Ultrafast photodriven intramolecular electron transfer from a zinc porphyrin to a readily reduced diiron hydrogenase model complex

Journal of the American Chemical Society

Volumn 132, Issue 26, 2010, Pages 8813-8815

  Samuel, Amanda P S ^a   Co, Dick T ^a   Stern, Charlotte L ^a   Wasielewski, Michael R ^a  

^a NORTHWESTERN UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ACIDS; CATALYSTS; CHROMOPHORES; DYES; ELECTRON TRANSITIONS; HYDROCARBONS; NAPHTHALENE; PHOTOEXCITATION; PORPHYRINS; PULSED LASER APPLICATIONS; SPECTROELECTROCHEMISTRY; TOLUENE; ZINC;

ACID CONCENTRATIONS; ACTIVE SITE; CHARGE RECOMBINATIONS; CHARGE SEPARATIONS; CYCLIC VOLTAMMOGRAMS; DIIRON COMPLEX; DITHIOLATES; DONOR-ACCEPTOR DYADS; ELECTRON TRANSFER; ELECTRONWITHDRAWING; FS LASER PULSE; HYDROGENASES; INTRA-MOLECULAR ELECTRON TRANSFER; MODEL COMPLEXES; PROTON REDUCTION; REDUCTION WAVE; SPECTROELECTROCHEMICAL MEASUREMENTS; SPECTROSCOPIC CHARACTERIZATION; TRANSIENT ABSORPTION SPECTRA; TRIFLIC ACIDS; TRIFLUOROACETIC ACIDS; ULTRA-FAST; VISIBLE LIGHT; ZINC PORPHYRINS; ZN PORPHYRIN; [FEFE]HYDROGENASES;

ZINC COMPOUNDS;

FERROUS ION; HYDROGEN; HYDROGENASE; PORPHYRIN; PROTON; ZINC; BIOMIMETIC MATERIAL; IRON HYDROGENASE; IRON SULFUR PROTEIN; METALLOPORPHYRIN; ZINC HEMATOPORPHYRIN;

ARTICLE; CATALYST; ELECTRON; ELECTRON TRANSPORT; MOLECULAR SYSTEMATICS; PHOTOCATALYSIS; PHOTOCHEMISTRY; CHEMICAL STRUCTURE; CHEMISTRY; CONFORMATION; ELECTROCHEMISTRY; KINETICS; METABOLISM; SPECTROSCOPY;

BIOMIMETIC MATERIALS; ELECTROCHEMISTRY; ELECTRON TRANSPORT; HYDROGENASE; IRON-SULFUR PROTEINS; KINETICS; METALLOPORPHYRINS; MODELS, MOLECULAR; MOLECULAR CONFORMATION; PHOTOCHEMICAL PROCESSES; SPECTRUM ANALYSIS;

EID: 77954296694     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja100016v     Document Type: Article

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