Thermodynamic assessment of the Fe-Mn-O system

Journal of Phase Equilibria and Diffusion

Volumn 31, Issue 2, 2010, Pages 113-134

  Kjellqvist, Lina ^a   Selleby, Malin ^a  

^a ROYAL INSTITUTE OF TECHNOLOGY   (Sweden)

Author keywords

CALPHAD; Fe Mn O system; Thermodynamic modelling

Indexed keywords

CALPHAD; COMPOUND ENERGY FORMALISMS; CR-FE-NI; CR-FE-NI-O SYSTEM; EXPERIMENTAL VALUES; HAUSMANNITES; HIGH-ALLOYED STEELS; INFLUENCE OF OXYGEN; IONIC TWO-SUBLATTICE MODEL; LIQUID PHASE; STOICHIOMETRIC PHASIS; SUB-LATTICE MODEL; SYSTEM THERMODYNAMICS; THERMODYNAMIC ASSESSMENT;

CHROMIUM; IONIZATION OF LIQUIDS; MANGANESE COMPOUNDS; OXYGEN; THERMODYNAMICS;

MANGANESE;

EID: 77953619577     PISSN: 15477037     EISSN: None     Source Type: Journal    
DOI: 10.1007/s11669-009-9643-6     Document Type: Article

References (123)

