Effect of temperature and solvent composition on the intrinsic viscosity of poly(ethylene glycol) in water-ethanol solutions

Journal of Chemical and Engineering Data

Volumn 55, Issue 7, 2010, Pages 2537-2541

  Mehrdad, Abbas ^a   Akbarzadeh, Reza ^a  

^a UNIVERSITY OF TABRIZ   (Iran)

Author keywords

[No Author keywords available]

Indexed keywords

EFFECT OF TEMPERATURE; EXPANSION FACTORS; HEAT OF DILUTION; INTRINSIC VISCOSITY; POLYMER CHAINS; POLYMER-SOLVENT INTERACTIONS; SOLVENT COMPOSITION; TEMPERATURE DEPENDENCE; THERMODYNAMIC PARAMETER; VIRIAL COEFFICIENT; WATER ETHANOL MIXTURES; WATER-ETHANOL;

EQUATIONS OF STATE; ETHANOL; ETHYLENE; ETHYLENE GLYCOL; POLYETHYLENE GLYCOLS; POLYETHYLENE OXIDES; POLYMERS; TEMPERATURE; THERMODYNAMICS; VISCOMETERS; VISCOSITY;

ORGANIC SOLVENTS;

EID: 77954493934     PISSN: 00219568     EISSN: 15205134     Source Type: Journal    
DOI: 10.1021/je900895c     Document Type: Article

References (17)

1. Song, Y.; Mathias, P. M.; Tremblay, D.; Chen, C. Liquid viscosity model for polymer solutions and mixtures Ind. Eng. Chem. Res. 2003, 42, 2415-2422
2. Novak, L. T.; Chen, C.; Song, Y. Segment-based Eyring-NRTL viscosity model for mixtures containing polymers Ind. Eng. Chem. Res. 2004, 43, 6231-6237
3. Rushing, T. S.; Hester, R. D. Intrinsic viscosity dependence on polymer molecular weight and fluid temperature J. Appl. Polym. Sci. 2003, 89, 2831-2835
4. Kirincčič, S.; Klofutar, C. Viscosity of aqueous solutions of polyethylene glycols at 298.15 K Fluid Phase Equilib. 1999, 155, 311-325
5. Hasse, H.; Kany, H.-P.; Tintinger, R.; Maurer, G. Osmotic virial coefficients of aqueous poly(ethylene glycol) from laser-light scattering and isopiestic measurements Macromolecules 1995, 28, 3540-3552
6. Woodley, D. M.; Dam, C.; Lam, H.; LeCave, M.; Devanand, K.; Selser, J. C. Draining and long-ranged interactions in the Poly(ethylene oxide)/water good solvent system Macromolecules 1992, 25, 5283-5286
7. Boucher, E. A.; Hines, P. M. Properties of aqueous salt solutions of poly(ethylene oxide): thermodynamic quantities based on viscosity and other measurements J. Polym. Sci. Polym. Phys. 1978, 16, 501-511
8. + ions on the intrinsic viscosity of poly(ethylene oxide) in aqueous solutions Fluid Phase Equilib. 2008, 268, 109-113
9. Briscoe, B.; Luckham, P.; Zhu, S. Rheological properties of poly(ethylene oxide) aqueous solutions J. Appl. Polym. Sci. 1998, 70, 419-429
10. Hammouda, B.; Ho, D. L. Insight into chain dimensions in PEO/water solutions J. Polym. Sci. Polym. Phys. 2007, 45, 2196-2200
11. Branca, C.; Magazu, S.; Maisano, G.; Migliardo, F.; Migliardo, P.; Romeo, G. Study of conformational properties of poly(ethylene oxide) by SANS and PCS techniques Phys. Scr. 2003, 67, 551-554
12. Torres, M. F.; Muëller, A. J.; Sáez, A. E. Effect of ethanol addition on the elongational flow behavior of aqueous solutions of poly(ethylene oxide) Polym. Bull. 2002, 47, 475-483
13. Huggins, M. L. The viscosity of dilute solutions of long-chain molecules. IV. Dependence on concentration J. Am. Chem. Soc. 1942, 64, 2716-2718
14. Flory, P. J. Principles of polymer chemistry; Cornell University Press: London, 1953.
15. Flory, P. J.; Fox, T. G., Jr. Treatment of intrinsic viscosities J. Am. Chem. Soc. 1951, 73, 1904-1908
16. Teraoka, I. Polymer solutions: An Introduction to Physical Properties; John Wiley and Sons, Inc.: New York, 2002.
17. Sun, S. F. Physical chemistry of macromolecules: Basic principles and issues; John Wiley and Sons, Inc.: New York, 1994.