Kinetics of the redox reaction between sodium tetrahydroborate and copper(II) sulphate. Evidence for cuprous hydride

Oxidation Communications

Volumn 33, Issue 1, 2010, Pages 88-92

  Dasgupta, M ^a   Mahanti, M K ^a,b  

^a NORTH EASTERN HILL UNIVERSITY   (India)

^b NATIONAL INSTITUTE OF SCIENCE EDUCATION AND RESEARCH   (India)

Author keywords

Copper(II); Kinetics; Sodium tetrahydroborate

Indexed keywords

EID: 77951864989     PISSN: 02094541     EISSN: None     Source Type: Journal    
DOI: None     Document Type: Article

References (17)

1. A. P. GINSBERG: Diborane Derivatives of Transition Metal Ions. Adv. Transition Metal Chem., 1, 111 (1965).
2. M. L. H. GREEN, D. J. JONES: Hydride Complexes of the Transition Metals. Adv. Inorg. Chem. Radiochem., 7, 215 (1965).
3. S. W. CHAIKIN, W. G. BROWN: Reduction of Aldehydes, Ketones and Acid Chlorides by Sodium Borhydride. J. Amer. Chem. Soc., 71, 122 (1955).
4. H. C. BROWN, E. J. MEAD, B. C. SUBBA RAO: A Study of Solvents for Sodium Borohydride and the Effect of Solvent and the Metal Ion on Borohydride Reductions. J. Amer. Chem. Soc., 77, 6209 (1955).
5. -. Polyhedron, 3, 771 (1984).
6. G. THOMAS, P. S. ZACHARIAS: Cyclic Voltammetric Studies of Copper(II) Dipeptide Complexes. Evidence for Copper(I) Dipeptide Complexes in Aqueous Media. Polyhedron, 3, 861 (1984).
7. J. C. WARF, W. FEITKNECHT: Zur kenntnis des Kupferhydrids, insbesondere der Kinetik des Zerfalls. Helv. Chim. Acta, 33, 613 (1950).
8. E. WIBERG, W. HENLE: The Reaction of Copper(II) and Lithium Aluminium Hydride. Formation of Cuprous Hydride. Z. Naturforsch., 72, 250 (1952).
9. V. I. MIKHEEVA, M. N. MAL'TSEVA: Infrared Absorption Spectra of Some Simple Hydrides. J. of Struct. Chem., 4, 643 (1964).
10. J. A. DILTS, D. F. SHRIVER: Nature of Soluble Copper(I) Hydride. J. Am. Chem. Soc., 90, 5769 (1968).
11. E. PETERS, J. HALPERN: Homogeneous Catalytic Activation of Molecular Hydrogen by Cupric Perchlorate. J. Phys. Chem., 59, 793 (1955).
12. G. J. KORINEK, J. HALPERN: Kinetics of the Reaction of Molecular Hydrogen with Mercuric and Mercurous Perchlorate in Aqueous Solution. J. Phys. Chem., 60, 285 (1956).
13. A. H. WEBSTER, J. HALPERN: Homogeneous Catalytic Activation of Molecular Hydrogen in Aqueous Solution by Silver Salts. II. High Temperature Hydrogenation and Exchange Studies. J. of Phys. Chem., 61, 1239 (1957)
14. A. H. WEBSTER, J. HALPERN: Homogeneous Catalytic Activation of Molecular Hydrogen in Aqueous Solution by Silver Salts. III. Precipitation of Metallic Silver from Solutions of Various Silver Salts. J. Phys. Chem., 61, 1245 (1957).
15. J. HALPERN: Homogeneous Catalytic Hydrogenation: A Retrospective Account. J. Organomet. Chem., 200, 133 (1980) and references therein.
16. J. GOUBEAU, H. KALFASS: Die Reaktion Natriumborhydrid und Wasser. Z. Anorg. Allgem. Chem., 299, 160 (1959).
17. J. A. GARDINER, J. W. COLLATT: Kinetics of the Stepwise Hydrolysis of Tetrahydroborate Ion. J. Amer. Chem. Soc., 87, 1692 (1965).