A novel three dimensional 3d-4f heterometallic coordination framework with 2, 2′-bipyridine-3-carboxylate and oxalate ligands

Inorganic Chemistry Communications

Volumn 13, Issue 8, 2010, Pages 924-928

  Tang, Yun Zhi ^a   Wen, He Rui ^a   Cao, Zan ^a   Wang, Xiao Wei ^a   Huang, Shuai ^a   Yu, Chang Lin ^a  

^a JIANGXI UNIVERSITY OF SCIENCE AND TECHNOLOGY   (China)

Author keywords

Copper complex; Heterometallic polymer; Hydrothermal synthesis; Neodymium complex

Indexed keywords

EID: 77953871113     PISSN: 13877003     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.inoche.2010.04.027     Document Type: Article

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22. 2 (0.079 g, 0.3 mmol), and HL (0.116 g, 0.6 mmol) and oxalic acid (0.107, 1.2 mmol) was dissolved into a mixed solution of absolute ethanol (2 mL) and distilled water (10 mL). The resulting solution was stirred for about 1 h at room temperature, sealed in a 23-mL Teflon-lined stainless steel autoclave, and heated at 140 °C for 3 days under autogenously pressure, then; the reaction system was gradually cooled to room temperature. Blue crystals of 1 suitable for single-crystal X-ray diffraction analysis were collected from the final reaction system by filtration, washed several times with distilled water, and dried in air at ambient temperature. Yield: 45% based on Cu. Anal. Calcd for 1: C, 26.74; H, 2.52, N, 4.16. Found: C, 26.73; H, 2.50; N, 4.17.
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