On the origin of siphonariid polypropionates: Total synthesis of baconipyrone A, Baconipyrone C, and siphonarin B via their putative common precursor

Journal of the American Chemical Society

Volumn 132, Issue 20, 2010, Pages 7210-7215

  Beye, Garrison E ^a   Ward, Dale E ^a  

^a UNIVERSITY OF SASKATCHEWAN   (Canada)

Author keywords

[No Author keywords available]

Indexed keywords

BIOMIMETIC SYNTHESIS; BIOSYNTHETIC PRECURSORS; CASCADE PROCESS; CLAISEN REARRANGEMENT; COMPLEX MIXTURE; CONTROL EXPERIMENTS; ENANTIOSELECTIVE; ENANTIOSELECTIVE TOTAL SYNTHESIS; HEMIACETALS; KETONIZATION; NON-ENZYMATIC; TOTAL SYNTHESIS;

BIOMIMETICS; BIOSYNTHESIS; ETHERS; EXPERIMENTS;

CYCLIZATION;

14 (6 ETHYL 3,5 DIMETHYL 4 OXO 4H PYRAN 2 YL) 5,11 DIHYDROXY 4,6,8,10,12 PENTAMETHYLPENTADECANE 3,7,9,13 TETRAONE; ALUMINUM OXIDE; BACONIPYRONE A; BACONIPYRONE C; CALOUNDRIN B; IMIDAZOLE; PROPIONIC ACID DERIVATIVE; SIPHONARIN B; THIOPYRAN DERIVATIVE; UNCLASSIFIED DRUG;

ARTICLE; BIOSYNTHESIS; CLAISEN REARRANGEMENT; CONTROLLED STUDY; CYCLIZATION; ENANTIOSELECTIVITY; ISOMERIZATION; KINETICS; NONHUMAN; PRECURSOR; SIPHONARIA ZELANDICA; SNAIL; THERMODYNAMICS;

ISOMERISM; KETONES; POLYMERS; PROPIONATES; PYRONES; SPIRO COMPOUNDS;

EID: 77952563153     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja102356j     Document Type: Article

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