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Evidence that chain formation occurred in solution, asopposed to being caused by solvent evaporation, wasobtained in light-scattering and UV-visible spectroscopyexperiments, as well as in the control experimentsconducted at different solvent evaporation rates and ondifferent substrates.
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Evidence that chain formation occurred in solution, asopposed to being caused by solvent evaporation, wasobtained in light-scattering and UV-visible spectroscopyexperiments, as well as in the control experimentsconducted at different solvent evaporation rates and ondifferent substrates.
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In the control experiments, the time of bond formation wasmarkedly reduced for the self-assembly of cylindrical Aunanorods end-terminated with thiolated PS, which did notrequire specific orientation of the NR during bond formation.
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In the control experiments, the time of bond formation wasmarkedly reduced for the self-assembly of cylindrical Aunanorods end-terminated with thiolated PS, which did notrequire specific orientation of the NR during bond formation.
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We thank the National Science and Engineering ResearchCouncil of Canada (under Discovery program and CanadaResearch Chair program) for financial support. M.R.acknowledges financial support from the NSF undergrants CHE-0911588, DMR-0907515, and CBET-0609087 and the NIH under grant 1-R01-HL077546-03A2. The authors are grateful to Y. Chen and G. Wufor their contribution in image analysis.
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We thank the National Science and Engineering ResearchCouncil of Canada (under Discovery program and CanadaResearch Chair program) for financial support. M.R.acknowledges financial support from the NSF undergrants CHE-0911588, DMR-0907515, and CBET-0609087 and the NIH under grant 1-R01-HL077546-03A2. The authors are grateful to Y. Chen and G. Wufor their contribution in image analysis.
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