFONE); SULFONATION DEGREE; THERMAL STABILITY; VICTREX; WATER UPTAKE;

DEIONIZED WATER; ELECTRIC CONDUCTIVITY; ION EXCHANGE; ION EXCHANGERS; KETONES; O RINGS; PHENOLS; POLYCONDENSATION; POLYMERS; PROTON EXCHANGE MEMBRANE FUEL CELLS (PEMFC); PROTONS; SULFONATION;

ETHERS;

EID: 77954953577     PISSN: 01700839     EISSN: None     Source Type: Journal    
DOI: 10.1007/s00289-010-0243-8     Document Type: Article

References (27)

1. Carette L, Friedrich KA, Stimming U (2001) Fuel cells'fundamentals and applications. Fuel Cells 1:5-39
2. Neburchilov V, Martin J, Wang H, Zhang J (2000) A review of polymer electrolyte membranes for direct methanol fuel cells. J Power Sources 169:221-238
3. Li L, Zhang J, Wang Y (2003) Sulfonated poly (ether ether ketone) membranes for direct methanol fuel cell. J Membr Sci 226:159-167
4. Gil M, Ji X, Li X, Na H, Hampsey JE, Lu Y (2004) Direct synthesis of sulfonated aromatic poly (ether ether ketone) proton exchange membranes for fuel cell applications. J Membr Sci 234:75-81
5. Huang RYM, Shao P, Burns CM, Feng X (2001) Sulfonation of poly (ether ether ketone) (PEEK): kinetic study and characterization. J Appl Polym Sci 82:2651-2660
6. Javaid ZSM (2005) Preparation and characterization of composite membranes using blends of SPEEK/PBI with boron phosphate. Electrochim Acta 50:4771-4777
7. Kaliaguine S, Mikhailenko SD, Wang KP, Xing P, Robertson G, Guiver M (2003) Properties of SPEEK based PEMs for fuel cell application. Catal Today 82:213-222
8. Li X, Wang Z, Lu H, Zhao C, Na H, Zhao C (2005) Electrochemical properties of sulphonated PEEK used ion exchange membranes. J Membr Sci 254:147-155
9. Li X, Zhao C, Lu H, Wang Z, Jiang W, Na H (2005) Preparation of a new type of ion-exchange membrane based on sulfonated poly (ether ether ketone ketone) s. J Appl Polym Sci 98:2481-2486
10. Mikhailenko SD, Robertson GP, Guova MD, Kaliaguine S (2006) Properties of PEMs based on cross-linked sulfonated poly (ether ether ketone). J Membr Sci 285:306-316
11. Mikhailenko SD, Wang K, Kaliaguine S, Xing P, Robertson GP, Guiver MD (2004) Proton conducting membranes based on cross-linked sulfonated poly (ether ether ketone) (SPEEK). J Membr Sci 223:93-99
12. Reyna-Valencia A, Kaliaguine S, Bousmina M (2006) Structural and mechanical characterization of poly (ether ether ketone) (PEEK) and sulfonated PEEK films: effects of thermal history, sulfonation, and preparation conditions. J Appl Polym Sci 99:756-774
13. Wang F, Li J, Chen T, Xu J (2003) Synthesis of poly (ether ether ketone) with high content of sodium sulfonate groups and its membrane characteristics. Polymer 40:795-799
14. Wang Z, Ni H, Zhao C, Li X, Fu T, Na H (2006) Investigation of sulfonated poly (ether ether ketone sulfone/Heteropolyacid composite membranes for high temperature fuel cell applications. J Polym Sci Polym Phys 44:1967-1978
15. Xing P, Robertson GP, Guiver MD, Mikhailenko SD, Wang K, Kaliaguine S (2004) Synthesis and characterization of sulfonated poly (ether ether ketone) for proton exchange membranes. J Membr Sci 229:95-106
16. Rao VL, Sabeena PU, Ninan KN (1998) Synthesis properties of polyetherketone and polyetherketonesulfone copolymers. Eur Polym J 34:567-570
17. Drioli E, Regina A, Casciola M, Oliveti A, Trotta F, Massari (2004) Sulfonated PEEK-WC membranes for possible fuel cell applications. J Membr Sci 228:139-148
18. Regina A, Fontananova E, Drioli E, Casciola M, Spanappa M, Trotta F (2006) Preparation and characterization of sulfonated PEEK-WC membranes for fuel cell applications: a comparison between polymeric and composite membranes. J Power Sources 160:139-147
19. Fontananova E, Regina A, Drioli E, Trotta F (2006) Improving of the performances of sulfonated PEEK-WC membranes by introducing heteropolyacids in the polymeric matrix. Desalination 200:658-659
20. Xiao G, Sun G, Yan D (2002) Synthesis and characterization of novel sulfonated poly (arylene ether ketone) s derived from 4, 4'-sulfonyldiphenol. Polym Bull 48:309-315
21. Li X, Lui C, Lu H, Zhao C, Wang Z, Xing W, Na H (2005) Preparation and characterization of sulfonated poly (ether ether ketone ketone) proton exchange membranes for fuel cell application. J Membr Sci 255:149-155
22. Vetter S, Ruffmann B, Buder I, Nunes SP (2005) Proton conductive membranes of sulfonated poly (ether ketone ketone). J Membr Sci 260:181-186
23. 3 crystals grown by epitaxy. J Phys B 17:552-558
24. Kunanuruksapong R, Sirivat A (2007) Poly (p-phenylene) and acrylic elastomer blends for electroactive application. Mater Sci Eng A 454-455:453-460
25. Gasa JV, Weiss RA, Shaw MT (2008) Structured polymer electrolyte blends based on sulfonated polyetherketonerketone (SPEKK) and a poly (ether imide) (PEI). J Membr Sci 320:215-223
26. Roeder J, Silva H, Nunes SP, Pires ATN (2005) Mixed conductive blends of SPEEK/PANI. Solid State Ion 176:1411-1417
27. Roede J, Zucolotto V, Shishatsky S, Bertolino JR, Nunes SP, Pires ATN (2006) Mixed conductive membrane: aniline polymerization in an acid SPEEK matrix. J Membr Sci 279:70-75