Influence of crystal expansion/contraction on zeolite membrane permeation

Journal of Membrane Science

Volumn 357, Issue 1-2, 2010, Pages 98-104

  Sorenson, Stephanie G ^a   Payzant, E Andrew ^b   Noble, Richard D ^a   Falconer, John L ^a  

^a University of Colorado at Boulder   (United States)

^b OAK RIDGE NATIONAL LABORATORY   (United States)

Author keywords

B ZSM 5 zeolite; SAPO 34 zeolite; Unit cell dimensions; X ray diffraction; Zeolite expansion and contraction

Indexed keywords

B-ZSM-5 ZEOLITE; EXPANSION AND CONTRACTION; SAPO-34; SAPO-34 ZEOLITE; UNIT-CELL DIMENSIONS; ZSM-5 ZEOLITES;

ADSORBATES; ADSORPTION; BORON; BORON COMPOUNDS; BUTANE; CRYSTALS; DEFECTS; HEXANE; LIQUEFIED PETROLEUM GAS; METHANOL; PERMEATION; SILICATE MINERALS; X RAY DIFFRACTION; X RAY POWDER DIFFRACTION;

LOADING;

BORON; BUTANE; CARBON DIOXIDE; HEXANE; METHANOL; SILICALITE; SILICON DIOXIDE; UNCLASSIFIED DRUG; ZEOLITE;

ADSORPTION; ARTICLE; CELL VOLUME; CHEMICAL REACTION; CONTROLLED STUDY; CORRELATION FUNCTION; CRYSTAL STRUCTURE; MEMBRANE PERMEABILITY; MEMBRANE TRANSPORT; POWDER; PRIORITY JOURNAL;

EID: 77952838497     PISSN: 03767388     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.memsci.2010.04.020     Document Type: Article

References (39)

