메뉴 건너뛰기




Volumn 16, Issue 20, 2010, Pages 5961-5968

Direct electrochemistry of cytochrome c at modified Si(100) electrodes

Author keywords

Bioelectrochemistry; Cytochromes; Hydrosilylation; Monolayers; Silicon

Indexed keywords

ALKYL MONOLAYERS; BIOELECTROCHEMISTRY; CYTOCHROME C; CYTOCHROMES; DIRECT ELECTROCHEMISTRY; DIRECT ELECTRON TRANSFER; HEME MOIETY; ISONICOTINAMIDE; ISONICOTINIC ACID; MODULAR APPROACH; RECEPTOR LIGANDS; REDOX CENTERS; REDOX PROTEINS; SAMS; SELF-ASSEMBLED; SI(1 0 0); SILICON SURFACES;

EID: 77952330844     PISSN: 09476539     EISSN: 15213765     Source Type: Journal    
DOI: 10.1002/chem.200903316     Document Type: Article
Times cited : (31)

References (84)
  • 2
    • 0034599876 scopus 로고    scopus 로고
    • Angew. Chem. Int. Ed. 2000, 39, 1180-1218;
    • (2000) Angew. Chem. Int. Ed. , vol.39 , pp. 1180-1218
  • 5
    • 10044258525 scopus 로고    scopus 로고
    • Angew. Chem. Int. Ed. 2004, 43, 6042-6108.
    • (2004) Angew. Chem. Int. Ed. , vol.43 , pp. 6042-6108
  • 11
  • 20
    • 57049104569 scopus 로고    scopus 로고
    • Angew. Chem. Int. Ed. 2008, 47, 9618-9647;
    • (2008) Angew. Chem. Int. Ed. , vol.47 , pp. 9618-9647
  • 23
    • 0037099395 scopus 로고    scopus 로고
    • Angew. Chem. Int. Ed. 2002, 41, 2596-2599;
    • (2002) Angew. Chem. Int. Ed. , vol.41 , pp. 2596-2599
  • 26
    • 0037099395 scopus 로고    scopus 로고
    • Angew. Chem. Int. Ed. 2002, 41, 2596-2599;
    • (2002) Angew. Chem. Int. Ed. , vol.41 , pp. 2596-2599
  • 36
    • 0037122125 scopus 로고    scopus 로고
    • Angew. Chem. Int. Ed. 2002, 41, 4700-4703;
    • (2002) Angew. Chem. Int. Ed. , vol.41 , pp. 4700-4703
  • 46
    • 77952344562 scopus 로고    scopus 로고
    • The oxygen Is emission at about 532 eV is ascribed to adventitiously adsorbed oxygen
    • The oxygen Is emission at about 532 eV is ascribed to adventitiously adsorbed oxygen.
  • 47
    • 77952416520 scopus 로고    scopus 로고
    • 3-hybridized. Given the chemical composition of the monolayer assembled from the diyne 1, a contribution ascribed to carbon atoms in a carbide carbon-silicon configuration was expected around about 284.1 eV, but could not be assigned unambiguously
    • 3-hybridized. Given the chemical composition of the monolayer assembled from the diyne 1, a contribution ascribed to carbon atoms in a carbide carbon-silicon configuration was expected around about 284.1 eV, but could not be assigned unambiguously.
  • 49
    • 77952400434 scopus 로고    scopus 로고
    • Under our XPS experimental conditions the SiO, sublayer detection limit was approximated to 0.06 monolayers
    • Under our XPS experimental conditions the SiO, sublayer detection limit was approximated to 0.06 monolayers.
  • 66
    • 77952391231 scopus 로고    scopus 로고
    • Sum of nitrogen-, oxygen- and carbonyl-bound carbon photoemissions
    • Sum of nitrogen-, oxygen- and carbonyl-bound carbon photoemissions.
  • 75
    • 77952336903 scopus 로고    scopus 로고
    • 0) were found for the cathodic wave when compared to the same value for the oxidation curve. A faster kinetic for the oxidation reaction is also supporting the stabilization of the heme by the pyridine moiety
    • 0) were found for the cathodic wave when compared to the same value for the oxidation curve. A faster kinetic for the oxidation reaction is also supporting the stabilization of the heme by the pyridine moiety.
  • 80
    • 77952325870 scopus 로고    scopus 로고
    • More conventional carbodiimide-based coupling procedures were found to be hampered by a rearrangement of the putative O-acylurea intermediate to the N-acylurea product. For instance the coupling reaction of isonicotinic acid with 3-azidopropylamine, with N, N'-dicyclohexylcarbodiimide (DCC) as the coupling agent, did not afford the intended amide product. The primary product of the DCC coupling reaction was the N-acyl-N, N'-dicyclohexylurea product.
    • More conventional carbodiimide-based coupling procedures were found to be hampered by a rearrangement of the putative O-acylurea intermediate to the N-acylurea product. For instance the coupling reaction of isonicotinic acid with 3-azidopropylamine, with N, N'-dicyclohexylcarbodiimide (DCC) as the coupling agent, did not afford the intended amide product. The primary product of the DCC coupling reaction was the N-acyl-N, N'-dicyclohexylurea product.
  • 81
    • 77952372780 scopus 로고    scopus 로고
    • The unreacted azide molecules 2 and 3 used in surface modification procedures was routinely recovered and purified through column chromatography (ethyl acetate/light petroleum, 3:5)
    • The unreacted azide molecules 2 and 3 used in surface modification procedures was routinely recovered and purified through column chromatography (ethyl acetate/light petroleum, 3:5).


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.