Thermodynamics of cesium complexes formation with 18-crown-6 in ionic liquids

Journal of Inclusion Phenomena and Macrocyclic Chemistry

Volumn 66, Issue 3, 2010, Pages 223-230

  Vendilo, A G ^a   Ronkkomaki H ^b   Hannu Kuure, M ^c   Lajunen, M ^c   Asikkala, J ^c   Krasovsky, V G ^d   Chernikova, E A ^d   Oksman, P ^c   Lajunen, L H J ^c   Tuomi, T ^b   Popov, K I ^e  

^a Institute of Chemical Reagents and Special Purity Substances   (Russian Federation)

^b FINNISH INSTITUTE OF OCCUPATIONAL HEALTH   (Finland)

^c UNIVERSITY OF OULU   (Finland)

^d N D ZELINSKY INSTITUTE OF ORGANIC CHEMISTRY   (Russian Federation)

^e MOSCOW STATE UNIVERSITY OF FOOD PRODUCTION   (Russian Federation)

Author keywords

18 crown 6; 133Cs NMR; Cesium; Complexes; RTIL; Stability constants

Indexed keywords

EID: 77952292813     PISSN: 09230750     EISSN: None     Source Type: Journal    
DOI: 10.1007/s10847-009-9600-3     Document Type: Article

References (39)

