The crystal structure of esperite, with a revised chemical formula, PbCa2(ZnSiO4)3, isostructural with beryllonite

American Mineralogist

Volumn 95, Issue 5-6, 2010, Pages 699-705

  Tait, Kimberly T ^a   Yang, Hexiong ^b   Downs, Robert T ^b   Li, Chen ^b   Pinch, William W ^c  

^a DEPARTMENT OF NATURAL HISTORY   (Canada)

^b The University of Arizona   (United States)

^c NONE   (United States)

Author keywords

Beryllonite; Crystal chemistry; Esperite; Pb Zn silicates; X ray diffraction

Indexed keywords

BINARY ALLOYS; CHROMIUM ALLOYS; CHROMIUM METALLOGRAPHY; CRYSTAL CHEMISTRY; ELECTRON PROBE MICROANALYSIS; LEAD ALLOYS; LEAD COMPOUNDS; LEAD METALLOGRAPHY; SILICATES; SILICON; SINGLE CRYSTALS; TEXTURES; X RAY DIFFRACTION; ZINC COMPOUNDS; ZINC METALLOGRAPHY;

BERYLLONITE; CHEMICAL COMPOSITIONS; CHEMICAL FORMULAE; COORDINATED SITES; ESPERITE; HIGH-TEMPERATURE POLYMORPH; SINGLE CRYSTAL X-RAY DIFFRACTION; UNIT CELL PARAMETERS;

CRYSTAL STRUCTURE;

BERYLLIUM; CALCIUM; CHEMICAL COMPOSITION; CRYSTAL CHEMISTRY; CRYSTAL STRUCTURE; LATTICE DYNAMICS; LEAD; PHASE TRANSITION; SILICATE MINERAL; TWINNING; X-RAY DIFFRACTION;

NEW JERSEY; UNITED STATES;

EID: 77953180395     PISSN: 0003004X     EISSN: None     Source Type: Journal    
DOI: 10.2138/am.2010.3415     Document Type: Article

References (46)