1. L. Kjellqvist, M. Selleby, and B. Sundman, Thermodynamic Modelling of the Cr-Fe-Ni-O System, CALPHAD, 2008, 32, p 577-592
2. L. Kjellqvist and M. Selleby, Adding C to the Thermody-namic Description of the Cr-Fe-Ni-O System, CALPHAD, 2009, 33, p 393-397
3. M. Hillert, B. Jansson, B. Sundman, and J. Ågren, A Two-Sublattice Model for Molten Solutions with Different Tendency for Ionization, Metall. Trans. A, 1985, 16A, p 261-266
4. B. Sundman, Modification of the Two-Sublattice Model for Liquids, CALPHAD, 1991, 15, p 109-119
5. M. Hillert, The Compound Energy Formalism, J. Alloys Compd., 2001, 320, p 161-176
6. N. Saunders and A.P. Miodownik, CALPHAD (Calculation of Phase Diagrams): A Comprehensive Guide, 1998
7. H. Lukas, S.G. Fries, and B. Sundman, Computational Thermodynamics, The CALPHAD Method, 2007
8. B. Sundman, An Assessment of the Fe-O System, J. Phase Equilib., 1991, 12, p 127-140
9. M. Selleby and B. Sundman, A Reassessment of the Ca-Fe-O System, CALPHAD, 1996, 20, p 381-392
10. M. Kowalski and P.J. Spencer, Thermodynamic Reevaluation of the Cr-O, Fe-O and Ni-O Systems: Remodelling of the Liquid, bcc and fcc Phases, CALPHAD, 1995, 19, p 229-243
11. A.N. Grundy, B. Hallstedt, and L.J. Gauckler, Assessment of the Mn-O System, J. Phase Equilib., 2003, 24, p 21-39
12. W. Huang, An Assessment of the Fe-Mn System, CALPHAD, 1989, 13, p 243-252
13. R. Weiland, "Untersuchungen zur thermodynamik oxide-scher lösungsphasen im system Co-Fe-Mn-O," Doctoral Thesis, Stuttgart, 2002
14. 4 Spinels by Phase Diagram Analysis, Ber. Bunsenges. Phys. Chem., 1979, 83, p 241-252
15. G. Inden, Determination of Chemical and Magnetic Interchange Energies in BCC Alloys. I. General Treatment, Z. Metallkd., 1975, 66, p 577-582
16. M. Hillert and M. Jarl, A Model for Alloying Effects in Ferromagnetic Metals, CALPHAD, 1978, 2, p 227-238
17. 3 Systems, CALPHAD, 2004, 28, p 307-312
18. H.A. Jahn and E. Teller, Stability of Polyatomic Molecules in Degenerate Electronic States. I. Orbital Degeneracy, Proc. R. Soc. Lond. A, 1937, 161, p 220-235
19. 4, J. Am. Ceram. Soc., 1988, 71, p 379-385
20. 4 and Some Related Manganates, Inorg. Chim. Acta, 1967, 1, p 193-207
21. D.S. McClure, The Distribution of Transition Metal Cations in Spinels, J. Phys. Chem. Solids, 1957, 3, p 311-317
22. J.D. Dunitz and L.E. Orgel, Electronic Properties of Transition-Metal Oxides - II. Cation Distribution Amongst Octahedral and Tetrahedral Sites, J. Phys. Chem. Solids, 1957, 3, p 318-323
23. 3+ Ions, J. Phys. Chem. Solids, 1960, 17, p 101-111
24. M. Hillert, L. Kjellqvist, H. Mao, M. Selleby, and B. Sundman, Parameters in the Compound Energy Formalism for Ionic Systems, CALPHAD, 2009, 33, p 227-232
25. L.B. Pankratz, Thermodynamic Properties of Elements and Oxides, Technical Report, Bureau of Mines Bulletin 672, 1982
26. 4, Trans. Inst. Min. Metall. C, 1973, 82, p 34-37
27. K.S. Irani, A.P.B. Sinha, and A.B. Biswas, Effect of Temperature on the Structure of Manganites, J. Phys. Chem. Solids, 1962, 23, p 711-727
28. 3C, J. Am. Chem. Soc., 1942, 64, p 1769-1770
29. 4 at High Temperatures, J. Solid State Chem., 1981, 38, p 335-341
30. 4), Ber. Bunsenges. Phys. Chem., 1985, 89, p 1095-1104 (Pubitemid 15604664)
31. A. Schmier and G. Sterr, Contribution to the Knowledge of the Hausmannite Phase, Z. Anorg. Allg. Chem., 1966, 346, p 181-187
32. 4, Am. Mineral., 1958, 43, p 69-83
33. G. Trömel, W. Fix, K. Koch, and F. Schaberg, The Phase Diagram of the Manganese-Oxygen System, Erzmetall., 1976, 29, p 234-237
