Prediction of solute solubility in supercritical carbon dioxide: A novel semi-empirical model

Chemical Engineering Research and Design

Volumn 88, Issue 7, 2010, Pages 893-898

  Jafari Nejad, Sh ^a   Abolghasemi, H ^a   Moosavian, M A ^a   Maragheh, M G ^a  

^a UNIVERSITY OF TEHRAN   (Iran)

Author keywords

AARD; Empirical equation; Solubility; Supercritical carbon dioxide

Indexed keywords

AARD; APPLIED PRESSURE; AS EXTRACTION; EMPIRICAL EQUATIONS; EXPERIMENTAL UNCERTAINTY; EXTRACTION PROCESS; LEAST SQUARES METHODS; MICRONIZATIONS; MODEL CONSTANTS; MOLE FRACTION; RELATIVE DEVIATIONS; SEMIEMPIRICAL MODELS; SOLUBILITY DATA; SOLUTE SOLUBILITY; SPEED-UPS; SUPERCRITICAL CARBON DIOXIDES; SUPERCRITICAL PHASE;

CARBON DIOXIDE; EFFLUENT TREATMENT; SOLUBILITY; SUPERCRITICAL FLUIDS;

SUPERCRITICAL FLUID EXTRACTION;

EID: 77953543390     PISSN: 02638762     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.cherd.2009.12.006     Document Type: Article

References (28)

1. Angus S., Armstrong B., de Reuck K.M. International Thermodynamic Tables of the Fluid State Carbon Dioxide 1976, Pergamon Press, Oxford, pp. 266-359.
2. Bartle K.D., Clifford A.A., Jafar S.A., Shilstone G.F. Solubilities of solids and liquids of low volatility in supercritical carbon dioxide. J. Phys. Chem. Ref. Data 1991, 20:713-725.
3. Bush D., Eckert C.A. Estimation of solid solubilities in supercritical carbon dioxide from solute solvatochromic parameters. J. Supercrit. Fluid 1997, 37-50.
4. Coimbra P., Gil M.H., Duarte C.M.M., Heron B.M., de Sousa H.C. Solubility of a spiroindolinonaphthoxazine photochromic dye in supercritical carbon dioxide: experimental determination and correlation. Fluid Phase Equilibr. 2005, 238:120-128.
5. ® 2959 photoinitiator in supercritical carbon dioxide: experimental determination and correlation. J. Supercrit. Fluids 2008, 45:272-281.
6. Chrastil J. Solubility of solids and liquids in supercritical gases. J. Phys. Chem. 1982, 86:3016-3022.
7. Dondeti P., Desai Y. Supercritical fluid technology in pharmaceutical research. Encyclopedia Pharmaceut. Technol. 1999, 18:219-248.
8. 2. Ind. Eng. Chem. Res. 1988, 27:1551-1559.
9. Furton K.G., Chen L., Jaffe R. Rapid determination of uranium on solid matrices by synergistic in situ chelation supercritical fluid extraction and UV absorption spectroscopy. Anal. Chim. Acta 1995, 304:203-208.
10. Garnier S., Neau E., Alessi P., Cortesi A., Kikic I. Modeling solubility of solids in supercritical fluids using fusion properties. Fluid Phase Equilibr. 1999, 491:158-162.
11. Gordillo M.D., Blanco M.A., Molero A., Martinez de la Ossa E. Solubility of the antibiotic penicillin G in supercritical carbon dioxide. J. Supercrit. Fluids 1999, 15:183-189.
12. Huang S.Y., Tang M., Ho S.L., Chen Y.P. Solubilities of N-phenylacetamide, 2-methyl-N-phenylacetamide and 4-methyl-N-phenylacetamide in supercritical carbon dioxide. J. Supercrit. Fluids 2007, 42:165-171.
13. Hojjati M., Yamini Y., Khajeh M., Vatanara A. Solubility of some statin drugs in supercritical carbon dioxide and representing the solute solubility data with several density-based correlations. J. Supercrit. Fluids 2007, 41:187-194.
14. Iso S., Meguro Y., Yoshida Z. Extraction of uranium(VI) from nitric acid solution into supercritical carbon dioxide containing tri-n-butylphosphate. Chem. Lett. 1995, 24:365-371.
15. Jafari Nejad Sh., Mohammadikhah R., Abolghasemi H., Moosavian M.A., Maragheh M.G. A novel equation of state (EOS) for prediction of solute solubility in supercritical carbon dioxide: experimental determination and correlation. Can. J. Chem. Eng. 2009, 87:930-938.
16. Jouyban A., Chan H.K., Foster N.R. Mathematical representation of solute solubility in supercritical carbon dioxide using empirical expressions. J. Supercrit. Fluids 2002, 24:19-35.
17. Khimeche K., Alessi P., Kikic I., Dahmani A. Solubility of diamines in supercritical carbon dioxide: experimental determination and correlation. J. Supercrit. Fluids 2007, 41:10-19.
18. 2. Anal. Chem. 1994, 2190.
19. Lin Y., Smart N.G., Wai Supercritical fluid extraction and chromatography of metal chelates and organometallic compounds. C.M. Trends Anal. Chem. 1995, 14:123-133.
20. Lucien F.P., Foster N.R. Solubilities of solid mixtures in supercritical carbon dioxide: a review. J. Supercrit. Fluids 2000, 17:111-119.
21. Mèndez-Santiago J., Teja A.S. Solubility of solids in supercritical fluids: consistency of data and a new model for cosolvent systems. Ind. Eng. Chem. Res. 2000, 39:4767-4771.
22. Meguro Y., Iso S., Takeishi H., Yoshida Z. Extraction of uranium (VI) in nitric acid solution with supercritical carbon dioxide fluid containing tributylphosphate. Radiochim. Acta 1996, 75:185-193.
23. Smart N.G., Carleson T.E., Elshani S., Wang S.H., Wai C.M. Extraction of toxic heavy metals using supercritical fluid carbon dioxide containing organophophorus reagents. Ind. Eng. Chem. Res. 1997, 1819.
24. Tian G., Jin J., Zhang Z., Guo J. Solubility of mixed solids in supercritical carbon dioxide. Fluid Phase Equilibr. 2007, 251:47-51.
25. Toews K.L., Smart N.G., Wai C.M. Complexation and transport of uranyl nitrate in supercritical carbon dioxide with organophosphorus reagents. Radiochim. Acta 1996, 75:179-184.
26. Wang S., Wai C.M. Supercritical fluid extraction of bioaccumulated mercury from aquatic plants. Environ. Sci. Technol. 1996, 30:3111-3114.
27. Yu Z., Singh B., Rizvi S.S.H., Zollewg J.A. Solubilities of fatty acids, fatty acid esters, and fats and oils in supercritical carbon dioxide. J. Supercrit. Fluids 1994, 7:51-61.
28. Ziger D.H., Eckert C.A. Correlation and prediction of solid supercritical fluid phase equilibria. Ind. Eng. Chem. Process. Des. Dev. 1983, 22:582-593.