Axially chiral anilido-aldimine aluminum complexes with a pseudobinaphthyl skeleton

Chemistry Letters

Volumn 39, Issue 6, 2010, Pages 643-645

  Hayashi, Kazuhiro ^a   Nakajima, Yumiko ^a   Ozawa, Fumiyuki ^a   Kawabata, Takeo ^a  

^a KYOTO UNIVERSITY   (Japan)

Author keywords

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Indexed keywords

EID: 77952686453     PISSN: 03667022     EISSN: 13480715     Source Type: Journal    
DOI: 10.1246/cl.2010.643     Document Type: Article

References (12)

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8. 2: C, 80.91; H, 8.19; N, 5.55%. Found: C, 80.96; H, 8.26; N, 5.58%.
9. See Supporting Information for crystallographic data of 3 b, which is available electronically on the CSJ-Jouraal Web site http://www.csj.jp/journals/ chem-lett. The crystallographic data have been deposited with Cambridge Crystallographic Data Centre as a supplementary publication No. CCDC-771984. Copies of the data can be obtained free of charge via www.ccdc.cam.ac.uk/conts/ retrieving.html (or from the Cambridge Crystallographic Data Centre, 12, Union Road, Cambridge, CB2 IEZ, UK; fax: +44 1223 336033; or deposit@ccdc.cam.ac.uk
10. Z.-Y. Chai, C Zhang, Z.-X. Wang, Organometallics 2008, 27, 1626.
11. The sum of the internal angles of the six-membered chelate ring is 712°, which is comparable with 720° for the completely planar six-membered ring.
12. Attempted formation of anilido-aldimine aluminum complexes from 4 or the related diarylamines with high configurational stability under the conditions similar to those for 7 was not successful so far.