Asymmetrie synthesis of allylsilanes by the borylation of lithiated carbamates: Formal total synthesis of (-)-decarestrictine D

Angewandte Chemie - International Edition

Volumn 49, Issue 25, 2010, Pages 4264-4268

  Binanzer, Michael ^a   Fang, Guang Yu ^a   Aggarwal, Varinder K ^a  

^a UNIVERSITY OF BRISTOL   (United Kingdom)

Author keywords

Boranes; Borates; Homologation; Lithium natural products

Indexed keywords

ALLYLSILANES; BORATES; BORYLATION; CHEMICAL EQUATIONS; INVERSION OF CONFIGURATION; NATURAL PRODUCTS; TOTAL SYNTHESIS;

BORON COMPOUNDS; HYDRIDES; LITHIUM;

ORGANIC COMPOUNDS;

ALKENE; ALLYLSILANE; BORON; CARBAMIC ACID DERIVATIVE; DECARESTRICTINE D; EPOXIDE; LACTONE; LITHIUM DERIVATIVE; SILANE DERIVATIVE;

ARTICLE; CHEMICAL STRUCTURE; CHEMISTRY; HYDROXYLATION; STEREOISOMERISM; SYNTHESIS;

ALKENES; BORON; CARBAMATES; EPOXY COMPOUNDS; HYDROXYLATION; LACTONES; LITHIUM COMPOUNDS; MOLECULAR STRUCTURE; SILANES; STEREOISOMERISM;

EID: 77953516846     PISSN: 14337851     EISSN: 15213773     Source Type: Journal    
DOI: 10.1002/anie.201001223     Document Type: Article

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