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The analysis of rhodium was carried out by gravimetric method in which the rhodium metal complex was converted to metallic rhodium by following steps: The complex was first decomposed by boiling in conc. H2SO4/HNO3. It was then allowed to react with thiourea when black rhodium sulfide was formed which on ignititon gives the oxide. Lastly, the oxide was quantitively reduced by H2 gas (at elevated temperature) to metallic rhodium and weighted as such
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