Hydrogen production from sodium borohydride for fuel cells in presence of electrical field

International Journal of Energy Research

Volumn 34, Issue 7, 2010, Pages 557-567

  Sahin, Ömer ^a   Dolas, Hacer ^b   Kaya, Mustafa ^a   Izgi, Mehmet Sait ^a   Demir, Halil ^a  

^a SIIRT UNIVERSITY   (Turkey)

^b ISTANBUL TECHNICAL UNIVERSITY   (Turkey)

Author keywords

Electrical field; Fuel cells; Hydrogen generation; Hydrogen storage; Hydrolysis; Sodium borohydride

Indexed keywords

AC VOLTAGE; ALTERNATIVE CURRENT; DC VOLTAGE; ELECTRICAL FIELD; EXPERIMENTAL DATA; FIRST-ORDER; HYDROGEN GENERATION; HYDROGEN GENERATIONS; HYDROLYSIS REACTION; KINETIC MODELS; ROOM TEMPERATURE; SODIUM BOROHYDRIDES; SQUARE WAVES;

ACTIVATION ENERGY; FUEL CELLS; FUEL STORAGE; GAS FUEL PURIFICATION; HYDROGEN PRODUCTION; HYDROGEN STORAGE; HYDROLYSIS; RATE CONSTANTS; REACTION KINETICS; SODIUM;

ELECTRIC GENERATORS;

EID: 77953439650     PISSN: 0363907X     EISSN: 1099114X     Source Type: Journal    
DOI: 10.1002/er.1563     Document Type: Article

References (30)

1. Dincer I. Enviromental and sustainability aspects of hydrogen and fuel cell systems. International Journal of Energy Research 2007; 31(1):29-55.
2. Dicks AL. Hydrogen generation from natural gas for the fuel cell systems of tomorrow. Journal of Power Source 1996; 61:113.
3. Uribe FA, Gottesfeld S, Zawodzinski TA. Effect of ammonia as potential fuel impurity on proton exchange membrane fuel cell performance. Journal of the Electrochemical Society 2002; 149:A293.
4. Papageorgopoulos DC, de Bruijn FA. Examining a potential fuel cell poison. Journal of the Electrochemical Society 2002; 149:A140.
5. Camara GA, Ticianelli EA, Mukerjee S, Lee SJ, McBreen J. Hydrogen generation from catalytic hydrolysis of sodium borohydride for proton exchange membrane fuel cells. Journal of the Electrochemical Society 2002; 149:A748.
6. Zhang J, Thampan T, Datta R. Influence of anode flow rate and cathode oxygen pressure on CO poisoning of proton exchange membrane fuel cells. Journal of the Electrochemical Society 2002; 149:A765.
7. Qi Z, He C, Kaufman A. Effect of CO in the anode fuel on the performance of PEM fuel cell cathode. Electrochemical and Solid-state Letters 2001; 4:A204.
8. Brankovic SR, Wang JX, Adzic RR. Spontaneous deposition of Pt on the Ru(0001) surface. Electrochemical and Solid-state Letters 2001; 4:A217.
9. Schlesinger HI, Brown HC, Finholt AE, Gilbreath JR, Hoekstra HR, Hyde EK. Sodium borohydride: hydrolysis and its generation of hydrogen. Journal of the American Chemical Society 1953; 75:215-219.
10. Li ZP, Liu BH, Arai K, Morigazaki N, Suda S. Protide compounds in hydrogen storage systems. Journal of Alloys and Compounds 2003; 356-357:469-474.
11. 4 solution. Material Letters 2006; 60:2236-2239.
12. Amendola SC, Sharp-Goldman SL, Janjua MS, Kelly MT, Petillo PJ, Binder M. An ultrasafe hydrogen generator: aqueous, alkaline borohydride solutions and Ru catalyst. Journal of Power Sources 2000; 85(2):186-189.
13. Amendola SC, Sharp-Goldman SL, Janjua MS, Spencer NC, Kelly MT, Petillo PJ et al. A safe, portable, hydrogen gas generator using aqueous borohydride solution and Ru catalyst. International Journal of Hydrogen Energy 2000; 25(10):969-975.
14. 4 solution. Journal of Power Sources 2008; 177(2):485-492.
15. Ozkar S, Zahmakiran M. Hydrogen generation from hydrolysis of sodium borohydride using Ru(0) nanoclusters as catalyst. Journal of Alloys and Compounds 2005; 404:728-731.
16. Zahmakiran M, Ozkar S. Water dispersible acetate stabilized ruthenium (0) nanoclusters as catalyst for hydrogen generation from the hydrolysis of sodium borohyride. Journal of Molecular Catalysis A: Chemical 2006; 258(1-2):95-103.
17. Shang YH, Chen R. Semiempirical hydrogen generation model using concentrated sodium borohydride solution. Energy Fuels 2006; 20(5):2149-2154.
18. Zhang JS, Delgass WN, Fisher TS, Gore JP. Kinetics of Ru catalyzed sodium borohydride hydrolysis. Journal of Power Sources 2007; 164(2):772-781.
19. Kojima Y, Suzuki K, Fukumoto K, Kawai Y, Kimbara M, Nakanishi H et al. Development of 10 kW-scale hydrogen generator using chemical hydride. Journal of Power Sources 2004; 125(1):22-26.
20. Patel N, Patton B, Zanchetta C, Fernandes R, Guella G, Kale A et al. Pd-C powder and thin film catalysts for hydrogen production by hydrolysis of sodium borohydride. International Journal of Hydrogen Energy 2008; 33(1):287-292.
21. Liu BH, Li ZP, Suda S. Nickel-and cobalt-based catalysts for hydrogen generation by hydrolysis of borohydride. Journal of Alloys and Compounds 2006; 415(1-2):288-293.
22. Metin O, Ozkar S. Hydrogen generation from the hydrolysis of sodium borohydride by using water dispersible, hydrogen phosphate-stabilized nickel(0) nanoclusters as catalyst. International Journal of Hydrogen Energy 2007; 32(12):1707-1715.
23. Ye W, Zhang HM, Xu DY, Ma L, Yi BL. Hydrogen generation utilizing alkaline sodium borohydride solution and supported cobalt catalyst. Journal of Power Sources 2007; 164(2):544-548.
24. Malvadkar N, Park S, Urquidi-MacDonald M, Wang H, Demirel MC. Catalytic activity of cobalt deposited on nanostructured poly(p-xylene) films. Journal of Power Sources 2008; 182(1):323-328.
25. 4 solution using the high-performance Co-B catalyst. Journal of Power Sources 2005; 144(1):129-134.
26. 4 solution using carbon-supported Co-B as catalysts. International Journal of Hydrogen Energy 2007; 32(18):471-476.
27. Dong H, Yang HX, Ai XP, Cha CS. Hydrogen production from catalytic hydrolysis of sodium borohydride solution using nickel boride catalyst. International Journal of Hydrogen Energy 2003; 28(10):100-109.
28. Ingersoll JC, Mani N, Thenmozhiyal JC, Muthaiah A. Catalytic hydrolysis of sodium borohydride by a novel nickel-cobaltboride catalyst. Journal of Power Sources 2007; 173:450-457.
29. 4 for fuel cells. Journal of Power Sources 2007; 165(1): 315-323.
30. Şahin Ö, Dolaş-H, Özdemir M. The effect of various factors on the hydrogen generation by hydrolysis reaction of potassium borohydride. International Journal of Hydrogen Energy 2007; 32:2330-2336.