1. Abel, E.W. (1973) Lead. In A.F. Trotman-Dickinson, Ed., Comprehensive Inorganic Chemistry, p. 105-146. Pergamon Press, Oxford.
2. Aminoff, G. (1926) Zur kristallographie des trimerits. Geologiska Föreningens i Stockholm Förhandlingar, 48, 19-43.
3. 4 (M = Na, K). Journal of Solid State Chemistry, 71, 361-370.
4. 4 system. Physics and Chemistry of Minerals, 16, 276-285.
5. Brese, N.E. and O'Keeffe, M. (1991) Bond-valence parameters for solids. Acta Crystallographica, B47, 192-197.
6. 4miscibility gap with applications to franklinite-gahnite exsolution intergrowths from the Sterling Hill zinc deposit, New Jersey. Economical Geology, 83, 1447-1452.
7. 4. Physics and Chemistry of Minerals, 20, 594-600.
8. Downs, R.T., Hazen, R.M., and Finger, L.W. (1995) Crystal chemistry of lead aluminosilicate hollandite: A new high-pressure synthetic phase with octahedral Si. American Mineralogist, 80, 937-940.
9. Dunn, P.J. (1985) The lead silicates from Franklin, New Jersey: Occurrence and composition. Mineralogical Magazine, 49, 721-727.
10. 4. Tschermaks Mineralogishe und Petrographische Mitteilungen, 20, 1-12.
11. 4). Soviet Physics. Crystallography, 6, 733-739.
12. 4. Canadian Mineralogist, 43, 759-767.
13. Grundmann, G., Lehrberger, G., and Schnorrer-Köhler, G. (1990) The El Dragón Mine, Potosí Bolivia. Mineralogical Record, 21, 142.
14. 4 (X = Be, Zn). Journal of Solid State Chemistry, 141, 177-185.
15. Henderson, C.M.B. and Roux, J. (1977) Inversions in sub-potassic nephelines. Contributions to Mineralogy and Petrology, 61, 279-298.
16. Hewins, R.H. and Yersak, T.E. (1977) Conditions of the formation of the Franklin-Sterling ores, New Jersey. Geological Association of Canada Program with Abstracts, 2, 24.
17. Hill, R.J. (1985) Refinement of the structure of orthorhombic PbO (massicot) by Rietveld analysis of neutron powder diffraction data. Acta Crystallographica, C41, 1281-1284.
18. 4. Journal of Inorganic and Nuclear Chemistry, 38, 983-984.
19. 4. Acta Crystallographica, B38, 1112-1116.
20. Ito, J. (1968) Synthesis of some lead calcium zinc silicates. American Mineralogist, 53, 231-240.
21. 4. European Journal of Mineralogy, 13, 403-410.
22. Khavryuchenko, V.D., Khavryuchenko, O.V., and Lisnyak, V.V. (2007) Quantum chemical insight on vibration spectra of silica systems. Molecular Simulation, 33, 531-540.
23. Kihara, K., Hirose, T., and Shinoda, K. (2005) Raman spectra, normal modes and disorder in monoclinic tridymite and its higher temperature orthorhombic modification. Journal of Mineralogical and Petrological Sciences, 100, 91-103. (Pubitemid 43716154)
24. 3 und das trimeritgesetz der verzwillingung. Zietschrift für Krystallographie und Mineralogie, 145, 46-65.
25. Klaska, R., Klaska, K.-H., and Jarchow, O. (1979) Struktur und verwachsung zweie topologisch unterschiedlicher tetraedergerüste der pseudosymmetric Icmm. Zeitschrift für Kristallographie, 149, 135-136.
26. 4. American Mineralogist, 42, 910-911.
27. Leavens, P.B. and Nelen, J.A. (1990) Franklinites from Franklin and Sterling Hill, New Jersey and oxygen fugacities of the deposits. Symposium on Character and Origin of the Franklin-Sterling Hill Orebodies, Lehigh University, Proceedings Volume, 49-62.
28. 4 (M = Co, Zn, Mg). Journal of Solid State Chemistry, 102, 115-125.
29. 4. American Mineralogist, 32, 426-441.
30. Moore, A.D., Leavens, P.B., Jenkins II, R.E., and Altounian, N.M. (2003) Wollastonite at the Sterling Hill Fe-Zn-Mn ore body, Ogdensburg, New Jersey. Mineralogy and Petrology, 79, 225-241.
31. Moore, P.B. and Ribbe, P.H. (1965) A study of "calcium- larsenite" renamed esperite. American Mineralogist, 50, 1170-1178.
32. Palache, C. (1935) The Minerals of Franklin and Sterling Hill, Sussex County, New Jersey. U.S. Geological Survey Professional Paper 180, p. 80-81.
33. Palache, G., Bauer, L.H., and Berman, H. (1928a) Larsenite and calcium-larsenite, new members of the crystolite group, from Franklin, New Jersey. American Mineralogist, 13, 142-144.
34. -(1928b) Larsenite, calcium larsenite, and the associated minerals at Franklin, New Jersey. American Mineralogist, 13, 334-340.
35. Sahl, K. (1970) Lead. 82-A. Crystal Chemistry. In K.H. Wedepohl, Ed., Handbook of Geochemistry II-5, p. 821-826. Springer-Verlag, Berlin.
36. 4. Kristallografiya, 31, 522-527.
37. Sclar, G.B. (1990) Geothermometry at the Sterling Hill zinc deposit, Sussex County, New Jersey (just how hot did it get at Sterling Hill?). Symposium on Character and Origin of the Franklin-Sterling Hill Orebodies, Lehigh University, Proceedings Volume, p. 110-118.
38. Sheldrick, G.M. (1997) The SHELX-97 Manual. University of Göttingen, Germany.
39. - (2007) TWINABS. University of Göttingen, Germany.
40. - (2008) A short history of SHELX. Acta Crystallographica, A64, 112-122.
41. 6, from the Khibina-Lovozero complex, Kola Peninsula, Russia. Canadian Mineralogist, 39, 159-169.
42. Swainson, I.P., Dove, M.T., and Palmer, D.C. (2003) Infrared and Raman spectroscopy studies of the - phase transition in cristobalite. Physics and Chemistry of Minerals, 30, 353-365.
43. Taylor, D. (1983) The structural behavior of tetrahedral framework compounds-a review. Part I. Structural behavior. Mineralogical Magazine, 47, 319-326.
44. -(1984) The structural behavior of tetrahedral framework compounds-a review. Part II. Framework structures. Mineralogical Magazine, 48, 65-79.
45. Yang, H. and Downs, R.T. (2008) Crystal structure of glaucodot, (Co, Fe)AsS, and its relationships to marcasite and arsenopyrite. American Mineralogist, 93, 1183-1186.
46. 4): optical phonons and phase transition(s). Physics and Chemistry of Minerals, 30, 457-462.