Enantioselective total synthesis of idesolide via NaHCO3- promoted dimerization

Tetrahedron

Volumn 66, Issue 27-28, 2010, Pages 4965-4969

  Nagasawa, Tomohiro ^a   Shimada, Naoyuki ^a   Torihata, Munefumi ^a   Kuwahara, Shigefumi ^a  

^a TOHOKU UNIVERSITY   (Japan)

Author keywords

Antiinflammatory; Dimerization; Idesolide; Spiro compounds; Total synthesis

Indexed keywords

1 (HYDROXYMETHYL) 7 OXABICYCLO[4.1.0]HEPTAN 2 ONE; ALCOHOL; BICARBONATE; DIMETHYL 3A,6,7,7A TETRAHYDRO 2',7A DIHYDROXYSPIRO[1,3 BENZODIOXOLE 2,1' [3]CYCLOHEXENE] 2'3A DICARBOXYLATE; IDESOLIDE; METHYL 1 HYDROXY 6 OXO 2 CYCLOHEXENE 1 CARBOXYLATE; METHYL 1,2 DIHYDROXYCYCLOHEXANE 1 CARBOXYLATE; METHYL 2 (TERT BUTYLDIMETHYLSILYLOXY) 7 OXABICYCLO[4.1.0]HEPTANE 1 CARBOXYLATE; METHYL 2 HYDROXY 7 OXABICYCLO[4.1.0]HEPTANE 1 CARBOXYLATE; METHYL 2 OXO 7 OXABICYCLO[4.1.0 OXABICYCLO[4.1.0]HEPTANE 1 CARBOXYLATE; METHYL 6 (TERT BUTYLDIMETHYLSILYLOXY) 1 HYDROXY 2 CYCLOHEXENE 1 CARBOXYLIC ACID; MONOMER; UNCLASSIFIED DRUG;

ARTICLE; CATALYST; CHEMICAL STRUCTURE; CHIRALITY; DIMERIZATION; ENANTIOSELECTIVITY; EPOXIDATION; PRIORITY JOURNAL; SYNTHESIS;

EID: 77954349011     PISSN: 00404020     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.tet.2010.05.034     Document Type: Article

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