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For hard-core particles in higher dimensions the quasistatic approximation is expected to break down, at least for low particle densities since a tracer particle diffuses normally invalidating the above argument.
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The compressibility of the particle system does not necessarily involve the compressibility of the medium between the particles. For instance, if the particles are embedded in water that can flow past the particles, then the statistical mechanical calculation of the compressibility of the particle system should involve water kept at a uniform chemical potential.
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The compressibility of the particle system does not necessarily involve the compressibility of the medium between the particles. For instance, if the particles are embedded in water that can flow past the particles, then the statistical mechanical calculation of the compressibility of the particle system should involve water kept at a uniform chemical potential.
-
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