Inter-and intramolecular isocarbon couplings of cobalt-complexed propargyl radicals: Challenging the consensus

Tetrahedron

Volumn 66, Issue 29, 2010, Pages 5321-5328

  Melikyan, Gagik G ^a   Spencer, Ryan ^a  

^a CALIFORNIA STATE UNIVERSITY   (United States)

Author keywords

Cobalt; Diastereoselectivity; Propargylradical; Radical coupling

Indexed keywords

5,6 DIARYL 3,7 DECADIYNE DERIVATIVE; ALCOHOL DERIVATIVE; ALKYL GROUP; ALKYNE DERIVATIVE; AROMATIC COMPOUND; AROMATIC HYDROCARBON SUBSTITUENT; CARBON; DEXTRO LEVO 5,6 DI(3',4' DIMETHOXYPHENYL) 3,7 DECADIYNE; DEXTRO LEVO 5,6 DI(4' METHOXYPHENYL) 3,7 DECADIYNE; GAMMA ALKYL; GAMMA ETHYL; GAMMA PHENYL; ISOCARBON; MESO 5,6 DI(4' ISOPROPYLPHENYL) 3,7 DECADIYNE; MESO 5,6 DIPHENYL) 3,7 DECADIYNE; MESO MU ETA 2 (5,6 DIPHENYL 3,7 DECADIYNE)BIS(DICOBALT HEXACARBONYL); MESO MU ETA 2 [5,6 DI(3',4' DIMETHOXYPHENYL) 3,7 DECADIYNE]BIS(DICOBALTHEXACARBONYL); MESO MU ETA 2 [5,6 DI(4' ISOPROPYLPHENYL) 3,7 DECADIYNE]BIS(DICOBALTHEXACARBONYL); MESO MU ETA 2 [5,6 DI(4' METHOXYPHENYL) 3,7 DECADIYNE]BIS(DICOBALTHEXACARBONYL); MU ETA 2 (1 PHENYL 2 PENTYN 1 OL)DICOBALTHEXACARBONYL; MU ETA 2 [1 (3',4' DIMETHOXYPHENYL) 2 PENTYN 1 OL]DICOBALT HEXACARBONYL; MU ETA 2 [1 (4' ISOPROPYLPHENYL) 2 PENTYN 1 OL]DICOBALT HEXACARBONYL; MU ETA 2 [1 (4' METHOXYPHENYL) 2 PENTYN 1 OL]DICOBALT HEXACARBONYL; PHENYL GROUP; PROPARGYLALCOHOL; UNCLASSIFIED DRUG;

ARTICLE; CHEMICAL REACTION; CHEMICAL STRUCTURE; CYCLIZATION; PRIORITY JOURNAL; STEREOCHEMISTRY; SUBSTITUTION REACTION;

EID: 77954310356     PISSN: 00404020     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.tet.2010.05.011     Document Type: Article

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