The hydrolysis of Al(III) in NaCl solutions: A model for M(II), M(III), and M(IV) Ions

Aquatic Geochemistry

Volumn 16, Issue 3, 2010, Pages 317-324

  Woosley, Ryan J ^a   Millero, Frank J ^a  

^a UNIVERSITY OF MIAMI   (United States)

Author keywords

Divalent, trivalent, and quadrivalent metals; Hydrolysis constants

Indexed keywords

ALUMINUM; AQUEOUS SOLUTION; COMPLEXATION; CORRELATION; ENTHALPY; HYDROLYSIS; IONIC COMPOSITION; LINEARITY; NUMERICAL MODEL; PH; SODIUM CHLORIDE; SPECIATION (CHEMISTRY); WATER TEMPERATURE;

EID: 77951977473     PISSN: 13806165     EISSN: 15731421     Source Type: Journal    
DOI: 10.1007/s10498-009-9075-2     Document Type: Article

References (25)

1. Baes CF Jr, Mesmer RE (1976) The hydrolysis of cations. Wiley, New York.
2. Benézéth P, Palmer DA, Wesolowski DJ (2001) Aqueous high-temperature solubility studies. II. The solubility of Boehmite at 0. 03 m ionic strength as a function of temperature and pH as determined by in situ measurements. Geochim Cosmochim Acta 65: 2097-2111.
3. Bourcier WL, Knauss KG, Jackson KJ (1993) Aluminum hydrolysis constants to 250°C from boehmite solubility measurements. Geochim Cosmochim Acta 57: 747-762.
4. Castet S, Dandurand JL, Schott J, Gout R (1993) Boehmite solubility and aqueous aluminum speciation in hydrothermal solutions (90-350°). Experimental study and modelling. Geochim Cosmochim Acta 57: 4869-4884.
5. Choppin GR, Bond AH, Hromadka PM (1997) Redox speciation of plutonium. J Radioanal Nuclear Chem 219: 203-210.
6. Couturier Y, Michard G, Sarazin G (1984) Constantes de formation des complexes hydroxydés de l'aluminum en solution aqueuse de 20 et 70°C. Geochim Cosmochim Acta 48: 649-659.
7. Ekberg C, Albinsson Y, Comarmound MJ, Brown PL (2000) Studies on the complexation behavior of Thorium(IV). 1. Hydrolysis equilibria. J Soln Chem 29: 63-86.
8. Ekberg C, Källvenius G, Albinsson Y, Brown PL (2004) Studies on the hydrolytic behavior of zirconium(IV). J Soln Chem 33: 47-79.
9. Frink CR, Peech M (1963) Hydrolysis of the aluminum ion in dilute solutions. Inorg Chem 2: 473-478.
10. Klungness GD, Byrne RH (2000) Comparative hydrolysis behavior of the rare earths and yttrium: the influence of temperature and ionic strength. Polyhedron 19: 99-107.
11. 4+. J Soln Chem 35: 927-937.
12. 4 solutions. Geochim Cosmochim Acta 71: 4825-4833.
13. Millero FJ, Woosley RJ (2009) The hydrolysis of Al(III) in NaCl solutions-a model for Fe(III). Environ Sci Technol 43(6): 1818-1823.
14. Neck V, Kim JI (2001) Solubility and hydrolysis of tetravalent actinides. Radiochem Acta 89: 1-16.
15. Palmer DA, Wesolowski DJ (1992) Aluminum speciation and equilibria in aqueous solution: II. The solubility of gibbsite in acidic sodium chloride solutions from 30 to 70°C. Geochim Cosmochim Acta 56: 1092-1111.
16. Palmer DA, Wesolowski DJ (1993) Aluminum speciation and equilibria in aqueous solution: III. Potentiometric determination of the first hydrolysis constant of aluminum (III) in sodium chloride solutions to 125°C. Geochim Cosmochim Acta 57: 2929-2938.
17. Paulson AJ, Kester DR (1980) Copper(II) ion hydrolysis in aqueous solution. J Solution Chem 9: 269-277.
18. 2+) in concentrated aqueous electrolyte solutions at 25°C. J Colloid Interface Sci 291: 421-432.
19. 2(am). J Solution Chem 30: 949-967.
20. Schofield RK, Taylor AW (1954) The hydrolysis of aluminum salt solutions. J Chem Soc 4445-4448.
21. Tarapcik P, Fourest B, Giffaut E (2005) Comparative approach of the solubility of protactinium oxy/hydroxides. Radiochem Acta 93: 27-33.
22. Verdes G, Gout R, Castet S (1992) Thermodynamic properties of aluminate ion and of bayerite, boehmite, diaspore and gibbsite. Eur J Mineral 4: 767-792.
23. Wesolowski DJ (1992) Aluminum speciation and equilibria in aqueous solution: I. The solubility of gibbsite in the system Na-K-Cl-OH-Al(OH)4 from 0 to 100°C. Geochim Cosmochim Acta 56: 1065-1091.
24. Wesolowski DJ, Palmer DA (1994) Aluminum speciation and equilibria in aqueous solutions: V. Gibbsite solubility at 50°C and pH 3-9 in 1 molal NaCl solutions (a general model for aluminum speciation; analytical methods). Geochim Cosmochim Acta 58: 2947-2969.
25. Zakanova-Herzog VP, Seward TM, Sulemenov OM (2006) Arsenous acid ionization in aqueous solutions from 25 to 300°C. Geochim Cosmochim Acta 70: 1928-1938.