Selective single monomer addition in living cationic polymerization: Sequential double end-functionalization in combination with capping agent

Journal of Polymer Science, Part A: Polymer Chemistry

Volumn 48, Issue 15, 2010, Pages 3375-3381

  Ida, Shohei ^a   Terashima, Takaya ^a   Ouchi, Makoto ^a   Sawamoto, Mitsuo ^a  

^a KYOTO UNIVERSITY   (Japan)

Author keywords

Cationic polymerization; Living polymerization; Nationalization of polymers; Poly(vinyl ethers); Sequence regulation

Indexed keywords

BUTYL VINYL ETHERS; CAPPING AGENT; CARBOXYLATE GROUPS; DEPROTECTION; END-FUNCTIONALIZATION; FUNCTIONALIZED; LIVING CATIONIC POLYMERIZATION; MALONATES; MOLAR EXCESS; POLY(VINYL ETHERS); POLYMER CHAINS; SELECTIVE ADDITION; SINGLE MONOMERS; SITE-SPECIFIC; SODIUM MALONATE; VINYL ETHERS;

CARBOXYLATION; ETHERS; FUNCTIONAL GROUPS; FUNCTIONAL POLYMERS; LIVING POLYMERIZATION; OLEFINS; POLYMERS; STYRENE; ZINC;

CATIONIC POLYMERIZATION;

EID: 77954911100     PISSN: 0887624X     EISSN: 10990518     Source Type: Journal    
DOI: 10.1002/pola.24122     Document Type: Article

References (24)

1. For recent reviews on sequence control in artificial polymerization, see: (a) Badi, N.; Lutz, J.-F. Chem Soc Rev 2009, 38, 3383-3390;
2. (b) Lutz, J.-F. Nature Chem 2010, 2, 84-85;
3. (c) Lutz, J.-F. Polym Chem 2010, 1, 55-62.
4. (a) Minoda, M.; Sawamoto, M.; Higashimura, T. Macromolecules 1990, 23, 4889-4895;
5. (b) Minoda, M.; Sawamoto, M; Higashimura, T. J Polym Sci Part A: Polym Chem 1993, 31, 2789-2797;
6. (c) Ida, S.; Terashima, T; Ouchi, M; Sawamoto, M. J Am Chem Soc 2009, 131, 10808-10809.
7. (a) Sawamoto, M. Prog Polym Sci 1991, 16, 111-172;
8. (b) Kennedy, J. P.; Iván, B. Designed Polymers by Carbocationic Macromolecular Engineering: Theory and Practice; Henser: Munich, 1992;
9. (c) Matyjaszewski, K., Ed. Cationic Polymerization; Marcel Dekker: New York, 1996.
10. (a) Hadjikyriacou, S.; Fodor, Zs.; Faust, R. J Macromol Sci Pure Appl Chem 1995, A32, 1137-1153;
11. (b) Schlaad, H.; Erentova, K.; Faust, R.; Charleux, B.; Moreau, M.; Vairon, J.-P.; Mayr, H. Macromolecules 1998, 31, 8058-8062.
12. Hashimoto, T.; Ibuki, H.; Sawamoto, M.; Higashimura, T. J.; Polym Sci Part A: Polym Chem 1988, 26, 3361-3374.
13. Shohi, H.; Sawamoto, M.; Higashimura, T. Macromolecules 1992, 25, 58-63.
14. Sawamoto, M.; Enoki, T.; Higashimura, T. Macromolecules 1987, 20, 1-6.
15. Higashimura, T.; Kamigaito, M.; Kato, M.; Hasebe, T.; Sawamoto, M. Macromolecules 1993, 26, 2670-2673.
16. (a) Higashimura, T.; Ishihama, Y.; Sawamoto, M.; Macromolecules 1993, 26, 744-751;
17. (b) Kamigaito, M.; Maeda, Y.; Sawamoto, M.; Higashimura, T. Macromolecules 1993, 26, 1643-1649.
18. The methoxide terminal is derived from methanol quenching.
19. (a) Aoshima, S.; Yoshida, T.; Kanazawa, A.; Kanaoka, S. J. Polym Sci Part A: Polym Chem 2007, 45, 1801-1813;
20. (b) Aoshima, S.; Higashimura, T. Macromolecules 1989, 22, 1009-1013;
21. (c) Kishimoto, Y.; Aoshima, S.; Higashimura, T. Macromolecules 1989, 22, 3877-3882;
22. (d) Kaszas, G.; Puskas, J. E.; Chen, C. C.; Kennedy, J. P. Polym Bull 1988, 20, 413-419;
23. (e) Yonezumi, M.; Takano, N.; Kanaoka, S.; Aoshima, S. J Polym Sci Part A: Polym Chem 2008, 46, 6746-6753.
24. Liu, Q.; Konas, M.; Davis, R. M.; Riffle, J. S. J Polym Sci Part A: Polym Chem 1993, 31, 1709-1717.