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H. Liu, H. Yamamoto, J. Wei, D. H. Waldeck, Langmuir 2003, 19, 2378-2387.
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Langmuir
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Liu, H.1
Yamamoto, H.2
Wei, J.3
Waldeck, D.H.4
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80
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77952325870
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More conventional carbodiimide-based coupling procedures were found to be hampered by a rearrangement of the putative O-acylurea intermediate to the N-acylurea product. For instance the coupling reaction of isonicotinic acid with 3-azidopropylamine, with N, N'-dicyclohexylcarbodiimide (DCC) as the coupling agent, did not afford the intended amide product. The primary product of the DCC coupling reaction was the N-acyl-N, N'-dicyclohexylurea product.
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More conventional carbodiimide-based coupling procedures were found to be hampered by a rearrangement of the putative O-acylurea intermediate to the N-acylurea product. For instance the coupling reaction of isonicotinic acid with 3-azidopropylamine, with N, N'-dicyclohexylcarbodiimide (DCC) as the coupling agent, did not afford the intended amide product. The primary product of the DCC coupling reaction was the N-acyl-N, N'-dicyclohexylurea product.
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81
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77952372780
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The unreacted azide molecules 2 and 3 used in surface modification procedures was routinely recovered and purified through column chromatography (ethyl acetate/light petroleum, 3:5)
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The unreacted azide molecules 2 and 3 used in surface modification procedures was routinely recovered and purified through column chromatography (ethyl acetate/light petroleum, 3:5).
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82
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33745853185
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A. F. Stalder, G. Kulik, D. Sage, L. Barbieri, P. Hoffmann, Colloids Surf. 2006, 256, 92-103.
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(2006)
Colloids Surf.
, vol.256
, pp. 92-103
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Stalder, A.F.1
Kulik, G.2
Sage, D.3
Barbieri, L.4
Hoffmann, P.5
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