34. H.F. McMurdie and E. Golovato, Study of the Modifications of Manganese Dioxide, J. Res. Nat. Bur. Stand., 1948, 41, p 589-600
35. A.Z. Hed and D. Tannhauser, Contribution to the Mn-O Phase Diagram at High Temperature, J. Electrochem. Soc., 1967, 114, p 314-318
36. 4-MnO Equilibria, Am. J. Sci., 1960, 258, p 66-78
37. R.W. Millar, The Specific Heats at Low Temperatures of Manganous Oxide, Manganous-Manganic Oxide and Manganese Dioxide, J. Am. Chem. Soc., 1928, 50, p 1875-1883
38. C.H. Shomate, Heats of Formation of Manganomanganic Oxide and Manganese Dioxide, J. Am. Chem. Soc., 1943, 65, p 785-789
39. 3), Arch. Eisenhuttenw., 1963, 34, p 511-518
40. C. Benedicks and J. Löfquist, Non-Metallic Inclusions in Iron and Steel, Chapman & Hall, London, 1930
41. M. Le Blanc and G.Z. Wehner, Contribution to the Knowledge of the Manganese Oxides, Phys. Chem. Abt. A, 1934, 168, p 59-78
42. 3O4-MnO System and its Pressures of Dissociation, Arch. Eisenhuttenw., 1969, 40, p 395-399
43. T.E. Moore, M. Ellis, and PW. Selwood, Solid Oxides and Hydroxides of Manganese, J. Am. Chem. Soc., 1959, 72, p 856-866
44. N.G. Schmahl and D.F.K. Hennings, The Nonstoichiometry of the Manganese(II)-Oxide in Thermal Equilibrium, Z Phys. Chem., 1969, 63, p 111-124
45. A. Bergstein and J. Vintera, The Thermal Decomposition of Manganese Carbonates, Coll. Czech. Chem. Commun., 1956, 22, p 884-895
46. D.R. Petzold, Zuchtung und Eigenschaften von Mangan-, Kobalt- und Zinkmanganatkristallen, Kristall und Technik, 1971, 6, p 53-57
47. H. Von Wartenberg, H.J. Reusch, and E. Saran, Schmelzpunktsdiagramme höchstfeuerfester Oxyde. VII. Systeme mit CaO und BeO, Z. Anorg. Chem., 1937, 230, p 257-276
48. C. Klingsberg and R. Roy, Solid-Solid and Solid-Vapor Reactions and a New Phase in the System Mn-O, J. Am. Ceram. Soc, 1960, 43, p 620-626
49. 3 in Luft und Sauerstoff Z Anorg. Chem., 1908, 57, p 104-112
50. H.E. Kissinger, H.F. McMurdie, and B.S. Simpson, Thermal Decomposition of Manganous and Ferrous Carbonates, J. Am. Ceram. Soc, 1956, 39, p 168-172
51. T.R. Ingraham, Thermodynamics of the Mn-S-O System Between 1000°K and 1250°K, Can. Metall. Quart., 1966, 5, p 109-122
52. 3O4 Solid Solutions, Trans. Met. Soc. AIME, 1967, 239, p 1114-1119
53. H. Le Chatelier, Heat of Formation of Manganese Compounds, C. R. Hebd. Seances Acad. Sci., 1896, 122, p 80-82
54. O. Ruff and E. Gersten, Über die Carbide des Mangans und Nickels, Ber Deutsche Chem. Ges., 1913, 46, p 400
55. WA. Roth, Zur Thermochemie des Eisens, Mangans und Nickels, Z Angew. Chem., 1929, 42, p 981-984
56. H. Siemonsen, Neubestimmung der bildungswaermen der manganoxyde, Z Elektrochem., 1939, 45, p 637-645
57. H. Ulich and H. Siemonsen, Contribution to the Metallurgy of Manganese by Thermochemical Measurements and Equilibria Calculations, Arch. Eisenhuttenw., 1940, 14, p 27-34
58. A.D. Mah, Thermodynamic Properties of Manganese and its Compounds, Technical Report, Bureau of Mines Report of Investigations 5600, 1960
59. TA. Zordan and L.G. Hepler, Thermochemistry and Oxidation Potentials of Manganese and its Compounds, Chem. Rev., 1968, 68, p 737-745
60. RA. Robie and D.R. Waldbaum, Thermochemical Properties of Minerals and Related Substances at 298.15 K (25°C and One Atmosphere (1.013 Bars) Pressure and at Higher Temperatures, Technical Report, Geological Survey Bulletin 1259, 1968
61. O. Knacke, O. Kubaschewski, and K. Hesselmann, Thermodynamic Properties of Inorganic Substances, Springer-Verlag, Berlin, 1991
62. O. Kubaschewski, C.B. Alcock, and P.J. Spencer, Materials Thermochemistry, 6th ed., Pergamon Press, New York, 1993
