Viscosity of cellulose-imidazolium-based ionic liquid solutions

Journal of Physical Chemistry B

Volumn 114, Issue 21, 2010, Pages 7222-7228

  Sescousse, Romain ^a   Le, Kim Anh ^a   Ries, Michael E ^b   Budtova, Tatiana ^a  

^a PSL RESEARCH UNIVERSITY   (France)

^b UNIVERSITY OF LEEDS   (United Kingdom)

Author keywords

[No Author keywords available]

Indexed keywords

ARRHENIUS PLOTS; CELLULOSE; CHLORINE COMPOUNDS; DISSOLUTION; IONIC LIQUIDS; IONIZATION OF LIQUIDS; SOLVENTS; VISCOMETERS; VISCOSITY;

1-BUTYL-3-METHYLIMIDAZOLIUM CHLORIDE; ARRHENIUS ACTIVATION ENERGY; CELLULOSE SOLUTIONS; CONCAVE SHAPE; DATA ANALYSIS; HUGGINS EQUATION; HYDRODYNAMIC PROPERTIES; IMIDAZOLIUM-BASED IONIC LIQUID; IMPROVED METHODS; INTRINSIC VISCOSITY; MICROCRYSTALLINE CELLULOSE; POLYMER CONCENTRATIONS; POWER-LAW FUNCTIONS; SOLUTION VISCOSITY; THERMODYNAMIC QUALITY;

ACTIVATION ENERGY;

ACTIVATION ENERGY; CELLULOSE; CHLORINE COMPOUNDS; CONCENTRATION; DISSOLVING; IONIZATION; SOLVENTS; VISCOMETERS; VISCOSITY;

EID: 77952939654     PISSN: 15206106     EISSN: 15205207     Source Type: Journal    
DOI: 10.1021/jp1024203     Document Type: Article

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35. The melting temperature of BMIMC, as given by the manufacturer, is around 70 °C. Our mesaurements performed with DSC show that the melting temperature is about 55 °C. A detailed investigation of BMIMCl and cellulose-BMIMCl solutions phase transitions is a subject of another study. What we want to emphasize here is that at the lowest temperatures studied BMIMCl is much closer to its solid-liquid phase transition temperature as compared to EMIMAc for which the melting temperature is so low that it have never been reported.