Dissolution behaviour and solubility of cellulose in NaOH complex solution

Carbohydrate Polymers

Volumn 81, Issue 3, 2010, Pages 668-674

  Zhang, Shuai ^a,b   Li, Fa Xue ^a   Yu, Jian yong ^a   Hsieh, You Lo ^b  

^a DONGHUA UNIVERSITY   (China)

^b UNIVERSITY OF CALIFORNIA   (United States)

Author keywords

Cellulose; Direct dissolution; Gelation; NaOH complex; Stability

Indexed keywords

AQUEOUS MIXTURES; CELLULOSE CONTENT; CELLULOSE MOLECULES; COMPLEX SOLUTION; COMPLEX STABILITY; DIRECT DISSOLUTION; DISSOLUTION BEHAVIOUR; DISSOLUTION PROCESS; GEL TEMPERATURES; HIGH CONCENTRATION; MOLECULAR HYDROGEN; NAOH COMPLEX; NAOH SOLUTIONS; NETWORK STRUCTURES; NON-DERIVATIZING SOLVENTS; NOVEL SOLVENTS; SOLUTION TEMPERATURE; STABLE SOLUTIONS;

COAGULATION; DISSOLUTION; GELATION; GELS; HYDROGEN BONDS; QUANTUM ENTANGLEMENT; SOLVENTS;

CELLULOSE;

CELLULOSE; COAGULATION; COMPLEX COMPOUNDS; DISSOLVING; GELATION; GELS; HYDROGEN BONDS; QUANTUM CHEMISTRY; SODIUM HYDROXIDE; SOLVENTS; STABILITY;

EID: 77953137437     PISSN: 01448617     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.carbpol.2010.03.029     Document Type: Article

References (40)

