Catalytic hydrodechlorination of 4-Chlorophenol in an aqueous solution with pd/ni catalyst and formic acid

Industrial and Engineering Chemistry Research

Volumn 49, Issue 10, 2010, Pages 4561-4565

  Wang, Shu ^a,b   Yang, Bo ^a,b   Zhang, Tingting ^a,b   Yu, Gang ^a,b   Deng, Shubo ^a,b   Huang, Jun ^a,b  

^a TSINGHUA UNIVERSITY   (China)

^b SHENZHEN UNIVERSITY   (China)

Author keywords

[No Author keywords available]

Indexed keywords

4-CHLOROPHENOL; 4-CHLOROPHENOL (4-CP); AQUEOUS SOLUTIONS; ATOMIC HYDROGEN; CATALYTIC ACTIVITY; CATALYTIC HYDRODECHLORINATION; CONVERSION RATES; DECHLORINATION PATHWAY; FOAM NICKEL; HYDRODECHLORINATION; LOADING AMOUNT; NI SUBSTRATES; OPERATIONAL CONDITIONS; ORGANOCHLORINES; PD PARTICLE; RADICAL MECHANISM; SOLUTION PH;

CATALYST ACTIVITY; DECHLORINATION; FORMIC ACID; ORGANIC ACIDS; PHENOLS;

PALLADIUM;

EID: 77952417748     PISSN: 08885885     EISSN: 15205045     Source Type: Journal    
DOI: 10.1021/ie9005194     Document Type: Article

References (39)

