메뉴 건너뛰기




Volumn 82, Issue 7, 2010, Pages 1461-1469

Highly enantioselective isomerization of primary allylic alcohols catalyzed by (P,N)-iridium complexes

Author keywords

(P,N) ligands; Allylic alcohols; Enantioselective catalysis; Iridium; Isomerization

Indexed keywords


EID: 77954508247     PISSN: 00334545     EISSN: 13653075     Source Type: Journal    
DOI: 10.1351/PAC-CON-09-09-10     Document Type: Article
Times cited : (14)

References (29)
  • 1
    • 0001239075 scopus 로고    scopus 로고
    • E. N. Jacobsen, A. Pfaltz, H. Yamamoto (Eds.), Chap. 23, Springer, Berlin
    • S. Akutagawa. Comprehensive Asymmetric Catalysis, Vol.2, E. N. Jacobsen, A. Pfaltz, H. Yamamoto (Eds.), Chap. 23, Springer, Berlin (1999).
    • (1999) Comprehensive Asymmetric Catalysis , vol.2
    • Akutagawa, S.1
  • 3
    • 0141554035 scopus 로고    scopus 로고
    • E. N. Jacobsen, A. Pfaltz, H. Yamamoto (Eds.), Chap. 41.4, Springer, Berlin
    • S. Akutagawa. Comprehensive Asymmetric Catalysis, Vol.3, E. N. Jacobsen, A. Pfaltz, H. Yamamoto (Eds.), Chap. 41.4, Springer, Berlin (1999).
    • (1999) Comprehensive Asymmetric Catalysis , vol.3
    • Akutagawa, S.1
  • 6
    • 44349092408 scopus 로고    scopus 로고
    • for Rh-catalyzed asymmetric isomerization of primary allylic alcohols
    • (c) V. Cadierno, P. Crochet, J. Gimeno. Synlett 8, 1105 (2008); for Rh-catalyzed asymmetric isomerization of primary allylic alcohols
    • (2008) Synlett , vol.8 , pp. 1105
    • Cadierno, V.1    Crochet, P.2    Gimeno, J.3
  • 11
    • 33744972845 scopus 로고    scopus 로고
    • For Ru-catalyzed asymmetric isomerization of secondary allylic alcohols
    • (h) F. Boeda, P. Mosset, C. Crévisy. Tetrahedron Lett. 47, 5021 (2006); For Ru-catalyzed asymmetric isomerization of secondary allylic alcohols.
    • (2006) Tetrahedron Lett. , vol.47 , pp. 5021
    • Boeda, F.1    Mosset, P.2    Crévisy, C.3
  • 28
    • 77954469807 scopus 로고    scopus 로고
    • CCDC-724940 These data can be obtained free of charge from The Cambridge Crystallographic Data Centre via
    • CCDC-724940. These data can be obtained free of charge from The Cambridge Crystallographic Data Centre via 〈www.ccdc.cam.ac.uk/data-request/ cif〉.
  • 29
    • 2142754143 scopus 로고
    • The tautomerization is presumably taking place outside the catalytic cycle, since attempts to isomerizes 2,3-disubstituted allylic alcohols gave the corresponding α-substituted aldehydes in racemic form. The tautomerization is the enantio-determining step for 2,3-disubstituted allylic alcohols. If the metal is not involved or if background tautomerization is too fast, racemic product is expected. For a relevant discussion, see: S. Bergens, B. Bosnich. J. Am. Chem. Soc. 113, 958 (1991).
    • (1991) J. Am. Chem. Soc. , vol.113 , pp. 958
    • Bergens, S.1    Bosnich, B.2


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.