1. Earle, M. J., Seddon, K. R.: Ionic liquids. Green solvents for future. Pure Appl. Chem. 72, 1391-1398 (2000).
2. Cocalia, V. A., Holbray, J. D., Gutowski, K. E., Bridges, N. J., Rogers, R. D.: Separations of metal ions using ionic liquids: the challenges of multiple mechanisms. Tsinghua Sci. Technol. 11, 188-193 (2006).
3. Visser, A. E., Swatloski, R. P., Reichert, W. M., Griffin, S. T., Rogers, R. D.: Traditional extractants in nontraditional solvents: Groups 1 and 2 extraction by crown ethers in room temperature ionic liquids. Ind. Eng. Chem. Res. 39, 304-3596 (2000).
4. Dai, S., Ju, Y. H., Barnes, C. E.: Solvent extraction of strontium nitrate by crown ether using room-temperature ionic liquids. J. Chem. Soc., Dalton Trans. 120, 1-1202 (1999).
5. Luo, H., Dai, S., Bonnesen, P. V., Buchana, A. C.: Separation of fission products based on ionic liquids containing aza-crown ether fragment. J. Alloy Compd. 418, 195-199 (2006).
6. Chen, P.-Y.: The assessment of removing strontium and cesium cations from aqueous solutions based on the combined methods of ionic liquid extraction and electrodeposition. Electrochim. Acta 52, 5484-5492 (2007).
7. Chun, S., Dzyuba, S. V., Bartsch, R. A.: Influence of structural variation in room-temperature ionic liquids on the selectivity and efficiency of competitive alkali metal salt extraction. Anal. Chem. 73, 3737-3741 (2001).
8. Visser, A. E., Roberts, R. D.: Room-temperature ionic liquids: new solvents for f-element separations and associated solution chemistry. J. Solid State Chem. 171, 109-113 (2003).
9. Shimojo, K., Goto, M.: Solvent extraction and stripping of silver ions in room-temperature ionic liquids containing calixarenes. Anal. Chem. 76, 5039-5044 (2004).
10. 2+: synthesis, characterization and extraction studies. Environ. Sci. Technol. 36, 2523-2529 (2002).
11. Visser, A. E., Swatloski, R. P., Reichert, W. M., Mayton, R., Sheff, S., Wierzbicki, A., Davis Jr, J. H., Rogers, R. D.: Task-specific ionic liquids for extraction of metal ions from aqueous solution. Chem. Commun. 13, 5-136 (2001).
12. Ajioka, T., Oshima, S., Hirayama, N.: Use of 8-sulfonamidoquinoline derivatives as chelate extraction reagents in ionic liquid extraction system. Talanta 74, 903-908 (2008).
13. Lohithakshan, K. V., Aggarwal, S. K.: Solvent extraction studies of Pu(IV) with CMPO in 1-octyl-3-methyl imidazolium hexafluorophosphate (C8mimPF6) room temperature ionic liquid (RTIL). Radiochim. Acta 96, 93-97 (2008).
14. Dietz, M. L., Stepinski, D. C.: Anion concentration-dependent partitioning mechanism in the extraction of uranium into room-temperature ionic liquids. Talanta 75, 598-603 (2008).
15. Nishi, N., Murakami, H., Imakura, H., Kakiuchi, T.: Facilitated transfer of alkali-metal cations by dibenzo-18-crown-6 across the electrochemically polarized interface between an aqueous solution and a hydrophobic room-temperature ionic liquid. Anal. Chem. 78, 5805-5812 (2006).
16. + complexes with cryptand 222 in ionic liqiuds. J. Inclusion Phenom. Macrocycl. Chem. 52, 237-240 (2005).
17. Popov, K., Rönkkömäki, H., Hannu-Kuure, M., Kuokkanen, T., Lajunen, M., Vendilo, V., Oksman, P., Lajunen, L. H. J.: Stability of crown-ether complexes with alkali-metal ions in ionic liquid-water mixed solvents. J. Inclusion Phenom. Macrocycl. Chem. 59, 377-381 (2007).
18. Popov, K. I., Rönkkömäki, H., Hannu-Kuure, M., Kuokkanen, T., Lajunen, M., Vendilo, A., Glazkova, I. V., Lajunen, L. H. J.: Stability constant of the sodium complex with dibenzo-18-crown-6 in mixed water-ionic liquid solvent. Russ. J. Coord. Chem. 33, 393-395 (2007).
19. Djigailo, D. I., Smirnova, S. V., Torocheshnikova, I. I., Vendilo, A. G., Popov, K. I., Pletnev, I. V.: Extraction of nitrates of alkali and alkaline earth metals with crown ether into hydrophilic ionic liquid in presence of salting-out agent. Vestn. Mosk. Univ. (Moscow University Bull.) Ser. 2 50, 164-168 (2009).
20. Farmer, V., Welton, T.: The oxidation of alcohols in substituted imidazolium ionic liquids using ruthenium catalysts. Green Chem. 4, 97-102 (2002).
21. Asikkala, J. Application of ionic liquids and microwave activation in selected organic reactions. PhD Theses. Acta Universitatis Oulunesis, A 502, Oulu University Press, Oulu (2008).
22. Sigmaplot for Windows, Version 4. 0, 1986-1997 SPSS Inc.
23. 13C NMR data processed by the new computer program HypNMR2000. Protonation sequence in polyamines. Anal. Biochem. 376, 1041-1052 (2003).
24. Arnaud-Neu, F., Delgado, R., Chaves, S.: Critical evaluation of stability constants and thermodynamic functions of metal complexes of crown ethers. Pure Appl. Chem. 75, 71-102 (2003).
25. Mei, E., Popov, A. I., Dye, J. L.: Complexation of the cesium cation by macrocyclic polyethers in various solvents. A cesium-133 Nuclear Magnetic Resonance study of the thermodynamics and kinetics of exchange. J. Phys. Chem. 81, 1677-1681 (1977).
26. Vendilo, A. G., Rönkkömäki, H., Hannu-Kuure, M., Lajunen, M., Asikkala, J., Petrov, A. A., Krasovsky, V. G., Chernikova, E. A., Oksman, P., Lajunen, L. H. J., Popov, K. I.: Stability constants of cesium complexes with 18-crown-6 in ionic liquids. Koord. Khim. 34, 645-650 (2008); [Russ. J. Coord. Chem. 34, 635-640].
27. Smetana, A. J., Popov, A. I.: Lithium-7 Nuclear Magnetic Resonance and calorimetric study of lithium crown complexes in various solvents. J. Solut. Chem. 9, 183-196 (1980).
28. Gutmann, V., Vichera, E.: Coordination reactions in non aqueous solutions-the role of the donor strength. Inorg. Nucl. Chem. Lett. 2, 257-260 (1966).
29. Kikuchi, Y., Sakamoto, Y.: Complex formation of alkali metal ions with 18-crown-6 and its derivatives in 1, 2-dichloroethane. Anal. Chim. Acta 403, 325-332 (2000).
30. Ohtsu, K., Ozutsumi, K.: Thermodynamics of solvation of 18-crown-6 and its alkali-metal complexes in various solvents. J. Inclusion Phenom. Macrocycl. Chem. 45, 217-224 (2003).
31. Ozutsumi, K., Ohtsu, K., Kawashima, T.: Thermodynamics of complexation of 18-crown-6 with sodium, potassium, rubidium caesium and ammonium ions in N, N-dimethylformamide. J. Chem. Soc. Faraday Trans. 90, 127-131 (1994).
32. 3]. Z. Anorg. Allg. Chem. 632, 2475-2480 (2006).
33. Ellerman, J., Bauer, W., Schuetz, M., Heinemann, F. W., Moll, M.: Chemie Polyfunctioneller Molecueler 130 Mitt.[1]: Spaltproduhte, Kristallstrukturen und Festkoerper-NMR-Spektern. Monatshefte fur Chemie 129, 547-566 (1998).
34. Ozutsumi, K., Natsuhara, M., Ohtaki, H.: An X-ray diffraction study on the structure of 18-crown-6 ether complexes with alkali metal ions in aqueous solutions. Bull. Chem. Soc. Jpn. 62, 2807-2818 (1989).
35. Dang, L. X.: Mechanism and thermodynamics of ion selectivity in aqueous solutions of 18-crown-6 ether: a molecular dynamic study. J. Am. Chem. Soc. 117, 6954-6969 (1995).
36. 2. J. Am. Chem. Soc. 104, 4073-4076 (1982).
37. 3CN). J. Inclusion Phenom. 6, 65-71 (1988).
38. Garrell, R. L., Smyth, J. C., Fronczek, F. R., Gandour, R. D.: Crystal structure of the 2: 1 acetonitrile complex of 18-crown-6. J. Inclusion Phenom. 6, 73-78 (1988).
39. 2]. Z. Naturforsch. 49b, 852-854 (1994).