63. 2O Oxygen Buffers and New Data for the W-W02 Buffer, Contrib. Mineral. Petrol., 1993, 114, p 296-314
64. 2O3 (Bixbyite), J. Chem. Thermodyn., 1985, 17, p 165-187
65. 2O4 at Low Temperatures, J. Chem. Thermodyn., 1986, 18, p 89-99
66. S. Fritsch and A. Navrotsky, Thermodynamic Properties of Manganese Oxides, J. Am. Ceram. Soc., 1996, 79, p 1761-1768
67. H. O'Neill and A. Navrotsky, Cation Distribution and Thermodynamic Properties of Binary Spinel Solid Solutions, Am. Mineral, 1984, 69, p 733-753
68. H. Okinaka, K. Kosuge, and S. Kachi, Phase Diagram of (Fe,Mn) O at 1260 K, J. Jpn. Soc. Powder Metall., 1968, 15, p 295-301
69. P. Franke and R. Dieckmann, Thermodynamics of Iron Manganese Mixed Oxides at High Temperatures, J. Phys. Chem. Solids, 1990, 51, p 49-57
70. AA. Lykasov and M.S. Pavlovskaya, Thermodynamic Properties of Manganowustite, Russ. J. Phys. Chem., 1988, 62(5), p 602-605
71. H. Soliman and A. Stoklosa, Deviation from Stoichiometry of Mn-Doped Ferrous Oxide, Solid State Ionics, 1990, 42, p 85-91
72. R. Subramanian and R. Dieckmann, Nonstoichiometry and Thermodynamics of the Solid Solution (Fe, Mn) 1-deltaO at 1200°C, J. Phys. Chem. Solids, 1993, 54, p 991-1000
73. P.K. Foster and A.J.E. Welch, Metal-Oxide Solid Solutions: Part 2. Activity Relationships in Solid Solutions of Ferrous Oxide and Manganous Oxide, Trans. Faraday Soc., 1956, 52, p 1636-1642
74. T.I. Bulgakova and A.G. Rozanov, Phase Equilibria in the Ferrite Region of the Mn-Fe-O System, Russ. J. Phys. Chem., 1970, 44, p 385-388
75. K. Ono, T. Ueda, Y. Ozaki, A. Yamaguchi, and J. Moriyama, Thermodynamic Study of the Iron-Manganese-Oxygen System, J. Jpn. Inst. Met, 1971, 35, p 757-763
76. A. Duquesnoy, J. Couzin, and P. Gode, Isothermal Representation of Ternary Phase Diagrams A-B-O. Study of the System Mn-Fe-O, C. R. Acad. Sci. Paris C, 1975, 281, p 107-109
77. H. Falke, "Innere Reduktion von (Fe,Mn) 10 Mischoxiden," Doctoral Thesis, Universität Hannover, 1987
78. 3O4, Zh. Neorg. Khim., 1964, 9, p 164-168
79. K.H. Ulrich, K. Bohnenkamp, and H.J. Engell, Über die Gleichgewichte von Magnetit-Hausmannit-Mischkristallen mit Wüstit-Mangan(II) oxid-Mischkristallen und Sauerstoff und die Reduktion von Magnetit-Hausmannit- Mischoxiden, Z. Phys. Chem., 1966, 51, p 35-49
80. B. Punge-Witteler, Phasengleichheit zwischen Spinell und Wüstit im System Fe-Mn-O bei 700°C, 1 bar, Z. Phys. Chem., 1984, 142, p 239-248
81. S. Takeuchi, K. Furukawa, and K. Gunji, Statistico-Thermo-dynamical Studies on Oxidation and Reduction Equilibriums of Mn-Wüstite with Gas Phases, J. Jpn. Inst. Met., 1960, 24, p 187
82. H.J. Engell, Equilibrium Measurements on Oxide Mixed Crystals, Z. Phys. Chem., 1962, 35, p 192-195
83. W. Ringsdorf, "Gleichgewichtsverschiebungen im System Eisen-Sauerstoff durch Legierungs- und Mischkristallbildung mit Nickel, Mangan und Kobalt bzw. deren Oxiden," Doctoral Thesis, Universität des Saarlandes, Saarbrucken, 1964
84. A. Muan and S. Somiya, The System Iron Oxide-Manganese Oxide in Air, Am. J. Sci., 1962, 260, p 230-240
85. y, Coll. Czech. Chem. Commun., 1964, 29, p 2549-2551
86. 4, J. Inorg. Nucl. Chem., 1969, 31, p 313-320
87. Y.V. Golikov, S.A. Petrova, R.G. Zakharov, V.K. Antonov, and V.F. Balakirev, Equilibrium and Unstable States of the Fe-Mn-O System in Air, Russ. J. Inorg. Chem., 1996, 41, p 1510-1513
88. S.A. Petrova, Y.V. Golikov, R.G. Zakharov, and V.F. Balakirev, Heterogeneous Equilibria in the Fe-Mn-O System in Air, Russ. J. Phys. Chem., 1997, 71, p 184-186
89. 3, Geol. Fören. Stockholm Förh., 1943, 65, p 97-180
90. 4, J. Phys. Chem. Solids, 1971, 32, p 2181-2191
