메뉴 건너뛰기




Volumn 326, Issue 1-2, 2010, Pages 21-28

Influence of phosphorus and oxygen donor diphosphine ligands on the reactivity of rhodium(I) carbonyl complexes

Author keywords

Carbonyl complexes; Carbonylation; Diphosphine; Oxygen donor; Rhodium

Indexed keywords

CARBONYL COMPLEXES; CATALYTIC ACTIVITY; DIPHOSPHINE LIGAND; DIPHOSPHINES; ELECTROPHILES; ELEMENTAL ANALYSIS; EXPERIMENTAL CONDITIONS; KINETIC DATA; MOLAR EQUIVALENT; OXIDATIVE ADDITIONS; OXYGEN DONOR; OXYGEN DONORS; PSEUDO-FIRST-ORDER REACTION; SINGLE CRYSTAL X-RAY DIFFRACTION; TURNOVER NUMBER; XANTPHOS;

EID: 77953729072     PISSN: 13811169     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.molcata.2010.05.008     Document Type: Article
Times cited : (24)

References (36)
  • 29
    • 77953711128 scopus 로고    scopus 로고
    • The analysis of rhodium was carried out by gravimetric method in which the rhodium metal complex was converted to metallic rhodium by following steps: The complex was first decomposed by boiling in conc. H2SO4/HNO3. It was then allowed to react with thiourea when black rhodium sulfide was formed which on ignititon gives the oxide. Lastly, the oxide was quantitively reduced by H2 gas (at elevated temperature) to metallic rhodium and weighted as such
    • 2 gas (at elevated temperature) to metallic rhodium and weighted as such.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.