1. U.S. Environmental Protection Agency. National Pollutant Discharge Elimination System, Code of Federal Regulations, 40, Part 122; U.S. Government Printing Office: Washington, DC, 1988.
2. Briois, C.; Visez, N.; Baillet, C.; Sawerysyn, J. P. Experimental Study on the Thermal Oxidation of 2-Chlorophenol in Air over the Temperature Range 450-900 °C Chemosphere 2006, 62, 1806
3. 2 or CuCl: Formation and Destruction of PCDD/Fs Chemosphere 2007, 67, S144
4. 3+ and UV-Enhanced Ozonation of Chlorophenolic Compounds in Aqueous Medium Chemosphere 1997, 35, 2837
5. 3-. The Case of 2,4,6-Trichlorophenol Environ. Sci. Technol. 2000, 34, 2024
6. Wang, H.; Wang, J. L. Electrochemical Degradation of 4-Chlorophenol Using a Novel Pd/C Gas-Diffusion Electrode Appl. Catal., B 2007, 77, 58
7. Wang, H.; Wang, J. L. Electrochemical Degradation of 2,4-Dichlorophenol on a Palladium Modified Gas-Diffusion Electrode Electrochim. Acta 2008, 53, 6402
8. Lai, T. L.; Lee, C. C.; Huang, G. L.; Shu, Y. Y.; Wang, C. B. Microwave-Enhanced Catalytic Degradation of 4-Chlorophenol over Nickel Oxides Appl. Catal., B 2008, 78, 151
9. Lim, M.; Son, Y.; Yang, J.; Khim, J. Addition of Chlorinated Compounds in the Sonochemical Degradation of 2-Chlorophenol Jpn. J. Appl. Phys. 2008, 47, 4123
10. Nomura, Y.; Nakai, S.; Hosomi, M. Elucidation of Degradation Mechanism of Dioxins during Mechanochemical Treatment Environ. Sci. Technol. 2005, 39, 3799
11. Yan, J. H.; Peng, Z.; Lu, S. Y.; Li, X. D.; Ni, M. J.; Cen, K. F.; Dai., H. F. Degradation of PCDD/Fs by Mechanochemical Treatment of Fly Ash from Medical Waste Incineration J. Hazard. Mater. 2007, 147, 652
12. Aramendia, M. A.; Borau, V.; Garcia, I. M.; Jimenez, C.; Lafont, F.; Marinas, A.; Marinas, J. M.; Urbano, F. J. Influence of the Reaction Conditions and Catalytic Properties on the Liquid-Phase Hydrodechlorination of Chlorobenzene over Palladium-Supported Catalysts: Activity and Deactivation J. Catal. 1999, 187, 392
13. Janiak, T. Kinetics of o -Chlorotoluene Hydrogenolysis in the Presence of 3%, 5% and 10% Pd/C Catalysts Appl. Catal., A 2008, 335, 7
14. 3: A Consideration of HC1/Catalyst Interactions and Solution pH Effects Appl. Catal., B 2004, 52, 301
15. Calvo, L.; Gilarranz, M. A.; Casas, J. A.; Mohedano, A. F.; Rodriguez, J. J. Hydrodechlorination of 4-Chlorophenol in Aqueous Phase Using Pd/AC Catalysts Prepared with Modified Active Carbon Supports Appl. Catal., B 2006, 67, 68
16. 3 J. Catal. 1996, 164, 378
17. 2 (CFC-12) over Gamma-Alumina Supported Palladium Catalysts Appl. Catal., A 1998, 166, 311
18. Grittini, C.; Malcomson, M.; Farnando, Q.; Korte, N. Rapid Dechlorination of Polychlorinated Biphenyls on the Surface of Pd/Fe Bimetallic System Environ. Sci. Technol. 1995, 29, 2898
19. Rodriguez, J. G.; Lafuente, A. Effective Elimination of PCBs Catalyzed by the Palladium/Hydrazine System as an Ecological Sustainable Process Ind. Eng. Chem. Res. 2008, 47, 7993
20. Ukisu, Y.; Miyadera, T. Dechlorination of Dioxins with Supported Palladium Catalysts in 2-Propanol Solution Appl. Catal., A 2004, 271, 165
21. Zhang, F.; Chen, J.; Zhang, H.; Ni, Y.; Zhang, Q.; Liang, X. Dechlorination of Dioxins with Pd/C in Ethanol-Water Solution under Mild Conditions Sep. Purif. Technol. 2008, 59, 164
22. Liu, Y.; Yang, F.; Yue, P.; Chen, G. Catalytic Dechlorination of Chlorophenols in Water by Palladium/Iron Water Res. 2001, 35, 1887
23. Jovanovic, G. N.; Znidarsic-Plazl, P.; Sakrittichai, P.; Al-Khaldi, K. Dechlorination of p -Chlorophenol in a Microreactor with Bimetallic Pd/Fe Catalyst Ind. Eng. Chem. Res. 2005, 44, 5099
24. Zhu, B. W.; Lim, T. T. Catalytic Reduction of Chlorobenzenes with Pd/Fe Nanoparticles: Reactive Sites, Catalyst Stability, Particle Aging, and Regeneration Environ. Sci. Technol. 2007, 41, 7523
25. Ghauch, A.; Tuqan, A. Reductive Destruction and Decontamination of Aqueous Solutions of Chlorinated Antimicrobial Agent Using Bimetallic Systems J. Hazard. Mater. 2009, 164, 665
26. Tee, Y. H.; Bachas, L.; Bhattacharyya, D. Degradation of Trichloroethylene and Dichlorobiphenyls by Iron-Based Bimetallic Nanoparticles J. Phys. Chem. C 2009, 113, 9454
27. Mallouk, T. E.; Schrick, B.; Blough, J. L. Hydrodechlorination of Trichloroethylene to Hydrocarbons Using Bimetallic Nickel-Iron Nanoparticles Chem. Mater. 2002, 14, 5140
28. Zhang, W.; Quan, X.; Wang, J. Rapid and Complete Dechlorination of PCP in Aqueous Solution Using Ni/Fe Nanoparticles under Assistance of Ultrasound Chemosphere 2006, 65, 58
29. Xu, Y.; Zhang, W. Subcolloidal Fe/Ag Particles for Reductive Dehalogenation of Chlorinated Benzenes Ind. Eng. Chem. Res. 2000, 39, 2238
30. Nutt, M. O.; Heck, K. N.; Alvarez, P.; Wong, M. S. Improved Pd-on-Au Bimetallic Nanoparticle Catalysts for Aqueous-Phase Trichloroethene Hydrodechlorination Appl. Catal., B 2006, 69, 115
31. Yang, B.; Yu, G.; Huang, J. Electrocatalytic Hydrodechlorination of 2,4,5-Trichlorobiphenyl on a Palladium-Modified Nickel Foam Cathode Environ. Sci. Technol. 2007, 41, 7503
32. Yang, B.; Yu, G.; Shuai, D. Electrocatalytic Hydrodechlorination of 4-Chlorobiphenyl in Aqueous Solution Using Palladized Nickel Foam Cathode Chemosphere 2007, 67, 1361
33. Yang, B.; Wang, S.; Yu, G.; Zhou, Y. Electrocatalytic Reduction of 2-Chlorobiphenyl in Contaminated Water Using Palladium-Modified Electrode Sep. Purif. Technol. 2008, 63, 353
34. Kopinke, F. D.; Machenzie, K.; Koehler, R.; Georgi, A. Alternative Sources of Hydrogen for Hydrodechlorination of Chlorinated Organic Compounds in Water on Pd Catalysts Appl. Catal., A 2004, 271, 119
35. Calvo, L.; Gilarranz, M. A.; Casas, J. A.; Mohedano, A. F.; Rodriguez, J. J. Hydrodechlorination of 4-Chlorophenol in Water with Formic Acid Using a Pd/Activated Carbon Catalyst J. Hazard. Mater. 2008, 161, 842
36. Roy, H. M.; Wai, C. M.; Yuan, T.; Kim, J. K.; Marshall, W. D. Catalytic Hydrodechlorination of Chlorophenols in Aqueous Solution under Mild Conditions Appl. Catal., A 2004, 271, 137
37. Vincent, T.; Spinelli, S.; Guibal, E. Chitosan-Supported Palladium Catalyst. II. Chlorophenol Dehalogenation Ind. Eng. Chem. Res. 2003, 42, 5968
38. Li, Q.; Mahendra, S.; Lyon, D. Y.; Brunet, L.; Liga, M. V.; Li, D.; Alvarez, P. J. J. Review: Antimicrobial Nanomaterials for Water Disinfection and Microbial Control: Potential Applications and Implications Water Res. 2008, 42, 4591
39. Prusse, U.; Vorlop, K. D. Supported Bimetallic Palladium Catalysts for Water-Phase Nitrate Reduction J. Mol. Catal. A: Chem. 2001, 173, 313