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Unexpected shoulders were observed in the GPC profile of II (ESI Fig. S1B), at both high and low molecular weights. This observation indicated lower chain transfer efficiency of the mPEG5k macro-CTA, compared with the mPEG2k macro-CTA used for the chain extension to block copolymer I (smaller low-molecular-weight shoulder). However, the relatively larger polydispersity of II did not affect its assembly behavior and uniform core-shell micelles with narrow size distributions were still obtained
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Unexpected shoulders were observed in the GPC profile of II (ESI Fig. S1B), at both high and low molecular weights. This observation indicated lower chain transfer efficiency of the mPEG5k macro-CTA, compared with the mPEG2k macro-CTA used for the chain extension to block copolymer I (smaller low-molecular-weight shoulder). However, the relatively larger polydispersity of II did not affect its assembly behavior and uniform core-shell micelles with narrow size distributions were still obtained
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max, abs for CCFNP2 was shifted to 500 nm, i.e., a 12 nm red-shift
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max, abs for CCFNP2 was shifted to 500 nm, i.e., a 12 nm red-shift.
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113 and the hydrophobic PVBA block was correspondingly lengthened to 46 repeating units to retain the block length ratio constant at ca. 2.5 (hydrophilic vs. hydrophobic)
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113 and the hydrophobic PVBA block was correspondingly lengthened to 46 repeating units to retain the block length ratio constant at ca. 2.5 (hydrophilic vs. hydrophobic).
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