Integrated CWPO and biological treatment for the removal of 4-chlorophenol from water

Separation Science and Technology

Volumn 45, Issue 11, 2010, Pages 1595-1602

  Molina, C B ^a   Pizarro, A H ^a   Monsalvo, V M ^a   Polo, A M ^a   Mohedano, A F ^a   Rodriguez, J J ^a  

^a UNIVERSIDAD AUTÓNOMA DE MADRID   (Spain)

Author keywords

4 chlorophenol; Al fe pillared clays; Biodegradability; CWPO; Respirometry

Indexed keywords

4-CHLOROPHENOL; 4-CHLOROPHENOL (4-CP); AL-FE PILLARED CLAYS; BIOLOGICAL TREATMENT; CATALYTIC WET PEROXIDE OXIDATION; CHLOROCATECHOL; MAIN COMPONENT; OXIDATION BY-PRODUCTS; OXIDATION PATHWAY; OXIDATION TREATMENTS; PILLARED CLAY; RESPIROMETRIC STUDIES; RESPIROMETRY; SHORT-CHAIN CARBOXYLIC ACIDS; TOXIC SPECIES;

BIOCHEMICAL ENGINEERING; BIODEGRADATION; BYPRODUCTS; CARBOXYLIC ACIDS; CATALYTIC OXIDATION; CLAY; EFFLUENTS; HYDROGEN; HYDROGEN PEROXIDE; KETONES; ORGANIC ACIDS; PHENOLS;

ALUMINUM;

BIOLOGICAL PROPERTY; CATALYST; EFFLUENT; HYDROGEN PEROXIDE; OXIDATION; TESTING; TOXICITY; WATER;

EID: 77954736349     PISSN: 01496395     EISSN: 15205754     Source Type: Journal    
DOI: 10.1080/01496395.2010.487710     Document Type: Article

References (29)

