A new analysis of internal cation mobilities in the molten binary system (Li, K)Cl

Journal of Chemical and Engineering Data

Volumn 55, Issue 5, 2010, Pages 1847-1854

  Okada, Isao ^a   Horinouchi, Hiroshi ^b   Lantelme, Frédéric ^c  

^a SOPHIA UNIVERSITY   (Japan)

^b TOKYO INSTITUTE OF TECHNOLOGY   (Japan)

^c SORBONNE UNIVERSITÉ   (France)

Author keywords

[No Author keywords available]

Indexed keywords

BINARY SYSTEMS; CATION MOBILITY; DISSOCIATION MODELS; EMPIRICAL EQUATIONS; INTERNAL MOBILITY; MOLAR VOLUMES;

SYSTEMS (METALLURGICAL);

VOLUME MEASUREMENT;

EID: 77952405713     PISSN: 00219568     EISSN: 15205134     Source Type: Journal    
DOI: 10.1021/je900866q     Document Type: Article

References (32)

1. Chemla, M. Improvement of the Isotope Separation Processes by Countercurrent Electromigration in the Molten Salts. (Perfectionnement aux procédés de séparation isotopique par é lectromigration en contre-courant dans les sels fondus). French Patent No. 1,216,418, Demanded on Nov 24, 1958, 1-2.
2. Klemm, A.; Hintenberger, H.; Hoernes, P. Enrichment of Heavier Isotopes of Li and K by Electromigration in Molten Chlorides. (Anreicherung der Schweren Isotope von Li und K durch Electrolytische Ionenwanderung in Geschmolzenen Chloriden) Z. Naturforsch. 1947, 2a, 245-249
3. Périé, J.; Chemla, M. Countercurrent Electromigration in Molten Halide Mixtures. (Èlectromigration en Contre-courant dans des Mélanges dHalogénures Fondus C. R. Acad. Sci. 1960, 250, 3986-3988
4. Périé, J.; Chemla, M.; Gignoux, M. Separation of Isotopes by Countercurrent Electromigration in Molten Alkali Bromides. (Séparation dIsotopes par Èlectromigration en Contre-courant dans des Systèmes dHalogénures Fondus) Bull. Soc. Chim. Fr. 1961, 1249-1256
5. Mehta, O. P. Study on Ion Transport in Molten Alkali Bromides. (Ètude du Transport Ionique dans des Bromures Alcalins Fondus). Thesis, Faculté des Science, Université dOrsay, France, 1967.
6. Mehta, O. P.; Lantelme, F.; Chemla, M. Electric Conductivity of the Molten Systems LiBr-KBr. (Conductibilité Èlectrique des Systèmes LiBr-KBr Fondus) Electrochim. Acta 1969, 14, 505-513
7. Chemla, M.; Lantelme, F.; Mehta, O. P. Diffusion and Transport in Molten Alkali Halides. (Diffusion et Transport Ionique dans les Halogénures Alcalins Fondus) J. Chim. Phys. (Num. Spec.) 1969, 136-144
8. 3 Z. Naturforsch. 1979, 34a, 498-503
9. Okada, I.; Lantelme, F. A New Interpretation of the Original Data of Chemlas Group on the Mobilities of Binary Molten System (Li, K)Br J. New Mater. Electrochem. Syst. 2006, 9, 165-174
10. Okada, I.; Lantelme, F. Application of an Empirical Internal Mobility Equation to the Molten Binary Bromide System (Li, K)Br Studied by Chemlas Group Z. Naturforsch. 2008, 63a, 318-320
11. Chemla, M.; Okada, I. Ionic Mobilities of Monovalent Cations in Molten Salt Mixtures Electrochim. Acta 1990, 35, 1761-1776
12. Okada, I. Transport Properties of Molten Salts. In Modern Aspects of Electrochemistry, Number 34; Bockris, J. OM., Ed.; Kluwer Academic/Plenum Publishers: New York, 2001; pp 119-203.
