Entropy variation in the two-dimensional phase transition of anthracene adsorbed at the hg electrode/ethylene glycol solution interface

Entropy

Volumn 12, Issue 3, 2010, Pages 570-577

  Fontanesi, Claudio ^a  

^a UNIVERSITY OF MODENA AND REGGIO EMILIA   (Italy)

Author keywords

Adsorption; Anthracene; Phase transition; Two dimensional

Indexed keywords

EID: 77953516058     PISSN: None     EISSN: 10994300     Source Type: Journal    
DOI: 10.3390/e12030570     Document Type: Article

References (15)

1. Finklea, H.O. Electrochemistry of organized monolayers of thiols and related molecules. In Electroanalytical Chemistry. A Series of Advances; Bard, A.J., Rubinstein, I., Eds.; Marcel Dekker Inc.: New York, NY, USA, 1996; Volume 19, Chapter 3, pp. 110-223.
2. Vetterl, V. Differentielle kapazitat der elektrolytischen doppelschicht in anwesenheit einiger purin und pyrimidinderivate. Coll. Czech. Chem. Commun. 1966, 31, 2105-2110.
3. Sridharan, R.; de Levie, R.; Rangarajan, S.K. Two-dimensional phase transitions at electrochemical interfaces. Chem. Phys. Lett. 1987, 142, 43-47.
4. De Levie, R. The dynamic double layer: two-dimensional condensation at the Mercury-Water interface. Chem. Rev. 1988, 88, 599-609.
5. Donner, C.; Baumgartel, H.; Pohlmann, L.; Retter, U.; Philip, R. Non-faradaic two-dimensional phase transitions on smooth surfaces-an example for time-dependent homogeneous nucleation. Ber. Bunsenges. Phys. Chem. 1996, 100, 403-412.
6. Buess-Herman, C. Self-assembled monolayers at electrode metal surfaces. Prog. Surf. Sci. 1994, 46, 335-375.
7. Fontanesi, C. Entropy change in the two-dimensional phase transition of adenine adsorbed at the Hg Electrode/Aqueous Solution Interface. J. Chem. Soc., Faraday Trans. 1994, 90, 2925-2930.
8. Striegler, H.; Krznaric, D.; Kolb, D.M. Two-dimensional condensation of camphor and its derivatives on Au(111) Electrodes. J. Electroanal. Chem. 2002, 532, 227-235.
9. 4). J. Phys. Chem. B 2004, 108, 14398-14406.
10. Tanaka, Y.; Sagara, T. Formation of Viologen Radical Cation condensed phase through two-dimensional molecular organization process on an HOPG Electrode Surface in Binary Viologen Solutions. J. Electroanal. Chem. 2008, 619-620, 65-74.
11. Sridharan, R; De Levie, R.; Rangarajan, S.K. Two-dimensional phase transitions at Electrochemical Interfaces. Chem. Phys. Lett. 1987, 142, 43-46.
12. Retter, U. On adsorption according to the Lattice Gas Model (Ising Model). J. Electroanal. Chem. 1987, 236, 21-30.
13. Benedetti, L.; Camurri, G.; Fontanesi, C.; Ferrarini, P.; Giovanardi, R. On the 2D phase transition of Adenine adsorbed at the Mercury/Ethylene Glycol Solution Interface. Electrochim. Acta 2004, 36, 1655-1662.
14. Tadjeddine, A.; Rahmani, A. Formation of condensed Film at a Mercury-Electrolyte Interface observed by Surface Plasmon Excitation. Electrochim. Acta 1991, 49, 1855-1857.
15. -1, was used in recording capacity vs. potential curves.