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CCDC-724940 These data can be obtained free of charge from The Cambridge Crystallographic Data Centre via
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CCDC-724940. These data can be obtained free of charge from The Cambridge Crystallographic Data Centre via 〈www.ccdc.cam.ac.uk/data-request/ cif〉.
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The tautomerization is presumably taking place outside the catalytic cycle, since attempts to isomerizes 2,3-disubstituted allylic alcohols gave the corresponding α-substituted aldehydes in racemic form. The tautomerization is the enantio-determining step for 2,3-disubstituted allylic alcohols. If the metal is not involved or if background tautomerization is too fast, racemic product is expected. For a relevant discussion, see: S. Bergens, B. Bosnich. J. Am. Chem. Soc. 113, 958 (1991).
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