13. Okada, I. The Chemla Effect-from the Separation of Isotopes to the Modeling of Binary Ionic Liquids J. Mol. Liq. 1999, 83, 5-22
14. Okada, I. Electric Conduction in Molten Salts Electrochemistry (Tokyo, Jpn.) 1999, 67, 529-540
15. Janz, G. J.; Tomkins, R. P. T.; Allen, C. B.; Downey, J. R., Jr.; Gardner, G. L.; Krebs, U.; Singer, S. K. Chlorides and Mixtures Electrical Conductance, Density, Viscosity, and Surface Tension Data J. Phys. Chem. Ref. Data 1975, 4, 871-1178
16. Moynihan, C. T.; Laity, R. W. Relative Cation Mobilities in Potassium Chloride-Lithium Chloride Melts J. Phys. Chem. 1964, 68, 3312-3317
17. Smirnov, M. V.; Alexandrov, K. A.; Khokhlov, V. A. Diffusion Potentials and Transport Numbers in Molten Alkali Chlorides and Their Binary Mixtures Electrochim. Acta 1977, 22, 543-550
18. Takagi, R.; Shimotake, H.; Jensen, K. J. Determination of Internal Cation Mobilities in the Molten System (Li-K)Cl at 273 K J. Electrochem. Soc. 1984, 131, 1280-1283
19. Lundén, A.; Okada, I. Internal Cation Mobilities and their Isotope Effects in the Molten System (Li, K)Cl Z. Naturforsch. 1986, 41a, 1034-1040
20. 3 Remeasured by the Column Method Z. Naturforsch. 1989, 44a, 747-750
21. Ljubimov, V.; Lundén, A. Electromigration in Molten and Solid Binary Sulfate Mixtures: Relative Cation Mobilities and Transport Numbers Z. Naturforsch. 1966, 21a, 1592-1600
22. Okada, I.; Horinouchi, H. The Chemla Effect in the Mobilities in the Molten Binary System of Lithium Chloride and Caesium Chloride J. Electroanal. Chem. 1995, 396, 547-552
23. Van Artsdalen, E. R.; Yaffe, I. S. Electrical Conductance and Density of Molten Salt Systems: KCl-LiCl, KCl-NaCl and KCl-KI J. Phys. Chem. 1955, 59, 118-128
24. Janz, G. J. Thermodynamic and Transport Properties for Molten Salts: Correlation Equations for Critically Evaluated Density, Surface Tension, Electrical Conductance, and Viscosity Data J. Phys. Chem. Ref. Data, Suppl. 1988, 17, 1-309
25. Fellner, P.; Votava, I.; Chrenková-Paučírová, M. Density of the Molten System LiCl-NaCl-KCl Chem. Zvesti 1980, 34, 330-334
26. Fellner, P. The Series and Parallel Models of Electrical Conductivity of Molten Salt Mixtures. I. Binary Mixtures with Simple Halide Anions Chem. Zvesti 1984, 38, 159-163
27. Daněk, V. Dissociation Model of the Electrical Conductivity of Molten Salt Mixtures I. Theory of Univalent Electrolytes Chem. Pap. 1989, 43, 25-34
28. 3 Z. Naturforsch. 1980, 35a, 1186-1191
29. Morgan, B.; Madden, P. A. Ionic Mobilities and Microscopic Dynamics in Liquid (Li, K)Cl J. Chem. Phys. 2004, 120, 1402-1413
30. Koura, T.; Matsuura, H.; Okada, I. A Dynamic Dissociation Model for Internal Mobilities in Molten Alkali and Alkaline Earth Nitrate Mixtures J. Mol. Liq. 1997, 73-74, 195-208
31. - Ions Z. Naturforsch. 1987, 42a, 21-28
32. Okada, I.; Takagi, R.; Kawamura, K. A Molecular Dynamics Simulation of Molten (Li-Rb)Cl Implying the Chemla Effect of Mobilities Z. Naturforsch. 1980, 35a, 493-499