Formation and decomposition of diazo ethers under acidic conditions. Effects of ethanol concentration, acidity, and temperature on the ethanolysis of 4-methylbenzenediazonium ions

Helvetica Chimica Acta

Volumn 93, Issue 5, 2010, Pages 877-887

  Fernández Alonso, Alejandra ^a   Bravo Díaz, Carlos ^a  

^a UNIVERSITY OF VIGO   (Spain)

Author keywords

[No Author keywords available]

Indexed keywords

ACIDIC CONDITIONS; CHROMATOGRAPHIC TECHNIQUES; COMPETITIVE MECHANISMS; COMPLEX KINETICS; COUPLING MECHANISM; DEDIAZONIATION; EFFECTS OF TEMPERATURE; ETHANOL CONCENTRATIONS; ETHANOLYSIS; EXPERIMENTAL CONDITIONS; FIRST-ORDER; HETEROLYTIC MECHANISMS; HPLC ANALYSIS; INFLEXION POINT; PRODUCT DISTRIBUTIONS; RADICAL PROCESS; REACTION MECHANISM; REACTION MIXTURE; REDUCTION PRODUCTS; S-SHAPED; SOLVENT COMPOSITION; SUBSTITUTION PRODUCTS; THERMODYNAMIC PARAMETER;

BELT DRIVES; EQUILIBRIUM CONSTANTS; ETHANOL; ETHERS; IONS; ORGANIC COMPOUNDS; TOLUENE;

ACIDITY;

4 METHYLBENZENEDIAZONIUM; ALCOHOL; DIAZO ETHER; DIAZONIUM COMPOUND; PARA CRESOL; PHENETOLE; SOLVENT; TOLUENE; UNCLASSIFIED DRUG;

ACIDITY; ARTICLE; CHEMICAL COMPOSITION; CHEMICAL STRUCTURE; CROSS COUPLING REACTION; DECOMPOSITION; EQUILIBRIUM CONSTANT; HIGH PERFORMANCE LIQUID CHROMATOGRAPHY; KINETICS; PRIORITY JOURNAL; REACTION ANALYSIS; SPECTROMETRY; TEMPERATURE; THERMODYNAMICS;

EID: 77952479514     PISSN: 0018019X     EISSN: 15222675     Source Type: Journal    
DOI: 10.1002/hlca.200900322     Document Type: Article

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