메뉴 건너뛰기




Volumn 13, Issue 5, 2010, Pages 577-579

Novel mixed valence U(VI)/U(IV) dipicolinate

Author keywords

[No Author keywords available]

Indexed keywords


EID: 77952109837     PISSN: 13877003     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.inoche.2010.02.007     Document Type: Article
Times cited : (12)

References (45)
  • 14
    • 77952103007 scopus 로고    scopus 로고
    • Apex 2, Bruker AXS Inc., Madison, Wisconsin, USA
    • Apex 2, Bruker AXS Inc., Madison, Wisconsin, USA
  • 15
    • 77952111114 scopus 로고    scopus 로고
    • Crystal data for (HMeIm)K[(UO2)(H2O)U(DPA)4].2H2O: M, 1344.74, triclinic, P-1, a, 9.6163(6) Å, b, 14.5969(12) Å, c, 15.0797(13) Å, α, 64.826(2)°, β, 78.327(2)°, γ, 85.208(4)°, V, 1876.04 Å3, Z, 2, 2θmax, 80°, R, 0.055, and wR2, 0.110
    • max = 80°, R = 0.055, and wR2 = 0.110
  • 25
    • 77952101284 scopus 로고    scopus 로고
    • Most of the observed IR absorption bands are multiplex and characterized by main component peaking and shoulders at the high or low energy sides. For reliable peak resolution of highly overlapped and hidden peaks in the spectrum the curve fitting procedure have been applied. The IR spectrum was smoothed over 10 data points. Second derivative of spectrum was used as starting parameters for the curve fitting. Both Lorentzian and Gaussian functions were used as possible models for the band shape, but Lorentzian function was found to be more appropriate in the case when absorption bands are significantly broadened. As an example, in Fig. S3 are the results shown of analysis of the spectrum in the 1800-1500 cm- 1 region, where vibrations of carboxylate ion νas(COO, and aromatic ring ν(NC)ring, ν(CC)ring as well as deformation vibrations of coordinated water molecule δ(H2O) are manifested
    • 2O) are manifested.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.