1. Yu M., Amundsen T.J., Hong M., Falconer J.L., Noble R.D. Flexible nanostructure of MFI zeolite membranes. J. Membr. Sci. 2007, 298:182.
2. Yu M., Falconer J.L., Amundsen T.J., Hong M., Noble R.D. A controllable nanometer-sized valve. Adv. Mater. 2007, 19:3032.
3. Yu M., Falconer J.L., Noble R.D. Characterizing non-zeolitic pore volume in zeolite membranes by temperature-programmed desorption. Micropor. Mesopor. Mater. 2008, 113:224.
4. Mentzen B.F. Energetics and siting of sorbed molecules in zeolites by computer-simulations-comparison with calorimetric and structural results. II. n-Alkanes in silicalite. Mater. Res. Bull. 1995, 30:1333.
5. Mentzen B.F. Structural correlations between the framework symmetry of highly siliceous MFI zeolitic materials (silicalite, ZSM-5 for Si/Al>75) and the location or the geometry of sorbed molecules. Mater. Res. Bull. 1992, 27:831.
6. Mentzen B.F., Gelin P. The silicate p-xylene system. Part I. Flexibility of the MFI framework and sorption mechanism observed during p-xylene pore-filling by X-ray-powder diffraction at room-temperature. Mater. Res. Bull. 1995, 30:373.
7. Mentzen B.F., Favre R., Cauwet F. Characterization of guest molecules sorbed in zeolites of known structure. Part VI. Localization of methanol at several pore fillings in a highly siliceous MFI silicalite material. Mater. Res. Bull. 1994, 29:587.
8. Sorenson S.G., Smyth J.R., Kocirik M., Zikanova A., Noble R.D., Falconer J.L. Adsorbate-induced expansion of silicalite-1 crystals. Ind. Eng. Chem. Res. 2008, 47:9611.
9. Sorenson S.G., Smyth J.R., Noble R.D., Falconer J.L. Correlation of crystal lattice expansion and membrane properties for MFI zeolites. Ind. Eng. Chem. Res. 2009, 48:10021.
10. Lee J.B., Funke H.H., Noble R.D., Falconer J.L. High selectivities in defective MFI membranes. J. Membr. Sci. 2008, 321:309.
11. Tokay B., Falconer J.L., Noble R.D. Alcohol and water adsorption and capillary condensation in MFI zeolite membranes. J. Membr. Sci. 2009, 334:23.
12. Bai C.S., Jia M.D., Falconer J.L., Noble R.D. Preparation and separation properties of silicalite composite membranes. J. Membr. Sci. 1995, 105:79.
13. 6 isomers in ZSM-5 tubular membranes. Ind. Eng. Chem. Res. 1998, 37:166.
14. Lai Z.P., Tsapatsis M. Gas and organic vapor permeation through b-oriented MFI membranes. Ind. Eng. Chem. Res. 2004, 43:3000.
15. Tuan V.A., Falconer J.L., Noble R.D. Alkali-free ZSM-5 membranes: preparation conditions and separation performance. Ind. Eng. Chem. Res. 1999, 38:3635.
16. Choi J., Ghosh S., King L., Tsapatsis M. MFI zeolite membranes from a- and randomly oriented monolayers. Adsorption 2006, 12:339.
17. Gade S.K., Tuan V.A., Gump C.J., Noble R.D., Falconer J.L. Highly selective separation of n-hexane from branched, cyclic and aromatic hydrocarbons using B-ZSM-5 membranes. Chem. Commun. 2001, (1):601.
18. Bhange D.S., Ramaswamy V. High temperature thermal expansion behavior of silicalite-1 molecular sieve: in situ HTXRD study. Micropor. Mesopor. Mater. 2007, 103:235.
19. Bhange D.S., Ramaswamy V. Negative thermal expansion in silicalite-1 and zirconium silicalite-1 having MFI structure. Mater. Res. Bull. 2006, 41:1392.
20. Marinkovic B.A., Jardim P.M., Saavedra A., Lau L.Y., Baehtz C., de Avillez R.R., Rizzo F. Negative thermal expansion in hydrated HZSM-5 orthorhombic zeolite. Micropor. Mesopor. Mater. 2004, 71:117.
21. Marinkovic B.A., Jardim P.M., Rizzo F., Saavedra A., Lau L.Y., Suard E. Complex thermal expansion properties of Al-containing HZSM-5 zeolite: a X-ray diffraction, neutron diffraction and thermogravimetry study. Micropor. Mesopor. Mater. 2008, 111:110.
22. Jardim P.M., Marinkovic B.A., Saavedra A., Lau L.Y., Baehtz C., Rizzo F. A comparison between thermal expansion properties of hydrated and dehydrated orthorhombic HZSM-5 zeolite. Micropor. Mesopor. Mater. 2004, 76:23.
23. Bhange D.S., Ramaswamy V. Thermal stability of the Mobil Five type metallosilicate molecular sieves-an in situ high, temperature X-ray diffraction study. Mater. Res. Bull. 2007, 42:851.
24. Amri M., Walton R.I. Negative thermal expansion in the aluminum and gallium phosphate zeotypes with CHA and AEI structure types. Chem. Mater. 2009, 21:3380.
25. 4 separations. Adv. Mater. 2006, 18:2601.
26. Lovallo M.C., Tsapatsis M. Preferentially oriented submicron silicalite membranes. AIChE J. 1996, 42:3020.
27. 2 separation by catalytic cracking of methyldiethoxysilane. Ind. Eng. Chem. Res. 2005, 44:4035.
28. Carreon M.A., Li S.G., Falconer J.L., Noble R.D. SAPO-34 seeds and membranes prepared using multiple structure directing agents. Adv. Mater. 2008, 20:729.
29. Bowen T.C., Wyss J.C., Noble R.D., Falconer J.L. Measurements of diffusion through a zeolite membrane using isotopic-transient pervaporation. Micropor. Mesopor. Mater. 2004, 71:199.
30. Czaplewsi K.F., Snurr R.Q. Hierarchical approach for simulation of binary adsorption in silicalite. AIChE J. 1999, 45:2223.
31. Chmelik C., Heinke L., Karger J., Schmidt W., Shah D.B., van Baten J.M., Krishna R. Inflection in the loading dependence of the Maxwell-Stefan diffusivity of iso-butane in MFI zeolite. Chem. Phys. Lett. 2008, 459:141.
32. Lee J.B., Funke H., Noble R.D., Falconer J.L. Adsorption-induced expansion of defects in MFI membranes. J. Membr. Sci. 2009, 341:238.
33. Krishna R., Baur R. Modeling issues in zeolite based separation processes. Sep. Purif. Technol. 2003, 33:213.
34. Wei Y., Zhang D., Xu L., Chang F., He Y., Meng S., Su B.-l., Liu Z. Synthesis, characterization and catalytic performance of metal-incorporated SAPO-34 for chloromethane transformation to light olefins. Catal. Today 2008, 131:262.
35. 4-18. J. Phys. Chem. 1993, 97:12042.
36. Vanleeuwen M.E. Derivation of Stockmayer potential parameters for polar fluids. Fluid Phase Equilib. 1994, 99:1.
37. 2 permeation across zeolite membranes. Ind. Eng. Chem. Res. 2007, 46:2974.
38. Hong M., Li S.G., Falconer J.L., Noble R.D. Hydrogen purification using a SAPO-34 membrane. J. Membr. Sci. 2008, 307:277.
39. 4 separations: effect of Si/Al ratio. Micropor. Mesopor. Mater. 2008, 110:310.