Characterization of vermiculite by XRD and spectroscopic techniques

Earth Sciences Research Journal

Volumn 13, Issue 2, 2009, Pages 108-118

  Campos, A ^a   Moreno, S ^a   Molina, R ^a  

^a UNIVERSIDAD NACIONAL DE COLOMBIA   (Colombia)

Author keywords

Layer charge; Structural formula; Vermiculite

Indexed keywords

CATALYSIS; CRYSTAL STRUCTURE; MINERAL; NUCLEAR MAGNETIC RESONANCE; PILLARED CLAY; SCANNING ELECTRON MICROSCOPY; SPECTROSCOPY; VERMICULITE; X-RAY DIFFRACTION; X-RAY FLUORESCENCE;

COLOMBIA; MAGDALENA; SANTA MARTA;

EID: 77953780963     PISSN: 17946190     EISSN: None     Source Type: Journal    
DOI: None     Document Type: Article

References (40)

1. Bensimon Y., Deroide B., Dijoux F., Martineau M. (2000). Nature and thermal stability of paramagnetic defects in natural clay: a study by electron spin resonance. Journal of Physics and Chemistry of Solids 61, 1623-1632.
2. Brown B. (1961) The X-Ray identification and crystal structures of clay minerals. Mineralogical Society; London.
3. Campos A., Moreno S., Molina R. (2005). Acidez e hidroisomerización de heptano en una vermiculita colombiana modificada con aluminio. Revista Colombiana de Química. 34, 79-92.
4. Campos A., Gagea B., Moreno S., Jacobs P., Molina R. (2007). Hydroisomerization of decane on Pt/Al,Ce-pillared vermiculites. Studies in Surface Science and Catalysis. 170, 1405-1409
5. Campos A., Gagea B., Moreno S., Jacobs P., Molina R. (2008). Decane hydroconversion with Al-Zr, Al-Hf, Al-Ce-pillared vermiculites. Applied Catalysis A. 345, 112-118.
6. Campos A., Moreno S., Molina R. (2008). Relationship between hydrothermal treatment parameters as a strategy to reduce layer charge in vermiculite, and its catalytic behavior. Catalysis Today. 133-135, 351-356.
7. Carriazo J., Guélou E., Barrault J., Tatibouët J., Molina R., Moreno S., 2005. Synthesis of pillared clays containing Al, Al-Fe or Al-Ce-Fe from a bentonite: Characterization and catalytic activity.Catalysis Today 107-108, 126-132.
8. Chapman H. (1965). Cation exchange capacity. In: Black C, Evans D, White J, Ensminger L, Clark E, editors. Methods of Soil Analysis (Agronomy 9), American Society of Agronomy.
9. Chung H., Sang-Won C., Yong-Sik O., Jinho J. (2004). EPR characterization of the catalytic activity of clays for PCE removal by gamma-radiation induced by acid and thermal treatments. Chemosphere 57, 1383-1387.
10. Cristiano D., Campos A., Molina R. (2005). Charge reduction in a vermiculite by acid and hydrothermal methods: A comparative study. Journal of Physical Chemistry B 109, 19026-19033.
11. del Rey-Pe ́rez-Caballero F., Poncelet G. (2000). Microporous 18 Å Al-pillared vermiculites: preparation and characterization. Microporous and Mesoporous Materials. 37, 313-327.
12. del Rey-Pérez-Caballero F., Sa ́nchez M., Poncelet G. (2000). Hydroisomerization of octane on Pt/Al-pillared vermiculite, and comparison with zeolites. Studies in Surface Science and Catalysis. 130, 2417-2422.
13. Dixon J., Weed S. (1989). Minerals in soil environments. Second edition. United States.
14. Fagel N., Robert C., Preda M., Thorez J. (2001). Smectite composition as a tracer of deep circulation: the case of the Northern North Atlantic. Marine Geology. 172, 309-330.
15. Gates W., Stucki J., Kirkpatrick R. (1996). Structural properties of reduced Upton montmorillonite. Physics and Chemistry of Minerals 2, 535-541.
16. Gordeeva L., Moroz E., Rudina N., Aristov Y. (2002). Formation of porous vermiculite structure in the course of swelling. Russian Journal of Applied Chemistry. 75, 357-361.
17. Guggenheim S., Adams J., Bain B., Bergaya F., Brigatti M., Drits V., Formoso M., Galán E., Kogure T., Stanjek H. (2006). Summary of recommendations of nomenclature committees relevant to clay mineralogy: report of the association international pour l'etude des argiles (AIPEA) nomenclature committee for 2006. Clays and Clay Minerals. 54, 761-772.