1. Perathoner, S.; Centi, G. (2005) Wet hydrogen peroxide catalytic oxidation (WHPCO) of organic waste in agro-food and industrial streams. Top. Catal., 33: 207-224.
2. 2 of carboxylic acids on homogeneous and heterogeneous Fenton-type catalysts. Catal. Today, 55: 62-69.
3. Edwards, J.O.; Curci, R. (1992) Catalytic Oxidations with Hydrogen Peroxide as Oxidants, Strukul, G., ed.; Kluwer: Dordrecht, The Netherlands, 97.
4. Fajerwerg, K.; Debellefontaine, H. (1996) Wet oxidation of phenol by hydrogen peroxide using heterogeneous catalysis Fe-ZSM-5: A promising catalyst. Appl. Catal. B: Environ., 10: L229-L235.
5. Zazo, J.A.; Casas, J.A.; Mohedano, A.F.; Rodríguez, J.J. (2006) Catalytic wet peroxide oxidation of phenol with a Fe=active carbon catalyst. Appl. Catal. B: Environ., 65: 261-268.
6. Doff, D.H.; Gangas, N.H.; Allan, J.E.; Coey, J.M. (1988) Preparation and characterization of iron-oxide pillared montmorillonite. Clay Miner., 23: 367-377.
7. Guélou, E.; Barrault, J.; Fournier, J.; Tatibouët, J.M. (2003) Active iron species in the catalytic wet peroxide oxidation of phenol over pillared clays containing iron. Appl. Catal. B: Environ., 44 (1): 1-8.
8. Molina, C.B.; Casas, J.A.; Zazo, J.A.; Rodríguez, J.J. (2006) A comparison of Al-Fe and Zr-Fe pillared clays for catalytic wet peroxide oxidation. Chem. Eng. J., 118: 29-35.
9. Barrault, J.; Abdellaoui, M.; Bouchoule, C.; Majesté, A.; Tatibouët, J.M.; Louloudi, A.; Papayannakos, N.; Gangas, N.H. (2000) Catalytic wet peroxide oxidation over mixed (Al-Fe) pillared clays. Appl. Catal. B: Environ., 27: L225-L230.
10. Letaïef, S.; Casal, B.; Aranda, P.; Martín-Luengo, M.A.; Ruiz-Hitzky, E. (2003) Fe-containing pillared clays as catalysts for phenol hydroxilation. Appl. Clay Sci., 22: 263-277.
11. Carriazo, J.G.; Guelou, E.; Barrault, J.; Tatibouet, J.M.; Moreno, S. (2003) Catalytic wet peroxide oxidation of phenol over Al-Cu or Al-Fe modified clays. Appl. Clay Sci., 22: 303-308.
12. Timofeeva, M.N.; Khankhasaeva, S.Ts.; Badmaeva, S.V.; Chuvilin, A.L.; Burgina, E.B.; Ayupov, A.B.; Panchenko, V.N.; Kulikova, A.V. (2005) Synthesis, characterization and catalytic application for wet oxidation of phenol of iron-containing clays. Appl. Catal. B: Environ., 59 (3-4): 243-248.
13. Pinnavaia, T.J.; Tzou, M.; Landau, S.D.; Raythatha, R.H. (1984) On the pillaring and delamination of smectite clay catalysts by polioxocations of Al. J. Mol. Catal., 27: 195-212.
14. 2. Microp. and Mesop. Mat., 107: 46-57.
15. Caudo, S.; Centi, G.; Genovese, C.; Perathoner, S. (2007) Copper and iron-pillared clay catalysts for the WHPCO of model and real wastewater streams from olive oil milling production. App. Catal. B: Environ., 70: 437-446.
16. Giordano, G.; Perathoner, S.; Centi, G.; De Rosa, S.; Granato, T.; Katovic, A.; Siciliano, A.; Tagarelli, A.; Tripicchio, F. (2007) Wet hydrogen peroxide catalytic oxidation of olive oil mill wastewaters using Cu-zeolite and Cupillared clay catalysts. Catal. Today, 124 (3-4): 240-246.
17. Najjar, W.; Azabou, S.; Sayadi, S.; Ghorbel, A. (2007) Catalytic wet peroxide photooxidation of phenolic olive oil mill wastewater contaminants. Appl. Catal. B: Environ., 74 (1-2): 11-18.
18. Chamarro, E.; Marco, A.; Esplugas, S. (2001) Use of Fenton reagent to improve organic chemical biodegradability. Water Res., 35: 1047-1051.
19. Mantzavinos, D.; Psillakis, E. (2004) Review: Enhancement of biodegradability of industrial wastewaters by chemical oxidation pre-treatment. J. Chem. Technol. Biotechnol., 79: 431-454.
20. Mantzavinos, D.; Kalogerakis, N. (2005) Treatment of olive mill effluents Part I. Organic matter degradation by chemical and biological processes an overview. Environ. Internat., 31: 289-295.
21. Benitez, F.J.; Beltrán-Heredia, J.; Torregrosa, J.; Acero, J.L. (1999) Treatment of olive mill wastewaters by ozonation, aerobic degradation and the combination of both treatments. J. Chem. Technol. Biotechnol., 74: 639-646.
22. Beltrán-Heredia, J.; Torregrosa, J.; García, J.; Domínguez, J.R.; Tierno, J.C. (2001) Degradation of olive mill wastewater by the combination of Fenton's reagent and ozonation processes with an aerobic biological treatment. Water Sci. Technol., 44: 103-108.
23. Ledakowicz, S.; Gonera, M. (1999) Optimization of oxidants dose for combined chemical and biological treatment of textile wastewater. Water Res., 33: 2511-2516.
24. Gogate, P.R.; Pandit, A.B. (2004) A review of imperative technologies for wastewater treatment II: Hybrid methods. Advances in Environm. Res., 8: 553-597.
25. 2 solar photo-assisted processes. Ecotox. And Environ. Safety, 69 (3): 546-555.
26. Cañizares, P.; Valverde, J.L.; Sun-Kou, M.R.; Molina, C.B. (1999) Synthesis and characterization of PILCs with single and mixed oxide pillars prepared from two different bentonites. A comparative study. Microp. Mesop. Mater., 29: 267-281.
27. 2 of carboxylic acids on homogeneous and heterogeneous Fenton-type catalysts. Catal. Today, 55: 61-69.
28. Tatibouët, J.-M.; Guélou, E.; Fournier, J. (2005) Catalytic oxidation of phenol by hydrogen peroxide over a pillared clay containing iron. Active species and pH effect. Topics in Catal., 33: 225-232.
29. APHA=AWWA=WPCF. (1998). Standard Methods for Examination of Water and Wastewater, 20th American Public Health Association Ed.; Washington, DC.