Convenient synthesis of dicyclohexyldithiophosphinic acid

Synthetic Communications

Volumn 40, Issue 14, 2010, Pages 2036-2041

  Jia, Cai ^a   Yu, Fengxian ^a,b   Wang, Fang ^a   Wu, Wangsuo ^b   Chen, Jing ^a  

^a TSINGHUA UNIVERSITY   (China)

^b LANZHOU UNIVERSITY   (China)

Author keywords

Actinides lanthanides separation; Dithiophosphinic acid; Synthesis

Indexed keywords

DICYCLOHEXYLDITHIOPHOSPHINIC ACID; PHOSPHINIC ACID DERIVATIVE; UNCLASSIFIED DRUG;

ARTICLE; CHEMICAL BOND; GRIGNARD REACTION; PROTON NUCLEAR MAGNETIC RESONANCE; SYNTHESIS;

EID: 77953698036     PISSN: 00397911     EISSN: 15322432     Source Type: Journal    
DOI: 10.1080/00397910903029909     Document Type: Article

References (21)

1. (a)Craig, W. G.; Miller, C. O. Esters of di(organo)-phosphinodithioic acids. US Patent 2881200, 1959;
2. (b)Schrader, G. Dithiophosphinic acid esters. Ger. Patent 1146883, 1963;
3. (c)Malz, H.; Schlesmann, H.; Dinges, K. Stabilization of acrylonitrile polymers. Ger. Patent 1173645, 1964;
4. (d)Wystrach, V. P.; Peters, G. A. Salts of 2-cyanoethylphosphino-dithioic acids. US Patent 3138605, 1964;
5. (e)Kozic, S. J.; Savides, C. Heat stabilizers for polypropylene containing asbestos. Ger. Patent 2009943, 1970;
6. (f)Wystrach, V. P.; Rauhut, M. M.; Freyberger, W. L. Froth flotation of ores by secondary dithiophosphinic acids or their salts or esters. Ger. Patent 1214171, 1966.
7. (a)Chen, J.; Jiao, R.; Zhu, Y. Purification and properties of Cyanex 301. Yingyong Huaxue 1996, 13(2), 45-48;
8. (b)Sherif Abdel, H. H. N. Hochselektive extraktionssysteme auf basis der dithiophosphinsauren: Experimentelle und theoretische untersuchungen zur actinoiden (III)\Abtrennung.=Highly selective extraction system based on dithiophosphinic acid: Experimental and the theoretical analysis of actinoide (III)\separation. Schriften des Forschungszentrums Juelich, Germany. Reihe Energietechnik=Energy Technology 2004, 29, 198;
9. (c)Modolo, G.; Odoj, R. Synergistic selective extraction of actinides(III) over lanthanides from nitric acid using new aromatic diorganyldithiophosphinic acids and neutral organophosphorus compounds. Solvent Extraction and Ion Exchange 1999, 17(1), 33-53;
10. 3 medium. Journal of Alloys and Compounds 1998, 271-273, 248-251.
11. Higgins, W. A.; Vogel, P. W.; Craig, W. G. Aromatic phosphinic acids and derivatives, I: Di-phenylphosphinodithioic acid and its derivatives. J. Am. Chem. Soc. 1955, 77, 1864-1866.
12. (a)Christen, P. J.; van der Linde, L. M.; Hooge, F. N. The reaction of alkylmagnesium halides with thiophosphoryl chloride, I: Formation of bi(dialkylphosphinothioyl) compounds. Recueil des Travaux Chimiques des Pays-Bas et de la Belgique 1959, 78, 161-172;
13. (b)Kuchen, W.; Metten, J. Metal complexes of dialkyldithiophosphinic acids. Ger. Patents 1137732 and 19621011, 1962;
14. (c)Kuchen, W.; Strolenberg, K.; Metten, J. Organophosphorus compounds, VI: Dialkyldithiophosphinic acids and bis(dialkylthiophosphoryl)sulfanes. Chem. Ber. 1963, 96, 1733-1740.
15. Rauhut, M. M.; Currier, H. A.; Wystrach, V. P. Preparation of dithiophosphinates from secondary phosphines and sulfur under alkaline conditions. J. Org. Chem. 1961, 26, 5133-5135.
16. (a)Mastryukova, T. A.; Shipov, A. E.; Kabachnik, M. I. Dimethylphosphinothioic and dimethylphosphinodithioic acids and their derivatives. Zh. Obshch. Khim. 1962, 32, 3579-3582.
17. (b)Grishina, O. N.; Kosova, L. M.; Klyuchanskaya, S. M. Alkylthionopho-sphine sulfides, XII: Reaction of alkylthionophosphine sulfides with organomagnesium compounds. Zh.Obshch. Khim. 1971, 41(9), 1995-1999.
18. (a)Issleib, K.; Tzschach, A. Preparation of secondary aliphatic phosphines. Chem. Ber. 1959, 92, 704-711;
19. (b)Christen, P. J.; van der Linde, L. M.; Hooge, F. N. The reaction of alkylmagnesium halides with thiophosphoryl chloride, I: Formation of bi(dialkylpho-sphinothioyl) compounds. Recueil des Travaux Chimiques des Pays-Bas et de la Belgique 1959, 78, 161-172.
20. (a)Cowley, A. H.; White, W. D. The vibrational spectra and structures of phosphorus compounds, I: Diphosphine disulfides. Spectrochim. Acta 1966, 22(8), 1431-1440;
21. (b)Exner, O.; Almasi, L.; Paskucz, L. Dipole moments and conformation of dialkyldithiopho-sphinic acids and their derivatives. Coll. Czech. Chem. Commun. 1973, 38(3), 677-689.