Influence of activated carbons on the kinetics and mechanisms of aromatic molecules ozonation

Catalysis Today

Volumn 151, Issue 1-2, 2010, Pages 166-172

  Merle, T ^a   Pic, J S ^a   Manero, M H ^b   Mathe S ^a   Debellefontaine, H ^a  

^a UNIVERSITÉ DE TOULOUSE   (France)

^b LABORATOIRE DE GÉNIE CHIMIQUE   (France)

Author keywords

2,4 Dichlorophenol; Activated carbon; Nitrobenzene, Oxidation by products; Ozone

Indexed keywords

2,4-DICHLOROPHENOL; ACTIVATED AROMATIC; ALIPHATIC SPECIES; AROMATIC MOLECULES; AROMATIC RINGS; BIOLOGICAL TREATMENT; BIOLOGICAL TREATMENT PROCESS; DICHLOROPHENOLS; DIPOLAR CYCLOADDITIONS; ELECTROPHILIC ATTACK; INDUSTRIAL WASTEWATER TREATMENT; KINETICS AND MECHANISM; MASS BALANCE; OH GROUP; OXIDATION BY-PRODUCTS; OZONATION; OZONE OXIDATION; REFRACTORY COMPOUNDS; REFRACTORY WASTEWATER;

ACTIVATED CARBON TREATMENT; AROMATIC COMPOUNDS; AROMATIZATION; BIOCHEMICAL ENGINEERING; BIOLOGICAL WATER TREATMENT; CARBOXYLIC ACIDS; CHEMICAL OXYGEN DEMAND; CYCLOADDITION; INDUSTRIAL WATER TREATMENT; MOLECULES; NIOBIUM COMPOUNDS; NITROBENZENE; ORGANIC ACIDS; OXIDATION; OZONE; OZONE WATER TREATMENT; OZONIZATION; REFRACTORY MATERIALS; WASTEWATER; WASTEWATER RECLAMATION; WASTEWATER TREATMENT;

ACTIVATED CARBON;

EID: 77953291777     PISSN: 09205861     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.cattod.2010.03.044     Document Type: Article

References (19)

1. Bailey P.S. Ozonation in Organic Chemistry (1978), Academic Press, New York
2. Alvarez P.M., Garcia-Araya J.F., Beltran F.J., Giraldez I., Jaramillo J., and Serrano G. The influence of various factors on aqueous ozone decomposition by granular activated carbons and the development of a mechanistic approach. Carbon 44 (2006) 3102-3112
3. Andreozzi R., Caprio V., Insola A., and Marotta R. Advanced oxidation processes (AOP) for water purification and recovery. Catal. Today 53 1 (1999) 51-59
4. Legube B., and Karpel Vel Leitner N. Catalytic ozonation: a promising advanced oxidation technology for water treatment. Catal. Today 53 1 (1999) 61-72
5. Lin J., Kawai A., and Nakajima T. Effective catalysts for decomposition of aqueous ozone. Appl. Catal. B 39 2 (2002) 157-165
6. Beltran F.J., Garcia-Araya J.F., and Giraldez I. Gallic acid water ozonation using activated carbon. Appl. Catal. B 63 (2005) 249-259
7. 4{radical dot} as chain intermediate. J. Phys. Chem. 88 24 (1984) 5999-6004
8. Staehelin J., and Hoigné J. Decomposition of ozone in water: rate of inititation by hydroxide ions and hydrogen peroxide. Environ. Sci. Technol. 16 (1982) 676-681
9. Stumm W. Der zerfall von ozon in wässriger Lösung. Helv. Chim. Acta 37 (1954) 773-778
10. Reungoat J., Pic J.S., Manero M.H., and Debellefontaine H. Adsorption of nitrobenzene from water onto high silica zeolites and regeneration by ozone. Sep. Sci. Technol. 42 (2008) 1447-1463
11. Merle T., Pic J.S., Manero M.H., and Debellefontaine H. Enhanced bio-recalcitrant organics removal by combined adsorption and ozonation. Water Sci. Technol. 60 11 (2009) 2921-2928
12. T. Merle, J.S. Pic, M.H. Manero, H. Debellefontaine, Comparison of activated carbon and hydrophobic zeolite efficiencies in 2,4-dichlorophenol advanced ozonation, Ozone: Sci. Eng., in press.
13. Monneyron P., Mathé S., Manero M.H., and Foussard J.N. Regeneration of high silica zeolites via A.O.P.-a preliminary study about adsorbent reactivity toward ozone. Chem. Eng. Res. Des. 81 A9 (2003) 1193-1198
14. Monneyron P., Manero M.H., and Mathe S. A combined selective adsorption and ozonation process for VOCs removal from air. Can. J. Chem. Eng. 85 (2007) 326-332
15. Rivera-Utrilla J., and Sánchez-Polo M. Ozonation of 1,3,6-naphatalenetrisulfonic acid catalysed by activated carbon in aqueous phase. Appl. Catal. B 39 (2002) 319-329
16. Lopez-Lopez A., Pic J.S., Benbelkacem H., and Debellefontaine H. Influence of t-butanol and pH on hydrodynamic and mass transfer parameters in an ozonation process. Chem. Eng. Process. 46 (2007) 649-655
17. Guiza M., Ouedemi A., and Ratel A. Decomposition of dissolved ozone in the presence of activated carbon: an experimental study. Ozone: Sci. Eng. 26 3 (2004) 299-307
18. Boehm H.P. Chemical identification of surface groups. Adv. Catal. 16 (1966) 179-274
19. Benitez F., Beltrán-Heredia J., Acero J.L., and Rubio F.J. Rate constants for the reactions of ozone with chlorophenols in aqueous solutions. J. Hazard. Mater. B79 (2000) 271-285