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Volumn 13, Issue 5, 2010, Pages 630-632

Structure and luminescent property of a novel one-dimensional organomercury complex

Author keywords

Bipyridine ligand; Luminescent property; Organomercury complex; X ray structure

Indexed keywords


EID: 77952108997     PISSN: 13877003     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.inoche.2010.03.005     Document Type: Article
Times cited : (15)

References (28)
  • 20
    • 77952108211 scopus 로고    scopus 로고
    • Synthesis of the ligand (L, A mixture of 1,3-dihydroxybenzene (resorcinol, 1.1 g, 10 mmol, 2-chloromethylpyridine hydrochloride (3.28 g, 20 mmol) and NaOH (1.6 g, 40 mmol) in acetonitrile (50 mL) was stirred at reflux under nitrogen for 24 h. After cooling to room temperature, the reactant was filtered, and the residue was washed with acetonitrile for several times. The mixed filtrate was evaporated under reduced pressure and the red residue was dissolved in dichloromethane and then washed twice with water, once with brine. The organic layer was dried over anhydrous Na2SO4 and filtered. After the removal of the solvent under reduced pressure, the residue was purified by chromatography on silica gel to give colorless solid substance. Yield: 2.57 g (88% based on resorcinol, Element Analysis: Calc. for C18H16O2N2: C, 73.95; H, 5.52; N, 9.58, Found: C, 73.78; H, 5.50; N, 9.53, IR (KBr, cm- 1, 3062 w, 3015
    • 3): 5.21 (4H, s, CH2), 6.62 (1H, t), 6.69 (2H, d), 7.24 (2H, q), 7.28 (1H, s), 7.53 (2H, d), 7.72 (2H, q), 8.62 (2H, t).
  • 21
    • 77952102460 scopus 로고    scopus 로고
    • - 1): 3379 (s), 3117 (w), 2922 (w), 1641 (s), 1599 (s), 1435 (s), 1354 (s), 1311 (s), 1294 (s), 1193 (s), 1052 (s), 756 (s), 683 (s).
    • - 1): 3379 (s), 3117 (w), 2922 (w), 1641 (s), 1599 (s), 1435 (s), 1354 (s), 1311 (s), 1294 (s), 1193 (s), 1052 (s), 756 (s), 683 (s).
  • 22
    • 77952103582 scopus 로고    scopus 로고
    • The X-ray diffraction measurements for the title complex was carried out on a Rigaku R-AXIS RAPID imaging plate diffractometer with graphite-monochromated Mo Kα (λ, 0.71073 Å) at 293 K. Empirical absorption corrections based on equivalent reflections were applied. The structure of complex was solved by direct methods using SHELXS 97. All nonhydrogen atoms were refined anisotropically by the full-matrix least-squares method on F2. H atoms bound to C atoms were placed in calculated positions and treated as riding on their parent with C-H, 0.93 Å (aromatic) or 0.97 Å (methylene, and with Uiso (H, 1.2 Ueq (C, Complex 1: triclinic, space group P21/c, a, 14.326(3) Å, b, 15.456(4) Å, c, 10.161(5) Å, α, 90°, β, 101.309(15)°, γ, 90°, V, 2206.1(12) Å3, Z, 4, R, 0.0624, Rw, 0.0764. The final cycle of full-matrix least-squares refinement was based on 5027
    • 3, Z = 4, R = 0.0624, Rw = 0.0764. The final cycle of full-matrix least-squares refinement was based on 5027 observed reflections and 291 variable parameters.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.