Unusual reversal of enantioselectivity in the proline-mediated α-amination of aldehydes induced by tertiary amine additives

Journal of the American Chemical Society

Volumn 132, Issue 22, 2010, Pages 7598-7599

  Blackmond, Donna G ^a,b   Moran, Antonio ^a   Hughes, Matthew ^a   Armstrong, Alan ^a  

^a IMPERIAL COLLEGE LONDON   (United Kingdom)

^b SCRIPPS RESEARCH INSTITUTE   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

KINETIC PROFILES; ORGANIC BASIS; STEREOCHEMICAL MODELS; TERTIARY AMINE;

ALDEHYDES; ELECTRON TRANSITIONS; ENANTIOSELECTIVITY;

AMINES;

ALDEHYDE; PROLINE; TERTIARY AMINE;

AMINATION; ARTICLE; CATALYSIS; CATALYST; ENANTIOSELECTIVITY; KINETICS; RACEMIZATION;

ALDEHYDES; AMINATION; AMINES; CATALYSIS; PROLINE; STEREOISOMERISM;

EID: 77953112544     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja102718x     Document Type: Article

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