1. Brown W., and Wiskston R. Viscosity-molecular weight relationship for cellulose incadoxen and hydrodynamic interpretation. European Polymer Journal 1 (1965) 1-10
2. Cai J., Liu Y.T., and Zhang L.N. Dilute solution properties of cellulose in LiOH/urea aqueous system. Journal of Polymer Science Part B: Polymer Physics 44 (2006) 3093-3101
3. Cai J., and Zhang L.N. Rapid dissolution of cellulose in LiOH/urea and NaOH/urea aqueous solutions. Macromolecular Bioscience 5 (2005) 539-548
4. Cai J., and Zhang L.N. Unique gelation behavior of cellulose in NaOH/urea aqueous solution. Biomacromolecules 7 (2006) 183-189
5. Cai J., Zhang L.N., Chang C.Y., Cheng G.Z., Chen X.M., and Chu B. Hydrogen-bond-induced inclusion complex in aqueous cellulose/LiOH/urea solution at low temperature. ChemPhysChem 8 (2007) 1572-1579
6. Cédric R., Tatiana B., Patrick N., and Olivier B. Structure of cellulose-soda solutions at low temperatures. Biomacromolecules 2 (2001) 687-693
7. 4SCN system. Journal of Polymer Science Part A: Polymer Chemistry 32 (1994) 229-239
8. Dogan H., and Hilmioglu N.D. Dissolution of cellulose with NMMO by microwave heating. Carbohydrate Polymers 75 (2009) 90-94
9. Egal M., Budtova T., and Navard P. Structure of aqueous solutions of microcrystalline cellulose/sodium hydroxide below 0 °C and the limit of cellulose dissolution. Biomacromolecules 8 (2007) 2282-2287
10. Fink H.P., Weigel P., Purz H.J., and Ganster J. Structure formation of regenerated cellulose materials from NMMO-solutions. Progress in Polymer Science 26 (2001) 1473-1524
11. Gagnaire D., Mancier D., and Vincendon M. Cellulose organic solutions: A nuclear magnetic resonance investigation. Journal of Polymer Science Part A: Polymer Chemistry 18 (1980) 13-25
12. Hattori M., Koga T., Shimaya Y., and Saito M. Aqueous calcium thio-cyanate solutions as a cellulose solvent structure and interactions with cellulose. Polymer Journal 30 (1998) 43-48
13. Heo Y., and Larson R.G. The scaling of zero-shear viscosities of semidilute polymer solutions with concentration. Journal of Rheology 49 (2005) 1117-1128
14. Isogai A., and Atalla R.H. Dissolution of cellulose in aqueous NaOH solutions. Cellulose 5 (1998) 309-319
15. Jin H.J., Zha C.X., and Gu L.X. Direct dissolution of cellulose in NaOH/thiourea/urea aqueous solution. Carbohydrate Research 342 (2007) 851-858
16. 13NMR. Polymer Journal 16 (1984) 857-866
17. Kamide K., and Saito M. Light scattering and viscometric study of cellulose in aqueous lithium hydroxide. Polymer Journal 18 (1986) 569-579
18. Klemm D., Heublein B., Fink H.-P., and Bohn A. Cellulose: Fascinating biopolymers and sustainable raw material. Angewandte Chemie International Edition 44 (2005) 3358-3393
19. Kuang Q.L., Zhao J.C., Niu Y.H., Zhang J., and Wang Z.G. Celluloses in an ionic liquid the rheological properties of the solutions spanning the dilute and semidilute regimes. Journal of Physical Chemistry B 112 (2008) 10234-10240
20. Kunze J., and Fink H.P. Structural changes and activation of cellulose by caustic soda solution with urea. Macromolecular Symposia 223 (2005) 175-188
21. Loubinoux D., and Chaunis S. An experimental approach to spinning new cellulose fibers with N-methylmorpholine oxide as a solvent. Textile Research Journal 57 (1987) 61-65
22. Marson G.A., and El Seoud O.A. Cellulose dissolution in lithium chloride/N,N-dimethylacetamide solvent system: Relevance of kinetics of decrystallization to cellulose derivatization under homogeneous solution conditions. Journal of Polymer Science Part A: Polymer Chemistry 37 (1999) 3738-3744
23. McCormick C.L., Callais P.A., and Hutchinson Jr. B.H. Solution studies of cellulose in lithium chloride and N,N-dimethylacetamide. Macromolecules 18 (1985) 2394-2401
24. 13C NMR studies of cellulose and cellulose oligomers in ionic liquid solutions. Chemical Communications 12 (2005) 1557-1559
25. 13C-NMR spectroscopy. Progress in Polymer Science 19 (1994) 29-78
26. 13NMR spectroscopic study of the homogeneous sulfation of cellulose and xylan in the dinitrogen tetroxide-DMF system. Carbohydrate Research 164 (1987) 107-116
27. Su C., and Puls R.W. Kinetics of trichloroethene reduction by zerovalent iron and tin: Pretreatment effect, apparent activation energy, and intermediate products. Environmental Science & Technology 33 (1999) 163-168
28. Swatloski R.P., Spear S.K., Holbrey J.D., and Rogers R.D. Dissolution of cellulose with ionic liquids. Journal of the American Chemical Society 124 (2002) 4974-4975
29. Tamai N., Aono H., Tatsumi D., and Matsumoto T. Differences in rheological properties of solutions of plant and bacterial cellulose in LiCl/N,N-dimethylacetamide. Journal of the Society of Rheology, Japan 31 (2003) 119-130
30. Ueberreiter K. The solution process. In: Crank J., and Park G.S. (Eds). Diffusion in polymers (1968), Academic Press, New York, NY 219-257
31. Wang Y., and Deng Y.L. The kinetics of cellulose dissolution in sodium hydroxide solution at low temperatures. Biotechnology and Bioengineering 102 (2009) 1398-1405
32. Weng L.H., Zhang L.N., Ruan D., Shi L.H., and Xu J. Thermal gelation of cellulose in a NaOH/thiourea aqueous solution. Langmuir 20 (2004) 2086-2093
33. Yamashiki T., Kamide K., Okajima K., Kowsaka K., Matsui T., and Fukase H. Some characteristic features of dilute aqueous alkali solutions of specific alkali concentration (2.5 mol/l) which possess maximum solubility power against cellulose. Polymer Journal 20 (1988) 447-457
34. Zhang L.N., Ruan D., and Gao S.J. Dissolution and regeneration of cellulose in NaOH/thiourea aqueous solution. Journal of Polymer Science Part B: Polymer Physics 40 (2002) 1521-1529
35. Zhang L.N., Ruan D., and Zhou J.P. Structure and properties of regenerated cellulose films prepared from cotton linters in NaOH/urea aqueous solution. Industrial & Engineering Chemistry Research 40 (2001) 5923-5928
36. Zhang L.N., Yang G., and Liu H. Recent progress in studies of cellulose in China. Cellulose Communications 6 (1999) 89-96
37. Zhang S., Li F.X., Yu J.Y., Fu C.F., and Gu L.X. Directly preparation of a membrane from unsubstituted cellulose in NaOH complex solution. Iranian Polymer Journal 18 (2009) 767-776
38. Zhang S., Li F.X., Yu J.Y., and Gu L.X. Novel fibers prepared from cellulose in NaOH/thiourea/urea aqueous solution. Fibers and Polymers 10 (2009) 34-39
39. Zhou J.P., and Zhang L.N. Solubility of cellulose in NaOH/urea aqueous solution. Polymer Journal 32 (2000) 866-870
40. Zhou J.P., Zhang L.N., and Cai J. Behavior of cellulose in NaOH/urea aqueous solution characterized by light scattering and viscometry. Journal of Polymer Science Part B: Polymer Physics 42 (2004) 347-353