91. 4+γ, J. Phys. Chem. Solids, 1973, 34, p 387-395
92. 4, J. Res. Nat. Bur. Stand., 1950, 45, p 35-41
93. J.M. Hastings and L.M. Corliss, Neutron Diffraction Study of Manganese Ferrite, Phys. Rev., 1956, 104, p 328-331
94. 4+γ Ferrites, Czech. J. Phys., 1959, 9, p 324-331
95. 4, Phys. Lett., 1967, 25A, p 147-148
96. T. Yamanaka and M. Nakahira, Dependence of the Cation Distribution in Manganese Ferrite on Temperature and Oxidation, Mineral. J., 1973, 7, p 202-220
97. 4, Czech. J. Phys., 1974, 24, p 642-647
98. 4, Phys. Stat. Sol., 1977, 40, p K169-K171
99. 4 (0 < × < 1.50), Solid State Ionics, 1996, 83, p 215-223
100. 2 Mixtures, Trans. Jpn. Inst. Met., 1983, 24, p 514-517
101. 4) in the 298-1000 K Range, Izv. Akad. Nauk SSSR Neorg. Mater., 1974, 10, p 477-480
102. 4, Solid State Chem., 1981, 36, p 28-35
103. S.E. Harrison, C.J. Kriessman, and S.R. Pollack, Magnetic Spectra of Manganese Ferrites, Phys. Rev., 1958, 110, p 844-849
104. V.L. Moruzzi, Triangular Moment Arrangements in Manganese-Iron Spinels, J. Appl. Phys. Sci., 1961, 32, p 59-61
105. R. Gerber, Z. Simsa, and M. Vichr, Some Physical Properties of Single Crystal Manganese Ferrites, Czech. J. Phys. Ser. B, 1966, 16, p 913-918
106. R. Buhl, Manganites spinelles purs d'elements de transition preparations et structures cristallographiques, J. Phys. Chem. Solids, 1969, 30, p 805-812
107. U. Nolle, "Gleichgewichtsuntersuchungen im System Eisen-Mangan-Sauerstoff," Doctoral Thesis, Technische Universi-tät Berlin, 1974
108. D. Janke and W.A. Fischer, Gleichgewichte von Chrom und Mangan mit Sauerstoff in Eisenschmelzen bei 1600°C, Arch. Eisenhuttenw., 1976, 47, p 147-151
109. D.C Hilty and W. Crafts, Solubility of Oxygen in Liquid Iron Containing Silicon and Manganese, Trans. Met. Soc. AIME, 1959, 188, p 425-436
110. S.M. Averbukh and LA. Smirnov, Equilibrium Between Manganese and Oxygen in Molten Iron, Steel in the USSR, 1981, 13, p 123-126
111. V.P.M. Mathew, M.L. Kapoor, and M.G. Frohberg, Untersuch-ungen zum Mangan-Sauerstoff-Gleichgewicht im flüssigen Eisen bei 1600°C, Arch. Eisenhuttenw., 1972, 43, p 865-872
112. V.E. Shevtsov, E.E. Merker, and V.P. Luzgin, Oxygen Solubility in High Manganese Iron Melts, Steel in the USSR, 1987, 17, p 393-394
113. P. Oberhoffer and H. Schenck, Theoretische und Experimen-telle Untersuchungen über die Desoxydation der Eisen mit Mangan, Stahl u. Eisen, 1927, 47, p 1526-1530
114. W. Oelsen and G. Heynert, Die Reaktionen zwischen Eisen-Mangan-Schmelzen und den Schmelzen ihrer Aluminate, Arch. Eisenhuttenw., 1955, 26, p 567-575
115. J.-O. Andersson, T. Helander, L. Höglund, P. Shi, and B. Sundman, Thermo-Calc & DICTRA, Computational Tools for Materials Science, CALPHAD, 2002, 26, p 273-312
116. A. Dinsdale, SGTE Data for Pure Elements, CALPHAD, 1991, 15, p 317-425
117. R.J. Hill, J.R. Craig, and G.V. Gibbs, Systematics of the Spinel Structure Type, Phys. Chem. Miner, 1979, 4, p 317-339
118. G.D. Rieck and F.C.M. Driessens, The Structure of Manganese-Iron-Oxygen Spinels, Acta Cryst., 1966, 20, p 521-525
119. G.D. Murthy, L.M. Rao, R.J. Begum, M.G. Natera, and S.I. Youssef, Neutron Scattering Studies of Some Spinels, J. de Phys., 1971, 32(Suppl C1), p 318-319
120. J. Faller and C.E. Birchenall, The Temperature Dependence of Ordering in Magnesium Ferrite, J. Appl. Cryst., 1970, 3, p 496-503
121. 3O4-MnO-FeO at 1000°C and Thermodynamic Properties of the Coexisting Phases, Inorg. Mater, 1965, 1, p 382-386
122. 2O3-SiO2 System, J. Am. Ceram. Soc., 2006, 89, p 298-308
123. 2O3-SiO2 System, J. Mater. Res., 2005, 20, p 975-986