Computational design of active, self-reinforcing gels

Journal of Physical Chemistry B

Volumn 114, Issue 19, 2010, Pages 6316-6322

  Yashin, Victor V ^a   Kuksenok, Olga ^a   Balazs, Anna C ^a  

^a University of Pittsburgh   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

BIOLOGY; BIOMIMETICS; COMPUTER SIMULATION; METAL IONS; REINFORCEMENT; RHENIUM COMPOUNDS;

BELOUSOV-ZHABOTINSKY REACTIONS; COMPLEX FORMS; COMPUTATIONAL DESIGN; CROSS-LINK DENSITIES; CROSS-LINKED GELS; LIVING ORGANISMS; MECHANICAL CONTACT; OXIDATION AND REDUCTION; POLYMER GELS; SELF PROTECTING; SIGNALING PROCESS; TERPYRIDINES; THEORETICAL MODELING;

GELS;

EID: 77952474053     PISSN: 15206106     EISSN: 15205207     Source Type: Journal    
DOI: 10.1021/jp101009h     Document Type: Article

References (27)

1. Echinoderms; Heinzeller, T., Nebelsick, J., Eds.; Taylor & Francis: London, 2004.
2. Capadona, J. R.; Shanmuganathan, K.; Tyler, D. J.; Rowan, S. J.; Weder, C. Stimuli-Responsive Polymer Nanocomposites Inspired by the Sea Cucumber Dermis Science 2008, 319, 1370-1374
3. Raven, P. H.; Evert, R. F.; Eichhorn, S. E. Biology of Plants; W.H. Freeman: New York, 2005.
4. Yoshida, R.; Takahashi, T.; Yamaguchi, T.; Ichijo, H. Self-Oscillating Gel J. Am. Chem. Soc. 1996, 118, 5134-5135
5. Yoshida, R. Self-Oscillating Polymer and Gels as Novel Biomimetic Materials Bull. Chem. Soc. Jpn. 2008, 81, 676-688
6. Kuksenok, O.; Yashin, V. V.; Balazs, A. C. Mechanically Induced Chemical Oscillations and Motion in Responsive Gels Soft Matter 2007, 3, 1138-1144
7. Kuksenok, O.; Yashin, V. V.; Balazs, A. C. Global Signaling of Localized Impact in Chemo-responsive Gels Soft Matter 2009, 5, 1835-1839
8. Fustin, C. A.; et al. Nanoporous Thin Films from Self-Assembled Metallo-Supramolecular Block Copolymers Adv. Mater. 2005, 17, 1162-1165
9. Fustin, C. A.; Guillet, P.; Schubert, U. S.; Gohy, J. F. Metallo-Supramolecular Block Copolymers Adv. Mater. 2007, 19, 1665-1673
10. 2. Comparisons Between the Chemical and Physical Properties of a Cis-Trans Isomeric Pair Inorg. Chem. 1980, 19, 1404-1407
11. Enoki, T.; et al. Frustrations in Polymer Conformation in Gels and Their Minimization Through Molecular Imprinting Phys. Rev. Lett. 2000, 85, 5000-5003
12. Alvarez-Lorenzo, C.; et al. Polymer Gels That Memorize Elements of Molecular Conformation Macromolecules 2000, 33, 8693-8697
13. Ito, K.; et al. Multiple Point Adsorption in a Heterogeneous Gel and the Tanaka Approach to Imprinting: Experiment and Theory Prog. Polym. Sci. 2003, 28, 1489-1515
14. Alvarez-Lorenzo, C.; Concheiro, A.; Chuang, J.; Grosberg, A. Yu. Imprinting Using Smart Polymers. In Smart polymers. Applications in biotechnology and biomedicine, 2nd ed.; Galaev, I.; Mattiasson, B., Eds.; CRC Press: Boca Raton, FL, 2008; pp 211 - 245.
15. 2+-Catalyzed Belousov-Zhabotinsky Reaction Under Different Solute Compositions J. Phys. Chem. A 2002, 106, 612-620
16. Tyson, J. J. A Quantitative Account of Oscillations, Bistability, and Traveling Waves in the Belousov-Zhabotinsky Reaction. In Oscillations and Traveling Waves in Chemical Systems; Field, R. J.; Burger, M., Eds.; Wiley: New York, 1985; pp 93 - 144.
17. Scott, S. K. Oscillations, Waves, and Chaos in Chemical Kinetics; Oxford University Press: New York, 1994.
18. Yashin, V. V.; Balazs, A. C. Modeling Polymer Gels Exhibiting Self-Oscillations Due to the Belousov-Zhabotinsky Reaction Macromolecules 2006, 39, 2024-2027
19. Yashin, V. V.; Balazs, A. C. Pattern Formation and Shape Changes in Self-Oscillating Polymer Gels Science 2006, 314, 798-801
20. Yashin, V. V.; Balazs, A. C. Theoretical and Computational Modeling of Self-Oscillating Polymer Gels J. Chem. Phys. 2007, 126, 124707; 17 pages
21. Tyson, J. J.; Fife, P. C. Target Patterns in a Realistic Model of the Belousov-Zhabotinskii Reaction J. Chem. Phys. 1980, 73, 2224-2237
22. Flory, P. J. Elasticity of Polymer Networks Cross-Linked in States of Strain Trans. Faraday Soc. 1960, 56, 722-743
23. Drozdov, A. D. Finite Elasticity and Viscoelasticity: A Course in the Nonlinear Mechanics of Solids; World Scientific: Singapore, 1996.
24. Yoshida, R.; Kokufuta, E.; Yamaguchi, T. Beating Polymer Gels Coupled With a Nonlinear Chemical Reaction Chaos 1999, 9, 260-266
25. Miyakawa, K.; Sakamoto, F.; Yoshida, R.; Kokufuta, E.; Yamaguchi, T. Chemical Waves in Self-Oscillating Gels Phys. Rev. E 2000, 62, 793-798
26. Hirotsu, S. Softening of Bulk Modules and Negative Poissons Ratio Near the Volume Phase Transition of Polymer Gels J. Chem. Phys. 1991, 94, 3949-3957
27. Sasaki, S.; Koga, S.; Yoshida, R.; Yamaguchi, T. Mechanical Oscillation Coupled With the Belousov-Zhabotinsky Reaction in Gel Langmuir 2003, 19, 5595-5600