18. Hernández W., Centeno M., Odriozola J., Moreno S., Molina R. (2007). Acidity characterization of a titanium and sulfate modified vermiculite. Materials Reserach Bulletin. 43, 1630-1640.
19. Kessissoglou D. (1999). Homoand mixed-valence EPR -active trinuclear manganese complexes. Coordination Chemistry Review. 185, 837-858.
20. Kishk F., Barshad I. (1969). The morphology of vermiculite clay particles as affected by their genesis. American Mineralogist. 54, 849-857.
21. Klinowski J. (1999). Solid-state NMR studies of molecular sieve catalysts. Chemical Reviews. 91, 1459-1479.
22. Laird D. (1999). Layer Charge Influences on the Hydration of Expandable 2:1 Phyllosilicates. Clays and Clay Minerals. 47, 630-636.
23. Malla P., Douglas L. (1987). Layer charge properties of smectites and vermiculites: tetrahedral vs. Octahedral. Soil Science Society of America Journal. 51, 1362-1366.
24. MacEwan, D. and Wilson, M. (1980). Interlayer and intercalation complexes of clay minerals. Pp. 197-248 in: Crystal Structures of Clay Minerals and Their X-ray Identification (G.W. Brindley and G. Brown, editors). Mineralogical Society, London.
25. McBride M., Pinnavaia T., Mortland M. (1975). Exchange Ion Positions in Smectite: Effects on Electron Spin Resonance of Structural Iron. Clays and Clay Minerals. 23,162-164.
26. Moreno S., Gutiérrez E., Alvarez A., Papayannakos N., Poncelet G. (1997). Al-pillared clays: from lab syntheses to pilot scale production characterization and catalytic properties. Applied Catalysis A 165, 103-114.
27. Moore D., Reynolds J. (1997). X-ray diffraction and the identification and analysis of clay minerals. Second edition. Oxford university press.
28. Pérez L., Balek V., Potayo J., Pérez J., Subrt J., Bountsewa I., Beckman I., Málek Z. (2003). Study of natural and ion exchanged vermiculite by emanation thermal analysis, TG, DTA and XRD. Journal of Thermal Analysis and Calorimetry. 71, 715-726.
29. 4 -vermiculite from Santa Olalla (Huelva, Spain) and its relation to the metal ion distribution in the octahedral sheet Physics and Chemistry of Minerals 31, 415-420.
30. Schoonheydt R., Pinnavaia T., Lagaly G., Gangas N. (1999). Pillared clays and pillared layered solids. Pure Applied Chemistry. 71: 2367-2371.
31. Slade P. (1976). Telleria M., Radoslovic W. The estructures of ornithine-vermiculite and 6-aminohexanoic acid-vermiculite. Clays and Clay Minerals 24, 134-141.
32. Suvorov D., Skurikhin V. (2003). Vermiculite: A promising material for high-temperature heat insulators. Refractories and Industrial Ceramics. 44, 186-193.
33. Stefanis A., Tomlinson A. (2006). Towards designing pillared clays for catalysis. Catalysis Today 114, 126-141.
34. Thorez J. (1976). Practical identification of clay minerals. G. Lelotte (Ed). Dison, Belgique.
35. Timofeeva M., Khankhasaeva S., Badmaeva S., Chuvilin A., Burgina E., Ayupov A., Panchenko V., Kulikova A. (2005). Synthesis, characterization and catalytic application for wet oxidation of phenol of iron-containing clays. Applied Catalysis B. 59: 243-248.
36. Tunega D., Lischka H. (2003). Effect of the Si/Al ordering on structural parameters ad the energetic stabilization of vermiculites a theoretical study. Physics and Chemistry of Minerals 30, 517-522.
37. Tusjar N., Zabukovec N., Vlaic G., Arcjon D., Daneu N., Kaucjicj V. (2005). Local environment of manganese incorporated in mesoporous MCM-41. Microporous and Mesoporous Materials. 82, 129-136.
38. Weaver C. (1958). Effects of geologic significance of potassium "fixation" by expandable clay minerals derived from muscovite, biotite, chlorite and volcanic material. American Mineralogist. 43, 839-861.
39. Wiewióra A., Perez-Rodriguez L., Perez-Maqueda L., Drapala J. (2003). Particle size distribution in sonicated high ad low charge vermiculites. Applied Clay Science. 24, 51-58.
40. Wilson M. (1969). Mineralogy: Spectroscopy and Chemical Determinative Methods. Champan & Hall ed; London.