Solubilities of NaCl, KCl, LiCl, and LiBr in methanol, ethanol, acetone, and mixed solvents and correlation using the liquac model

Industrial and Engineering Chemistry Research

Volumn 49, Issue 10, 2010, Pages 4981-4988

  Li, Miyi ^a,b   Constantinescu, Dana ^a,b   Wang, Lisheng ^a,b   Mohs, André ^a,b   Gmehling, Juürgen ^a,b  

^a BEIJING INSTITUTE OF TECHNOLOGY   (China)

^b Institut Fuür Reine und Angewandte Chemie   (Germany)

Author keywords

[No Author keywords available]

Indexed keywords

DATA BANK; DORTMUND; EXPERIMENTAL DATA; LIQUAC MODEL; MIXED SOLVENT; SALT SOLUBILITY; SOLUBILITY DATA; TEMPERATURE RANGE;

ACETONE; ETHANOL; METHANOL; SODIUM CHLORIDE; SOLUBILITY;

ORGANIC SOLVENTS;

EID: 77952357813     PISSN: 08885885     EISSN: 15205045     Source Type: Journal    
DOI: 10.1021/ie100027c     Document Type: Article

References (16)

1. Dortmund Data Bank, version 2008; DDBST Software and Separation Technology GmbH: Oldenburg, Germany, 2008; www.ddbst.de.
2. Pinho, S. P.; Macedo, E. A. Solubility of NaCl, NaBr, and KCl in Water, Methanol, Ethanol, and Their Mixed Solvents J. Chem. Eng. Data 2005, 50, 29
3. E Model for Single and Mixed Solvent Electrolyte Systems. 1. Model and Results for Strong Electrolytes Fluid Phase Equilib. 1994, 94, 89
4. E Model for Single and Mixed Solvent Electrolyte Systems. 2. Results and Comparison with Other Models Fluid Phase Equilib. 1994, 94, 115
5. Pinho, S. P.; Macedo, E. A. Experimental Measurement and Modeling of KBr Solubility in Water, Methanol, Ethanol and its Binary Mixed Solvents at Different Temperatures J. Chem. Thermodyn. 2002, 34, 337
6. E Model for Single- and Mixed-Solvent Electrolyte Systems. 3. Prediction of Salt Solubilities in Aqueous Electrolyte Systems Ind. Eng. Chem. Res. 2005, 44, 1602
7. Huang, J.; Li, J.; Gmehling, J. Prediction of Solubilities of Salts, Osmotic Coefficients, and Vapor-Liquid Equilibria for Single and Mixed Solvent Electrolyte Systems using the LIQUAC Model Fluid Phase Equilib. 2009, 275, 8
8. Pinho, S. P.; Macedo, E. A. Representation of Salt Solubility in Mixed Solvents: A Comparison of Thermodynamic Models Fluid Phase Equilib. 1996, 116, 209
9. Kiepe, J.; Noll, O.; Gmehling, J. Modified LIQUAC and Modified LIFAC-A Further Development of Electrolyte Models for the Reliable Prediction of Phase Equilibria with Strong Electrolytes Ind. Eng. Chem. Res. 2006, 45, 2361
10. Harner, R. E.; Sydnor, J. B.; Gilreath, E. S. Solubilities of Anhydrous Ionic Substances in Absolute Methanol J. Chem. Eng. Data 1963, 8, 411
11. Pavlopoulos, T.; Strehlow, H. The Solubilities of Alkali Halogenides in Methanol, Acetonitrile and Formic Acid. Z. Phys. Chem. 1954, 202, 474
12. Emons, H.-H.; Duümke, D.; Foürtsch, M. Investigation of Systems Consisting of Salts and Mixed Solvents. II The Systems Sodium Chloride Resp. Potassium Chloride, Methanol-Water and Sodium Chloride-Potassium Chloride-Methanol-Water. Wiss. Z. TH Leuna-Merseburg 1966, 8, 195
13. Turner, W. E. S.; Bissett, C. C. The Solubilities of Alkali Haloids in Methyl, Ethyl, Propyl, and iso-Amyl Alcohols J. Chem. Soc. London 1913, 103, 1904
14. Simmons, J. P.; Freimuth, H.; Russel, H. The Systems Lithium Chloride-Ethyl Alcohol and Lithium Bromide-Water-Ethyl Alcohol J. Am. Chem. Soc. 1936, 58, 1692
15. Vlasov, Yu. G.; Antonov, P. P.; Anokhin, V. N. The System LiCl-LiBr-Ethanol at 25 °C Zh. Prikl. Khim. 1975, 48, 1155
16. Plyushchev, V. E.; Shakhno, I. V.; Komissarova, L. N.; Nadezhdina, G. V. Study of Solubility of Alkali Metal Chlorides in Some Aliphatic Alcohols Tr. Mosk. Inst. Tonkoj Khim. Tekhnol. 1958, 7, 45