Theoretical investigation of ethane dehydrogenation on cationic Zn species in ZSM-5 zeolites - The second Al center in vicinity of the cation is essential for the accomplishment of the complete catalytic cycle

Catalysis Today

Volumn 152, Issue 1-4, 2010, Pages 78-87

  Aleksandrov, Hristiyan A ^a   Vayssilov, Georgi N ^a  

^a UNIVERSITY OF SOFIA   (Bulgaria)

Author keywords

Alkane dehydrogenation; Entropy; Free energy; Paired Al sites; Zeolite; Zinc

Indexed keywords

ACTIVATION ENERGY; CHEMICAL ACTIVATION; DEHYDROGENATION; ENTROPY; ETHANE; FREE ENERGY; ION EXCHANGE; POSITIVE IONS; REACTION INTERMEDIATES; ZEOLITES; ZINC; ZINC COMPOUNDS;

ACTIVATION BARRIERS; ALKANE DEHYDROGENATIONS; CATALYTIC CYCLES; ETHANE DEHYDROGENATION; FREE ENERGY OF ACTIVATIONS; HIGH-ACTIVATION; PAIRED AL SITES; THEORETICAL INVESTIGATIONS;

ALUMINUM;

EID: 77954310958     PISSN: 09205861     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.cattod.2010.01.001     Document Type: Article

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