Complexation and thermodynamic studies of oxathiadibenzocrown ethers with Cu2+, Pb2+, Zn2+ and Cd2+ ions

Journal of Inclusion Phenomena and Macrocyclic Chemistry

Volumn 67, Issue 1-2, 2010, Pages 81-84

  Ashram, M ^a   Bqaeen, M ^a   Mizyed, S ^b  

^a MUTAH UNIVERSITY   (Jordan)

^b YARMOUK UNIVERSITY   (Jordan)

Author keywords

Conductivity; Crown ethers; Oxathiadibenzocrown ethers; Stability constant; Transition metals

Indexed keywords

EID: 77952553823     PISSN: 09230750     EISSN: None     Source Type: Journal    
DOI: 10.1007/s10847-009-9676-9     Document Type: Article

References (19)

1. Gunnlaugsson, T., Leonard, J. P., Murray, N. S.: Highly selective colorimetric naked-eye Cu(II) detection using an azobenzene chemosensor. Org. Lett. 6, 1557-1560 (2004).
2. Kim, J. Y., Kim, C. R., Lees, H., Lee, J. H., Ki, J. S.: UV band splitting of chromogenic azo-coupled calix[4]crown upon cation complexation. J. Org. Chem. 68, 1933-1937 (2003).
3. Vetrichelvan, M., Lai, Y.-H., Mok, K. F.: 3, 11, 19-Trithia[3. 3. 3]pyridinophane: structural diversity in its transition metal complexes. Eur. J. Inorg. Chem. 2086-2095 (2004).
4. III of 2, 5, 8-trithia[9] (2, 9)-1, 10-phenanthrolinophane. J. Chem. Soc., Dalton Trans. 4401-4406 (1997).
5. Watzky, M. A., Waknine, D., Heeg, M. J., Endicott, J. F., Ochrymowyzc, L. A.: Tetradentate macrocyclic complexes of platinum. Evaluation of the stereochemical alterations of redox behavior and the x-ray crystal structure of (1, 4, 7, 10-tetrathiacyclododecane)platinum(II) chloride. Inorg. Chem. 32, 4882-4888 (1993).
6. 5=1, 4, 7, 10, 13-pentathiacyclopentadecane). J. Chem. Soc., Dalton Trans. 2803-2808 (1992).
7. Lee, S. J., Jung, J. H., Seo, J., Yoon, I., Park, K.-M., Lindoy, L. F., Lee, S. S.: A chromogenic macrocycle exhibiting cation-selective and anion-controlled color change: an approach to understanding structure-color relationships. Org. Lett. 8, 1641-1643 (2006).
8. 2O macrocycles: effect of ligand isomerism on the structural diversity. Inorg. Chem. 45, 952-954 (2006).
9. I in a single macrocycle. Inorg. Chem. 45, 3487-3489 (2006).
10. 2X (X = S, O and NH) donor sets. J. Chem. Soc., Dalton Trans. 2352-2354 (2005).
11. 2-macrocycle: twist-and-squeeze type metal binding via synergic action of metal-ligand and metal-π interaction. Tetrahedron Lett. 48, 8464-8467 (2007).
12. 2. Mendeleev Commun. 19, 21-23 (2009).
13. Ashram, M.: A convenient synthesis of novel 20-, 23-, and 26-membered macrocyclic oxathiadibenzo- and oxathiadinaphthalenocrown ethers, Part 1. Z. Naturforsch 60b, 891-900 (2005).
14. Mizyed, S. A.: Thermodynamic study of the association of alkali metal cations with some crown ethers. M. Sc. Dissertation, Yarmouk University, Jordan (1987).
15. Tawarah, K. M., Mizyed, S. A.: A conductance study of the binding of benzo-15-crown-5 with alkali cations in acetonitrile. J. Incl. Phenom. Macrocycl. Chem. 6, 583-591 (1988).
16. Pourghobadi, Z., Majidi, F., Asli, M., Parasa, F., Moghimi, M., Ganjali, M., Aghabozorg, H., Shamsipur, M.: Synthesis of a new triazine derived macrocycle and a thermodynamic study of its complexes with some transition and heavy metal ions in acetonitrile solution. Pol. J. Chem. 74, 837-846 (2000).
17. Pearson, R. G.: Hard and soft acids and bases. J. Am. Chem. Soc. 85(22), 3533-3539 (1963).
18. Alpb, H., Kantekina, H., Ocaka, U.: Synthesis and metal ion binding properties of thiaaza crown macrocycles. J. Hazard. Mater 159, 519-522 (2008).
19. Mizyed, S., Ashram, M., Saymeh, R., Marji, D.: A thermodynamic study of the charge transfer complexes of iodine with different tert-butylcalix[4]crowns. Z. Naturforsch 60, 1133-1137 (2005).